The synthesis of acryloyloxy-o,o'-dihydroxyazo dyes and their chromium complexes is described by IR, UV-VIS, and 1 H-NMR spectroscopic techniques, magnetic susceptibility, thin-layer chromatography, and elemerttal analysis. The synthesized dyes and complexes are applied to wool and nylon fabric. Fastness to light, washing, and rubbing of the dyed fabrics is measured and discussed.
Get full access to this article
View all access options for this article.
References
1.
Catino, S.C., and Farris, R.E., Azo Dyes in "Concise Encyclopedia of Chemical Technology," M. Grayson, Ed., John Wiley & Sons , NY, 1985, p. 142.
2.
"Colour Index," vol. IV, The Society of Dyers and Colourists, American Association of Textile Chemists , London, 1971, p. 4034.
3.
Dakiky, M. and Memcova, I., Aggregation of o,o'-Dihydroxyazo Dyes, 1: Concentration, Temperature, and Solvent Effect, Dyes Pigments40, 141-150 (1999).
4.
Freeman, H.S. , and Sokolowska, J., Developments in Dyestuff Chemistry, Rev. Prog. Color.29, 8-21 (1999).
5.
Gregory, P., "High-Technology Applications of Organic Colorants," Plenum Press, NY, 1991, pp. 1-3.
6.
Griffiths, J., "Colour and Constitution of Organic Molecules," Academic Press, NY, 1976, pp. 193-195.
7.
Hamed, M.M.A. , Ismail, N.M., and Ibrahim, S.A., SolventCharacteristics in The Spectral Behaviour of Eriochrome Black T, Dyes Pigments26, 297-305 (1994).
8.
Hsieh, B.R., Azo-Hydrazone of an o,o'-Dihydroxy Azo Dye—A Spectroscopic Study , Dyes Pigments14, 165-189 (1990).
9.
Hsieh, B.R., Synthesis of Aizen Spilon Black TRH and Its Derivatives, Dyes Pigments14, 287-305 (1990).
10.
Kocaokutgen, H., Erdem, E., and Gümrükçüoğlu , I.E., Synthesis of HMFAN and Its Chromium and Cobalt Complexes and Their Application on Nylon 6 and Wool, J. Soc. Dyers Colour.114, 93-95 (1998).
11.
Küppers, H., "Systematische Farbtabellen Für Den Sieben-Farben-Druck Farbenatlas," Callway, München. 1987.
12.
Law, K.Y., Tarnawskyj, I.W., and Lubberts, P.T., Azo Pigments and Their Intermediates, Effect of Substitution on the Diazotization and Coupling Reactions of o-Hydroxyanilines, Dyes Pigments23, 243-254 (1993).
13.
Monohan, A.R. , and Flannery, J.B., Hydrogen Bonding in Crystalline Arylazonaphthols , Chem. Phys. Lett.17, 510-513 (1972).
14.
Peters, A.T. , and Freeman, H.S., "Colour Chemistry, The Design and Synthesis of Organic Dyes and Pigments ," Elsevier Applied Science Publishing, Barking Essex, U.K., 1991, pp. 193-195.
15.
Rys, P., and Zollinger, H., "Fundamentals of the Chemistry and Application of Dyes," John Wiley and Sons, NY, 1972, pp. 54-58.
16.
Shuhaibar, K., and Pasch, F.H., The Synthesis andCharacterization of Polymerizable Azo-Naphthols for Use in Polymeric Materials, Dyes Pigments15, 57-67 (1991).
17.
Venkataraman, K., "The Chemistry of Synthetic Dyes," vol. 3, Academic Press, NY, 1970, pp. 303-369.
18.
Wang, I.J., Husu, Y.H., and Tian, J.H., Synthesis andProperties of Some Pyridone Chromium Complex Azo Dyes, Dyes Pigments16, 83-91 (1991).
