A series of polyurethane elastomers based on an aliphatic diisocyanate and a polyether macroglycol was polymerized with various crosslink densities and OH/NCO ratios. Stoichiometries yielding between 8,600 and 12,900 gm/ mole/crosslink and an OH/NCO ratio of 1.1 resulted in polymers with the low modulus, yet high strength and elongation necessary for maxillofacial applications.
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References
1.
Bulbulian, A.H. : Facial Prosthetics, Springfield: Charles C Thomas, 1973. 2. Castleberry, D.J.: Materials for External Prostheses; The Choices and the Challenge, Symposium on Dental Biomaterials-Research Priorities, NIDR, Des Plaines, II, Aug 1973.
2.
Firtell, D.N., and Bartlett, S.O.: Maxillofacial Prosthetics: Reproducible Fabrication, J Prosth Dent, 22:247-252, 1969. 4. Lepley, J.B., and Strauss, P.W.: Functional and Cosmetic Restoration of a Massive Orofacial Defect, J Prosth Dent, 30 :635-636, 1973.
3.
Chalian, V.A.; Drane, J.B. ; and Stan-Dish, S.M. : Maxillofacial Prosthetics: Multidisciplinary Practice, Baltimore: Williams and Wilkins Co., 1971, p 96.
4.
Lewis, D.H.; Miller, D.R.; and Cowsar, D.R.: Development of Improved Materials for Extraoral Maxillofacial Prostheses, P.H.S., N.I.D.R. Contract NOL-DE-42435, June 1976.
5.
Robeson, L.M.; Saunders, W.J.; Chow, S.; and Matzner, M.: Development of Improved Materials for Extraoral Prostheses, P.H.S., N.I.D.R. Contract NOL-DE-42436, November 1976.
6.
Lymann, D.J. ; Kwan-Gett, C.; Zwart, H.H.J. ; Bland, A.; Eastwood, N.; Kawai, J.; and Kolff, W.J.: The Development and Implantation of a Polyurethane Hemispherical Artificial Heart, Trans Am Soc Artif Intern Organs, 17:456-463, 1971.
7.
Kolff, T.; Burkett, G.; and Feyen, J.: Copoly(ether-urethanes) as Materials for Artificial Hearts, Biomater Med Devices Artif Organs1 :669-679, 1973.
8.
Gardner, D.L. : Stability of Heparin Sulfur-35 Attached to a Modified Polyurethane Vascular Prosthetic, Trans Am Soc Artif Intern Organs, 15:7-14, 1969.
9.
Brash, J.L. ; Fritzinger, B.K.; and Bruck, S.D.: Development of Block Copolyether-Urethane Intraaortic Balloons and Other Medical Devices, J Biomed Mater Res, 7: 313-334, 1973.
10.
Borftos, J.W. , and Pierce, W.S.: Segmented Polyurethane: A Polyether Polymer , J Biomed Mater Res2:121-130, 1968. 13.Boretos, J.W.; Detmer, D.E.; and Don-Achy, J.H.: Segmented Polyurethane: A Polyether Polymer, II: Two Years Experience, J Biomed Mater Res, 5:373-387, 1971. 14. Skornik, W.A.; Dressler, D.P.; and Rhi-Card, J.K.: Adherence of Prosthetic Skin, J Biomed Mater Res, 2:447-456, 1968. 15. Dressler, D.P.; Barlyn, L.; and Skornik, W.A.: Viable Prosthetic Interface, J Biomed Mater Res Symposium, 1: 169-178, 1971.
11.
Sharp, W.V. ; Taylor, B.C.; Wright, J.; and Finelli, A.F.: Experience with Negatively Charged Polyurethane Backed Velours, J Biomed Mater Res Symposium, 1: 75-81, 1971.
12.
Sharp, W.V. ; Gardner, D.L.; and Andre-Sen , G.J.: Bioelectric Polyurethane and Its Use in Internal Prostheses, U.S. Patent3, 512,183 (cl. 3-1; a61f), 19 May, 1970.
13.
Llewellyn-Thomas, E.; Wang, P.Y.; and Cannon, J.S.: Adhesion of Synthetic Organic Polymer on Soft Tissue. I. Fast Setting Polyurethane Adhesive, J Biomed Mater Res, 8:35-43, 1974.
14.
Bernhard, W.F. ; Cummin, A.S.; Harris, P.D.; and Kent, E.W.: New Flexible Vascular Adhesive for Use in Cardiovascular Surgery, Circulation, 27:739-741, 1963.
15.
Sherman, R.T.: Evaluation of Polymers as Surgical Prostheses, U.S. Clearinghouse Fed. Sci. Tech. Inform., AD 1969, AD690700. 21. PHILLIPS, R.W.: Science of Dental Materials , 7th ed., Philadelphia: W. B. Saunders, 1973, p 239.
16.
Saunders, J.H. , and Frisch, K.C.: Polyurethanes, Chemistry and Technology, Technology, Parts I and II, in High Polymers V. XVI, New York: Interscience, 1962 and 1964.
17.
Wright, P., and Cumming, A.P.C.: Solid Polyurethane Elastomers, New York: Gordon and Breach, 1969.
18.
Saunders, J.H. : Polyurethane Elastomers, in Polymer Chemistry of Synthetic Elastomer, Kennedy, J.P. and Tornquist, E.G.M., ed., New York: John Wiley, 1969. 25.Frisch, K.C.: Recent Advances in the Chemistry of Polyurethanes , Rubber Chem Technol, 45: 1442-1466, 1972 .
19.
Bonart, R.; Mobitzer, L.; and Hentze, G.: X-ray Investigations Concerning the Physical Structure of Crosslinking Urethane Elastomers. II. Butanediol as Chain Extender, J Macromol Sci Phys, 3 : 339-358, 1969. 27. Bonart, R.; Morbitzer, L.; and Mueller, E.H.: X-ray Investigations Concerning the Physical Structure of Crosslinking in Urethane Elastomers, III. Common Structure Principles for Extensions with Aliphatic Diamines and Diols, J Macromol Sci Phys, 9: 447-461, 1974.
Dieter, C.: Personal Communication, Dept. of Polymer Science, University of Detroit, Detroit, Michigan, 1972 .
22.
Smith, T.L. , and Magnusson, A.B.: Diisocyanate-Linked Polymers. II. Mechanical and Swelling Properties of Some Polyurethane Elastomers, J Polym Sci, 42:391-416. 1960.