The dyeing properties of chitin/cellulose composite fibers—Crabyon® (CR)—for four reactive dyes are examined and compared with those of viscose rayon and partially deacetylated chitin. The CR fibers show high fixation for dyeing with CI Reactive Blue 5 with a monochlorotriazinyl group in a weakly acidic solution and with CI Reactive Blue 19 with a sulfatoethylsulfonyl group from weakly acidic to weakly alkaline solutions. The CR fibers can be dyed with CI Reactive Blue 19 in wide pH ranges, compared with viscose rayon, which cannot be dyed at these same pH ranges.
Get full access to this article
View all access options for this article.
References
1.
Auzely-Velty, R., and Rinaudo, M., Chitosan Derivatives Bearing Pendant Cyclodextrin Cavities: Synthesis and Inclusion Performance, Macromolecules34, 3574-3580 (2001).
2.
Dohmyo, M., Shimizu, Y., and Kimura, M., Reaction Mechanism of Sulfatoethylsulfon Dye with Silk, J. Seric. Sci. Jpn.53, 64-68 (1984).
3.
Giles, G.H., "A Laboratory Course in Dyeing," The Society of Dyers and Colourists, England, 1974, p. 142.
4.
Izumi, S., Shimizu, Y., and Higashimura, T., Absorption Behaviors of Metal Ions on Chitin/Cellulose Composite Fibers with Chemical Modification by EDTA, Textile Res. J.72, 515-519 (2002).
5.
Knott, J., and Rossbach, V., Determination of the Amino End Groups in Polyamide 6 and 6,6 with Ninhydrin , Angew. Makromol. Chem.86, 203-213 (1980).
6.
Nakajima, T. , Shimizu, Y., and Higashimura , T., Dyeing Rates of an Acid Dye and a Direct Dye for Chitin/Cellulose Composite Fibers , Chitin Chitosan Res.6, 59-65 (2000).
7.
Reinert, G., Mella, K., Rouette, P.F., and Zahn, H., On the Chemical Binding of Reactive Dyes to Protein Fibers and Polyamide Fibers , Melliand Textilber.49, 1313-1321 (1968 ).
Seo, H., Antimicrobial Fiber from Chitosan, Senshoku Kougyou41, 177-183 (1993).
10.
Shimizu, Y. , On the Dyeing of Silk with Reactive Dye (Part 4), Sci. Rep. Shiga Prefect. J. Coll. (13), 18-21 (1972).
11.
Shimizu, Y. , Reaction of C.I. Reactive Blue 19 with Silk , Sen-i Gakkaishi31, T180-T185 ( 1975).
12.
Shimizu, Y. , Behaviors of C.I. Reactive Blue 19 in Aqueous Solution, Sen-i Gakkaishi33, T261-T265 (1977).
13.
Shimizu, Y. , Nakajima, T., Yoshikawa , M., and Takagishi, T., Dyeing of Chitin/Cellulose Composite Fibers with an Acid Dye, Textile Res. J.72, 563-567 (2002).
14.
Yoshikawa, M., Crabyon (in Japanese), Chemistry54, 34-36 (1999).