Infrared internal reflection spectroscopy (IRS) was used to study changes in surface chemistry of enamel after in vitro weak acid demineralization. Hypotheses that relate previous histomorphologic observations to current IRS findings are discussed.
Get full access to this article
View all access options for this article.
References
1.
Miller, W.D. : New Theories Concerning the Decay of Teeth , Dent Cosmos47: 1293, 1905.
2.
Little, M.F. ; Posen, J.; and Singer, L.: Chemical and Physical Properties of Altered and Sound Enamel: III. Fluoride and Sodium Content, J Dent Res41:784-789, 1962.
3.
Macgregor, A.B. : Acid Production and the Carious Process, J Dent Res38:1055, 1959.
4.
Shafer, W.G. ; Hine, M.G.; and Levy, B.M.: A Textbook of Oral Pathology, Philadelphia: W.B. Saunders Co., 1963, pp 308-377.
5.
Jenkins, G.N. : in Vitro Studies Using Chemicals, in Harris, R.S. (ed): Art and Science of Dental Caries Research, New York: Academic Press, 1968, pp 331-354.
6.
Brudevold, F. , and Soremark, R.: Chemistry of the Mineral Phase of Enamel , in Miles, A.E.W. (ed): Structural and Chemical Organization of Teeth, New York : Academic Press, Vol 2, pp 247-277, 1967.
7.
Wet, S.H.Y. : Remineralization of Enamel and Dentine-A Review , J Dent Child34: 444-451, 1967.
8.
Koulourides, T.; Feagin, F.; and Pigman, W.: Remineralization of Dental Enamel by Saliva In Vitro, Ann NY Acad Sci131: 685-693, 1965.
9.
Sognnaes, R.F.: Mechanisms of Hard Tissue Destruction, Washington, DC: AAAS1963, pp 91-153.
10.
Hoffman, S.; Rovelstad, G.; McEwan, S.; and Drew, C.M.: Demineralization Studies of Fluoride-Treated Enamel Using Scanning Electron Microscopy, J Dent Res48:1296-1307, 1969 .
11.
Poole, D.F.G. , and Silverstone , L.M.: Observations with the Scanning Electron Microscope on Trauma-Induced Microcavities in Human Enamel, Arch Oral Biol14: 1323-1329, 1969 .
12.
Krutchkoff, D.J. ; Rowe, N.H.; Mark , H.B., JR: Infrared Internal Reflection Spectroscopy of Human Enamel Surface, Arch Oral Biol16:161-175, 1971.
13.
Harrick, N.J.: Internal Reftection Spectroscopy, New York: Wiley and Sons, 1967, pp 217-291.
14.
i14. Silverstone, L.M.: The Surface Zone in Caries-Like Lesions Produced In Vitro, Brit Dent J125:145-157, 1968.
15.
Elliott, J.C.: The Interpretations of the Infrared Absorption Spectra of Some Carbonate-Containing Apatites, in Stack, M.V., and Fearnhead, R.W. (eds): International Symposium on Tooth Enamel, Bristol: John Wright , pp 20-25, 1965.
16.
Termine, J.D. , and Posner, A.S.: Infrared Determination of the Percentage of Crystallites in Apatitic Calcium Phosphates, Nature211:268-270, 1966.
17.
Stutman, J.M. ; Termine, J.D.; and Posner , A.S.: Vibrational Spectra of the Phosphate Ion in Some Calcium Phosphate, Trans NY Acad Sci27:669-675, 1965.
18.
McConnell, D.: The Crystal Chemistry of Carbonate Apatites and Their Relationship to the Composition of Calcified Animal Tissues, J Dent Res31:53, 1952.
19.
Meckel, A.H.; Griebstein, W.J.; and Neal, R.J.: Ultrastructure of Fully Calcified Human Dental Enamel, in Stack, M.V., and Fearnhead, R.W. (eds): International Symposium on Tooth Enamel, Bristol: John Wright, pp 160-163, 1965.
20.
Johansen, E.: Comparison of the Ultrastructure and Chemical Composition of Sound and Carious Enamel from Human Permanent Teeth, in Stack, M.V., and Fearnhead, R.W.: International Symposium on Tooth Enamel, Bristol: John Wright, pp 177-182, 1965.
21.
Helmcke, J.G. : Ultrastructure of Enamel, in Miles, A.E.W. (ed): Structural and Chemical Organization of Teeth, New York: Academic Press, Vol 2, 1967, pp 135-163.
22.
Lenz, H.: Ultrastructure of the Tooth in Respect of Mineralization, Demineralization and Remineralization, Int Dent J17: 684-692, 1967.
23.
Stack, M.V.: Chemical Organization of Enamel Matrix, in Miles, A.E.W. (ed): Structural and Chemical Organization of Teeth , New York: Academic Press, Vol 2, pp 317-342, 1967.
24.
Patel, P.R.: Studies on Acid Demineralization Kinetics of Enamel, PhD thesis, University of Michigan, 1965.