A model is presented of the steps involved in the manufacturing process of semicrystal line thermoplastic matrix composites. The model relates the temperature and pressure ap plied during processing to a) the flow of the matrix into the fiber tow, b) the formation of contact and bond between adjacent plies, and c) the crystallinity. The results of the model were verified by tests performed with PEEK 150P polymer and APC-2 graphite/PEEK composite.
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References
1.
Springer, G.S."A Model of the Curing Process of Epoxy Matrix Composites," in Progress in Science and Engineering of Composites, T. Hayashi, K. Kawaka and S. Umekawa, eds.), Japan Society for Composite Materials , pp. 23-35 (1982).
2.
Loos, A.C. and G.S. Springer."Curing of Epoxy Matrix Composites,"Journal of Composite Materials, 17:135-169 (1983)
3.
Campbell, F.C., A.L. Mallow, F.R. Muncaster, B.L. Boman, G.A. Blase."Computer Aided Curing of Composites," Air Force Materials Laboratory Report , AFWAL-TR-86-4060, Wright Patterson Air Force Base, Ohio (1986).
4.
Calius, E.P. and G.S. Springer."Modeling the Filament Winding of Composites," Proceedings of the Fifth International Conference on Composite Materials (W.C. Harrigan, Jr., J. Strife and A. K. Dhingra, eds.), The Metallurigical Society, pp. 1071-1088 (1985).
5.
Streeter, V.L. and E.B. Wylie.Fluid Mechanics, McGraw-Hill, New York (1975).
6.
Happel, J."Viscous Flow Relative to Arrays of Cylinders,"AICHE Journal, 5:174-177 (1959).
7.
Dara, P.H. and A.C. Loos."Thermoplastic Matrix Composite Processing Model,"Center for Composite Materials and Structures, Report CCMS-85-10, VPI-E-85-21,Virginia Polytechnic Institute and State University, Blacksburg, Virginia (1985).
8.
Wool, R.P. and K.M. O'Connor."Theory of Crack Healing in Polymers,"Journal of Applied Physics, 52:5953-5963 (1981 ).
9.
Wool, R.P."Relations for Healing, Fracture, Self-Diffusion and Fatigue of Random Cool Polymers,"ACS Polymer Prepnnts , 23(2):62 (1982).
10.
Jud, K., H.H. Kausch and J.G. Williams."Fracture Mechanics Studies of Crack Healing and Welding of Polymers,"Journal of Material Science, 16:204-210 (1981)
11.
Eckert, E.R.G. and R.M. Drake.Heat and Mass Transfer , New York:McGraw-Hill (1975).
12.
Springer, G.S. and S.W. Tsai"Thermal Conductivities of Unidirectional Materials,"Journal of Composite Materials, 1:166-173 (1967).
13.
Loos, A.C. and G.S. Springer."Curing of Graphite Epoxy Composites," Air Force Materials Laboratory Report AFWAL-TR-83-4040, Wnght Patterson Air Force Base , Ohio (1983).
14.
Lee, W.I., M.F. Talbott, G.S. Springer and L.A. Berglund."Effect of Cooling Rate on the Crystallimty and Mechanical Properties of Thermoplastic Composites,"Journal of Reinforced Plastics and Composites, 6:2-12 (1987).
15.
Talbott, M.F. , G.S. Springer and L.A. Berglund."The Effects of Crystallimty on the Mechanical Properties of PEEK Polymer and Graphite Fiber Reinforced PEEK,"Journal of Composite Materials , 21(11).1057-1082 (1987).
16.
Downs, R.J. and L.A. Berglund."Apparatus for Preparing Thermoplastic Composites,"Journal of Reinforced Plastics and Composites , 6:89-99 (1987).
17.
Blundell, D.J. and B.N. Osborn."The Morphology of Poly(aryl-ether-etherketone),"Polymer, 24:953-958 (1983).
18.
Ozawa, T."Kinetics of Nonisothermal Crystallization,"Polymer , 12:150-158 (1971).
19.
Seferis, J.C. and C.N. Velisaris."Modeling-Processing-Structure Relationships of Polyetheretherketone (PEEK) Based Composites," in Materials for the Future, Society for the Advancement of Material and Process Engineering, pp. 1236-1252 (1986 ).
20.
Velisaris, C.N. and J.C. Seferis."Crystallization Kinetics of Polyetheretherketone (PEEK) Matrices,"Polymer Engineering and Science , 26:1574-1581 (1986 ).
21.
Blundell, D.J. , J.M. Chalmers, M.W. MacKenzie and W.F. Gaskin."Crystalline Morphology of the Matrix of PEEK-Carbon Fiber Aromatic Polymer Composites. I. Assessment of Crystallinity,"SAMPE Quarterly , 16:22-30 (1985).
22.
Blundell, D.J. and B.N. Osborn."Crystalline Morphology of the Matrix of PEEK-Carbon Fiber Aromatic Polymer Composites. II. Crystallization Behavior,"SAMPE Quarterly, 17:1-6 (1985).
23.
Cebe, P. and S.D. Hong."Crystallization Behaviour of Poly(ether-ether-ketone),"Polymer, 27:1183-1192 (1986 ).