Abstract
The 4,5-dihydroxy-2-imidazolidinone system, with methyl and/or methylol substituents in the 1,3-positions, has been studied with respect to the geometry of the hydroxyls in the 4,5-positions and with respect to the textile properties of cotton cross-linked with these agents. In addition, some of the impurities and byproducts expected in this system are discussed. Fabrics finished with the cross-linking agents have been compared with respect to acidic and basic hydrolysis of the finish, wrinkle recovery angle, chlorine damage, discoloration, and formaldehyde release.
Keywords
CrosslinkingReactions (Chemical)GlyoxalUreaDMDHEUDeferred Cure MethodAcid HydrolysisAlkaline HydrolysisCottonCotton FabricsCatalystsImpuritiesDry Wrinkle RecoveryWet Wrinkle RecoveryChlorine DamageDiscolorationFormaldehydeOdorTear StrengthStoll QM Abrasion TestingBreaking StrengthNuclear Magnetic Resonance
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References
1.
Barker
R. H.
Vail
S. L.
Barcelo
G. B.
, J. Heterocyclic Chem . 3 , 354 (1966 ).
2.
Dinwoodie
A. H.
Fort
G.
Thompson
J. M. C.
, J. Chem. Soc. (C) , 1967 , 2565, and references therein.
3.
Harper
R. J.
Blanchard
E. J.
Lofton
J. T.
Gautreaux
G. A.
, Textile Res. J . 37 , 233 –241 (1967 ).
4.
Nematollahi
J.
Ketcham
R.
, J. Org. Chem . 28 , 2378 (1963 ).
5.
Petersen
H.
, Textile Res. J . 38 , 156 –176 (1968 ).
6.
Pierce
A. G.
Frick
J. G.
, Am. Dyestuff Reptr . (In press).
7.
Price
C. C.
Knell
M.
, J. Am. Chem. Soc . 64 , 552 (1942 ).
8.
Reeves
W. A.
Vail
S. L.
Frick
J. G.
, Textile Res. J . 32 , 305 –312 (1962 ).
9.
Rollins
M. L.
Carra
J. H.
Gonzales
E. J.
Berni
R. J.
, Ibid . 36 , 185 –201 (1966 ).
10.
Vail
S. L.
, Chem. and Ind . 1967 , 305 .
11.
Vail
S. L.
Barker
R. H.
Mennitt
P. G.
, J. Org. Chem . 30 , 2179 (1965 ).
12.
Vail
S. L.
Barker
R. H.
Moran
C. M.
, Ibid . 31 , 1642 (1966 ).
13.
Vail
S. L.
Murphy
P. J.
Frick
J. G.
Reid
J. D.
, Am. Dyestuff Reptr . 50 , 550 (1961 ).