The degradation of undyed yarns of viscose rayon, cellulose (secondary) acetate rayon, and nylon 6.6, both free from and containing titanium dioxide (anatase), has been studied at different temperatures. The degradation in moist air is particularly marked at high temperatures. A possible reaction mechanism for the sensitizing effect of titanium dioxide is discussed.
Get full access to this article
View all access options for this article.
References
1.
Anon., Silk and Rayon 7, 514 (1933).
2.
Barnes, B.T. and Forsythe, W.E., J. Optical Soc. Amer. 27, 83 (1937)
3.
Calvert, J.G. , Theurer, K., Rankin , G.T., and McNevin, W., J. Amer. Chem. Soe. 76, 2575 (1954 ).
4.
Chari, C.N. and Quereshi, M., J. Indian Chem. Soc. 21, 97 (1944)..
5.
Egerton, G.S. , J. Soc. Dyers Colourists63, 161 (1947); J. Textile Inst. 39, T293 (1948).
6.
Egerton, G.S. , J. Soc.Dyers Colourists64, 336 (1948).
7.
Egerton, G.S. , J. Soc.Dyers Colourists65, 764 (1949).
8.
Egerton, G.S. , J. Textile Inst. 39, T305 ( 1948).
9.
Egerton, G.S. , Nature204, 1153 (1964).
10.
Hall, A.J., Textile Mercury94, 578 (1936).
11.
Keiner, L., Melliand Textilber.15, 118 (1934).
12.
Markham, M.C. and Laidler, K.J., J. Phys. Chem. 57, 363 (1953).
13.
Markham, M.C. , Hannan, M.C., and Evans, S., J. Amer.Chem. Soc.76, 820 (1954).
14.
Markham, M.C. , Hannan, M.C., Paternostro , R.M., and Rose, C.B., J. Amer.Chem. Soc.80, 5394 (1958 ).
15.
Phillips, G.O. and Arthur, J.C., Jr., Textile Res. J. 34, 572 (1964).
16.
Rubin, T.R., Calvert, J.G., Rankin, G.T., and McNevin, W., J. Amer. Chem. Soc.75, 2850 (1953).