Composites of boron nitride (BN) have been made by the chemical vapor deposition (CVD) of a BN matrix on a BN felt fiber substrate. Reactant gases were boron trifluoride and ammonia. The composites have a relatively high density (1.70 g/cm3), a crystallite size LC = 150 A and an interlayer spacing d002 = 3.35 A. Measurements of elastic modulus and thermal conductivity and expansion showed some anisotropy as a result of the preferred fiber orientation of the substrate.
Get full access to this article
View all access options for this article.
References
1.
C F.Powell, J.H.Oxley, J.M. Blocher, Jr., Vapor DepositionJohn Wiley & Sons, New York, 1966.
2.
R.S. Pease, Nature Vol. 165, (1950 ), p. 722.
3.
K. Niedenzu, J.W. Dawson, Boron Nitrogen Compounds, Academic Press, New York, 1965.
4.
Handbook of Chemistry and Physics, 49th edition, The Chemical Rubber Co., 1969.
5.
M. Basche, D. Schiff, "New Pyrolytic Boron Nitride," Materials in Design Engineering, Feb. 1964, p. 78.
6.
H O.Pierson, M.L. Lieberman, "The CVD of Carbon on Carbon Fibers," Sandia Laboratories Report73-0925, 1974. To be published in Carbon.
7.
R. Ohnsorg, "Boron Nitride Felt Development" Carborundum Co ., Sandia Contract, Document No. 16-8635, 1974.
8.
8. U.S. Patents 3,429,722, 3,620,780, 3,668,059.
9.
The Carborundum Co., Bulletin No. 301, "Boron Nitride Long-Staple Fiber."
10.
J.J. Gebhardt , "CVD Boron Nitride Infiltration of Fibrous Structures. Properties of Low Temperature Deposites," Proceedings of the 4th CVD Conference, 1973, Electrochemical Society Publication.
11.
S R.Steele, J.Pappis, H.Schilling, L.Hagen, "CVD Materials for Electron Tubes" Final Report, RDTR ECON 01343F, Raytheon Co., Waltham, Mass.
12.
P C.Li, A.J.Capriulo, M.P. Lepie, "CVD of Boron Nitride," Proceedings of the OSU Randome Symposium, 1964.
13.
R H.Dungan, J.A. Gilbert, "Chemical Vapor Deposition of Boron Nitride," Sandia Laboratories Report SC TM 70-919, Apr. 1971 and unpublished data (1973 ).
14.
W J.Parker, R.J.Jenkins, C.P. Butler and G.L. Abbott, J. Appl. Phys. Vol. 32, ( 1961), p. 1679.
15.
Union Carbide Corp., Bulletin on HD 0092 Boron Nitride No. 442-209 DH.
16.
K. E. Lawson, Sandia Laboratories, private communication.