Properties of filled n-butyl-α-cyanoacrylates were studied as a function of filler-monomer ratio, time, and curing conditions. Matrix characteristics were determined on amine initiated bulk polymer. Calcium carbonate and mixtures of zinc oxide and zinc phosphate formed reinforced materials with low solubility and disintegration.
Get full access to this article
View all access options for this article.
References
1.
Medical Research Department, Ethicon, Inc.: Methyl 2-Cyanoacrylate Monomer, a Biodegradable Plastic Tissue Adhesive : Review, Somerville, NJ: Ethicon, Inc., 1966 revision, with separate supplement to bibliography revised June 30, 1967, 14 pp.
2.
Cueto, E.I. , and BuoNOcORE , M.G.: Sealing of Pits and Fissures with an Adhesive Resin: Its Use in Caries Prevention, JADA75:121-128, 1967.
3.
Buonocore, M. ; AzEvEDO, N.; and Dalton, E.: Evaluation of Cavity Liners for Permeability and Adhesion to Dentin, New York Dent J28:239-244, 1962.
4.
Collito, M.B. : Dental Methods Employing Cyanoacrylate, US Patent3,250,002, May 1966.
5.
Bhaskar, S.N. ; Frisch, J.; Margetis, P.M.; and Leonard, F.: Application of a New Chemical Adhesive in Periodontic and Oral Surgery, Oral Surg22:526-535, 1966.
6.
Bhaskar, S.N. ; Frisch, J.; and Margetis, P.M.: Tissue Response of Rat Tongue to Hexyl, Methyl and Octyl Cyanoacrylate, Oral Surg24:137-144, 1967.
7.
Kulkarni, R.K. : Determination of Sulfur Dioxide in Alpha Cyanoacrylates by pH of Aqueous Dispersions, U.S. Army Medical Biomechanical Research Laboratory Technical Report No. 6413, 1964.
8.
Brandes, G., and Kulicarni, R.K.: Cyanoacrylate Adhesives: II. Synthesis and Characterization of Alkyl Alpha Cyanoacrylates, U.S. Army Medical Biomechanical Research Laboratory Technical Report No. 6514, 1965.
9.
American Dental Association: Guide to Dental Materials, 3d ed, Chicago: American Dental Association, 1966.
10.
Civjan, S., and De Simon, L.B.: Evaluation of the Diametral Compression Test, J Dent Res46:1540, 1967.
11.
Taylor, D.F. , and Margetis, P.M.: Progress Report on a Setting Time Test for Dental Amalgam, National Bureau of Standards Report No. 6109, 1958.
12.
Civjan, S., and Brauer, G.M.: Physical Properties of Cements, Based on Zinc Oxide, Hydrogenated Rosin, o-Ethoxybenzoic Acid and Eugenol, J Dent Res43:281-299, 1964.
13.
Leonard, F. ; Kulkarni, R.K.; Brandes, G.; Nelson, J.; and Cameron, J.J.: Synthesis and Degradation of Poly(Alkyl-α-Cyanoacrylates) , J Appl Polym Sci10: 259-272, 1966.
14.
Graham, D.M. , and Mesrobian, R.B.: Oxidation of N,N-Dimethylaniline: I. The Reaction with Benzoyl Peroxide, Canad J Chem41:2938-2944, 1963.
15.
Porter, H.J. , and Kulkarni, R.K.: Polymethyl Alpha Cyanoacrylates: I. Molecular Weight Determination by Light Scattering: II. Effect of Various Anionic Initiators on Terminal Structure, U.S. Army Medical Biomechanical Research Laboratory Technical Report No. 6512, 1965.
16.
Porter, H.J. , and Kulkarni, R.K.: Glass Transition Temperatures of Poly Alkyl Alpha Cyanoacrylates, U.S. Army Medical Biomechanical Research Laboratory Technical Report No. 6602, 1966.
17.
Mark, H., and Tobolsky, A.V.: Physical Chemistry of High Polymeric Systems, 2d ed, New York: Interscience Publishers, Inc., 1950, pp 454-457.