Krypton adsorption studies demonstrated an easily accessible system of pores in enamel, measuring between 10 and 300 A, volume 0.26%, with a surface area of about 0.4 sq m/gm (BET analysis). These figures are much lower than is suggested by figures for water content, possibly resulting from non-penetration of the organic matrix by krypton. Some measurements on demineralized enamel were also made.
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References
1.
Darling, A.I. ; Mortimer, K.V.; Poole, D.F.G.; and Ollis, W.D.: Molecular Sieve Behaviour of Normal and Carious Human Dental Enamel, Arch Oral Biol5:251-273, 1961.
2.
Gwinnett, A.J. : Normal Enamel: I. Quantitative Polarized Light Study, J Dent Res45:120-127, 1966.
3.
Burnett, G., and Zenewitz, J.: Studies of the Composition of Teeth: VIII. The Moisture Content of Calcified Tooth Tissues, J Dent Res37:581-589, 1958.
4.
Little, M.F. , and Casciani, F.S.: The Nature of Water in Sound Enamel: A Preliminary Study, Arch Oral Biol11:565, 1966.
5.
Brudevold, F. ; Steadman, L.T.; and Smith, F.A.: Inorganic and Organic Components of Tooth Structure, Ann N Y Acad Sci85:110-132, 1960.
6.
McCann, H.G., and Bullock, F.A.: Reactions of Fluoride Ion with Powdered Enamel and Dentin, J Dent Res34:859-867, 1955.
7.
Brudevold, F. ; Mccann, H.G.; and Grn, P.: in Wolstenholme, G.F.W., and O'Con-nor, M. (eds.), Caries Resistant Teeth, LondonJ. A. Churchill, 1965, pp 125, 147.
8.
Poole , D.F.G., and Stack, M.V.: in Stack, M.V., and Fearnhead, R.W. (eds.), Tooth Enamel, Bristol, England: J. Wright & Sons, 1965, pp 172-176.
9.
Myers, H.M., and Myrberg, N.: Proton Magnetic Resonance Studies of the Water of Enamel at Low Temperature , Acta Odont Scand23:593-599, 1965.
10.
Myrberg, N.: Proton Magnetic Resonance in Human Enamel and Dentine, Trans Roy SchoolsDent, StockholmUmeå 14, 1968.
11.
Gillings, R.D. , and Beck, D.J.: Tooth Enamel Powders for Experimental Procedures , J Dent Res43:304, 1964.
12.
Rosenberg, A.J.: Rapid and Precise Measurement of Krypton Adsorption, J Amer Chem Soc78:2929-2934, 1956.
13.
Haynes, J.M. : Use of Krypton for Surface Area Measurements , J Phys Chem66:182-185, 1962.
14.
Brunauer, S. ; Emmett, P.H.; and Teller, G.: Adsorption of Gases in Multimolecular Layers , J Amer Chem Soc60:209-219. 1938.
15.
Cosgrove, L.A. : Porosity of Anodic Oxide Coatings on Aluminum and Comparison of n-Butane and Krypton Adsorption, J Phys Chem60:385-388, 1965.
16.
Schull, C.G.: The Determination of Pore-size Distribution from Gas Adsorption Data, J Amer Chem Soc70:1405-1410, 1948.
17.
Brunauer, S. ; Deming, L.S.; Deming, W.S.; and Teller, E.: On the Theory of the van der Waals Adsorption of Gases, J Amer Chem Soc62:1723, 1940.
18.
Barrer, R.M. , and Macleod, J.: Intercalation and Sorption by Montmorillonite , Trans Faraday Soc50:980-989, 1954.