Owing to the unique properties of 2D graphene derivatives (2D GDs), their composites with other materials possess superior characteristics over other existing materials in the universe. Accordingly, 2D GDs-based composites have emerged as leading materials for substantial advancements of various technological industries such as energy, electronics, sensors, catalysis, environmental remediation, biomedical and structural sectors. Recently, numerous research innovations, have been developed for reliable production of 2D GDs-based composites with high quality, plentiful availability and competitive costs. The overall performance of 2D GDs-based composites is controlled by three main issues. First, the synthesis strategy of GD sheets, which determines the characteristic properties, quantity and cost of the 2D GD product. Second, the surface functionalization of GD sheets, which enhances the compatibility and chemical affinity between GD sheets and other materials within the composites. Finally, the processing method of the composite that strongly affects its microstructure, properties, productivity and cost. This makes such three processes, matters of great concern when designing 2D GDs-based composites for specific application. In this article, the structure, properties, synthesis and surface functionalization of 2D GDs are reviewed. Then, the review article discusses the research developments of 2D GDs-based composites with inorganic materials and polymers, in terms of preparation, properties and applications. Particular focus is placed on Green and/or clean production technologies. The recent research interest in the 2D GDs/multicomponent hybrid composites, with their distinctive multifunctional properties, is highlighted. Also, the new implemented applications of 2D GDs-based composites from 2021, are pointed out, as well as the currently running practical projects, which are proposing innovative futural applications prospects.
NovoselovKSGeimAKMorozovSV, et al.Electric field effect in atomically thin carbon films. Science2004; 306(5696): 666–669.
2.
GeimAKNovoselovKS. The rise of graphene. Nat Mater2007; 6(3): 183–191.
3.
WallacePR. The band theory of graphite. Phys Rev1947; 71(9): 622–634.
4.
RandviirEPBrownsonDACBanksCE. A decade of graphene research: production, applications and outlook. Mater Today2014; 17(9): 426–432.
5.
StollerMDParkSZhuY, et al.Graphene-based Ultracapacitors. Nano Lett2008; 8: 3498–3502.
6.
BolotinKISikesKJJiangZ, et al.Ultrahigh electron mobility in suspended graphene. Solid State Commun2008; 146(9-10): 351–355.
7.
NovoselovKSGeimAKMorozovSV, et al.Two-dimensional gas of massless Dirac fermions in graphene. Nature2005; 438: 197–200.
8.
ZhangYBTanYWStormerHL, et al.Experimental observation of the quantum Hall effect and Berry’s phase in graphene. Nature2005; 438: 201–204.
9.
NovoselovKSJiangZZhangY, et al.Room-temperature quantum Hall effect in graphene. Science2007; 315: 1379.
10.
BalandinAAGhoshSBaoW, et al.Superior Thermal Conductivity of Single-Layer Graphene. Nano Lett2008; 8: 902–907.
11.
NairRRBlakePGrigorenkoAN, et al.Fine structure constant defines visual transparency of graphene. Science2008; 320: 1308.
12.
LeeCWeiXKysarJW, et al.Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science2008; 321: 385–388.
13.
DengDPanXYuL, et al.Toward N-Doped Graphene via Solvothermal Synthesis. Chem Mater2011; 23: 1188–1193.
14.
SunHLiuSZhouG, et al.Reduced Graphene Oxide for Catalytic Oxidation of Aqueous Organic Pollutants. ACS Appl Mater Interfaces2012; 4: 5466–5471.
15.
WangZhiMüllenXLK. Transparent, conductive graphene electrodes for dye- sensitized solar cells. Nano Lett2008; 8(1): 323–327.
16.
YooJJBalakrishnanKHuangJ, et al.Ultrathin planar graphene supercapacitors. Nano Lett2011; 11(4): 1423–1427.
17.
GhanyNAAElsherifSAHandalHT. Revolution of Graphene for different applications: State-of-the-art. Surface Interfac2017; 9: 93–106.
18.
AdelMEl-MaghrabyAEl-ShazlyO, et al.Synthesis of Few-layer Graphene-like Nanosheets from Glucose: New Facile Approach for Graphene-like Nanosheets Large- Scale Production. J Mater Res2016; 31(4): 455–467.
19.
LiFLongLWengY. A review on the contemporary development of composite materials comprising graphene/graphene derivatives. Adv Mater Sci Eng2020; 2020: 7915641–7915716.
20.
HuangXQiXBoeyF, et al.Graphene-based Composites. Chem Soc Rev2012; 41(2): 666–686.
21.
IqbalAASakibNIqbalAKMP, et al.Graphene-based nanocomposites and their fabrication, mechanical properties and applications. Materialia2020; 12: 100815.
22.
MohanVBLauK-THuiD, et al.Graphene-based materials and their composites: A review on production, applications and product limitations. Composites Part B2018; 142: 200–220.
23.
YinZWuSZhouX, et al.Electrochemical deposition of ZnO nanorods on transparent reduced graphene oxide electrodes for hybrid solar cells. Small2010; 6(2): 307–312.
24.
ZhouXHuangXQiX, et al.In Situ Synthesis of Metal Nanoparticles on Single- Layer Graphene Oxide and Reduced Graphene Oxide Surfaces. J Phys Chem C2009; 113(25): 10842–10846.
25.
ShiWZhuJSimDH, et al.Achieving high specific charge capacitances in Fe3O4/reduced graphene oxide nanocomposites. J Mater Chem2011; 21(10): 3422–3427.
26.
ZhuJZhuTZhouX, et al.Facile synthesis of metal oxide/reduced graphene oxide hybrids with high lithium storage capacity and stable cyclability. Nanoscale2011; 3: 1084–1089.
27.
AhmadIIslamMAbdoHS, et al.Toughening mechanisms and mechanical properties of graphene nanosheet-reinforced alumina. Mater Des2015; 88: 1234–1243.
28.
KumarASharmaKDixitAR. A review of the mechanical and thermal properties of graphene and its hybrid polymer nanocomposites for structural applications. J Mater Sci2019; 54(8): 5992–6026.
29.
YangHFZhangQXShanCS, et al.Stable, conductive supramolecular composite of graphene sheets with conjugated polyelectrolyte. Langmuir2010; 26(9): 6708–6712.
30.
RamanathanTAbdalaAAStankovichS, et al.Functionalized graphene sheets for polymer nanocomposites. Nat Nanotechnol2008; 3(6): 327–331.
31.
TungVCChenL-MAllenMJ, et al.Low-temperature solution processing of graphene-carbon nanotube hybrid materials for high-performance transparent conductors. Nano Lett2009; 9(5): 1949–1955.
32.
FanZYanJZhiL, et al.A three dimensional carbon nanotube/graphene sandwich and its application as electrode in supercapacitors. Adv Mater2010; 22(33): 3723–3728.
33.
YooEKimJHosonoE, et al.Large Reversible Li Storage of Graphene Nanosheet Families for Use in Rechargeable Lithium Ion Batteries. Nano Lett2008; 8(8): 2277–2282.
34.
WangYLiZHuD, et al.Aptamer/Graphene Oxid Nanocomplex for in-situ Molecular Probing in Living Cells. J Am Chem Soc2010; 132(27): 9274–9276.
35.
HanTHLeeWJLeeDH, et al.Peptide/Graphene Hybrid Assembly into Core/Shell Nanowires. Adv Mater2010; 22(18): 2060–2064.
36.
WangSGohBMMangaKK, et al.Graphene as atomic template and structural scaffold in the synthesis of graphene−organic hybrid wire with photovoltaic properties. ACS Nano2010; 4: 6180–6186.
37.
BiancoAChengH-MEnokiT, et al.All in the graphene family – A recommended nomenclature for two-dimensional carbon materials nomenclature for two-dimensional carbon materials. Carbon2013; 65: 1–6.
38.
DuplockEJSchefflerMLindanPJD. Hallmark of perfect graphene. Phys Rev Lett2004; 92(22): 225502.
39.
PatiSKEnokiTR RaoCN. Graphene and its fascinating attributes. Singapore: World Scientific Publishing Co., 2011.
40.
AlwarappanSKumarA. Graphene-based materials: science and technology. Florida, USA: CRC Press: Taylor and Francis Group, 2013.
41.
ChoiWLeeJ-W. Graphene: synthesis and applications. Florida, USA: CRC Press: Taylor and Francis Group, 2013.
42.
VinayanBP. Heteroatom Doped Graphene Based Hybrid Materials for Hydrogen Energy Conversion. In: Recent Advances in Graphene Research. InTech Open, 2016, pp. 178–194. Chapter 8.
43.
AnwarAMohammedBSWahabMA, et al.Enhanced properties of cementitious composite tailored with graphene oxide nanomaterial - A review. Developments in the Built Environment2020; 1: 100002.
44.
RamezaniMAlibolandiMNejabatM, et al.Graphene-Based Hybrid Nanomaterials for Biomedical Applications. In: NurunnabiMMcCarthyJR (eds). Biomedical Applications of Graphene and 2D Nanomaterials. Amsterdam, The Netherlands: Elsevier, 2019, pp. 119–141. Chapter 6.
45.
DreyerDRParkSBielawskiCW, et al.The chemistry of graphene oxide. Chem Soc Rev2010; 39: 228–240.
46.
ZhuYMuraliSCaiW, et al.Graphene and graphene oxide: synthesis, properties, and applications. Adv Mater2010; 22(35): 3906–3924.
47.
PerrozziFPreziosoSOttavianoL. Graphene oxide: from fundamentals to applications. J Phys: Condens Matter2015; 27: 013002.
48.
PeiSChengH-M. The Reduction of graphene oxide. Carbon2012; 50: 3210–3228.
49.
StylianakisMMViskadourosGPolyzoidisC, et al.Updating the Role of Reduced Graphene Oxide Ink on Field Emission Devices in Synergy with Charge Transfer Materials. Nanomaterials2019; 9: 137.
50.
McAllisterMJLiJ-LAdamsonDH, et al.Single sheet functionalized graphene by oxidation and thermal expansion of graphite. Chem Mater2007; 19: 4396–4404.
51.
KimKSZhaoYJangH, et al.Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature2009; 457: 706–710.
52.
ZandiatashbarALeeG-HAnSJ, et al.Effect of defects on the intrinsic strength and stiffness of graphene. Nat Commun2014; 5: 3186.
53.
FrankIWTanenbaumDMvan der ZandeAM, et al.Mechanical properties of suspended graphene sheets. J Vac Sci Technol B2007; 25(6): 2558–2561.
54.
MinKAluruN. Mechanical properties of graphene under shear deformation. Appl Phys Lett2011; 98(1): 013113.
55.
Ultimate tensile strength - Wikipedia(Last accessed June 2023).
56.
DikinDAStankovichSZimneyEJ, et al.Preparation and characterization of graphene oxide paper. Nature2007; 448: 457–460.
57.
XuZSunHZhaoX, et al.Ultrastrong fibers assembled from giant graphene oxide sheets. Adv Mater2013; 25(2): 188–193.
58.
SukJWPinerRDAnJ, et al.Mechanical properties of monolayer graphene oxide. ACS Nano2010; 4(11): 6557–6564.
59.
Gomez-NavarroCBurghardMKernK. Elastic properties of chemically derived single graphene sheets. Nano Lett2008; 8(7): 2045–2049.
60.
Graphene: properties, production and applications - Matmatch(Last accessed June 2023).
61.
LimSParkHYamamotoG, et al.Measurements of the Electrical Conductivity of Monolayer Graphene Flakes Using Conductive Atomic Force Microscopy. Nanomaterials2021; 11(10): 2575.
62.
Graphene - energy Education(Last accessed June 2023).
YanZNikaDLBalandinAA. Thermal properties of graphene and few-layer graphene: applications in electronics. IET Circuits, Devices Syst2015; 9(1): 4–12.
74.
KumarPShahzadFYuS, et al.Large-area reduced graphene oxide thin film with excellent thermal conductivity and electromagnetic interference shielding effectiveness. Carbon2015; 94: 494–500.
75.
ShenBZhaiWZhengW. Ultrathin flexible graphene film: an excellent thermal conducting material with efficient EMI shielding. Adv Funct Mater2014; 24(28): 4542–4548.
76.
PintoAMGonçalvesICMagalhãesFD. Graphene-based materials biocompatibility: a review. Colloids Surfaces B Biointerfaces2013; 111: 188–202.
77.
LiaoCLiYTjongSC. Graphene Nanomaterials: Synthesis, Biocompatibility, and Cytotoxicity. Int J Mol Sci2018; 19: 3564.
78.
KarSSahaSDuttaS, et al.A Comprehensive Review over Green Synthesis of Graphene. International Journal of Research and Scientific Innovation2018; 5(7): 1–12.
79.
LiRGuineyLMChangCH, et al.Surface oxidation of graphene oxide determines membrane damage, lipid peroxidation, and cytotoxicity in macrophages in a pulmonary toxicity model. ACS Nano2018; 12: 1390–1402.
80.
WangKRuanJSongH, et al.Biocompatibility of Graphene Oxide. Nanoscale Res Lett2010; 6: 8.
81.
SasidharanAPanchakarlaLSChandranP, et al.Differential nano-bio interactions and toxicity effects of pristine versus functionalized graphene. Nanoscale2011; 3: 2461–2464.
82.
MendesRGKochBBachmatiukA, et al.A size dependent evaluation of the cytotoxicity and uptake of nanographene oxide. J Mater Chem B2015; 3(12): 2522–2529.
83.
LiaoKHLinYSMacoskoCW, et al.Cytotoxicity of graphene oxide and graphene in human erythrocytes and skin fibroblasts. ACS Appl Mater Interfaces2011; 3: 2607–2615.
84.
ChengCNieSLiS, et al.Biopolymer functionalized reduced graphene oxide with enhanced biocompatibility via mussel inspired coatings/anchors. J Mater Chem B2013; 1(3): 265–275.
85.
YangKWanJZhangS, et al.In vivo pharmacokinetics, long-term biodistribution, and toxicology of PEGylated graphene in mice. ACS Nano2011; 5: 516–522.
86.
EdwardsRSColemanKS. Graphene synthesis: relationship to applications. Nanoscale2013; 5(1): 38–51.
87.
SahuDSutarHSenapatiP, et al.Graphene, Graphene-Derivatives and Composites: Fundamentals, Synthesis Approaches to Applications. J Compos Sci2021; 5: 181.
88.
WangXYNaritaAMullenK. Precision synthesis versus bulk-scale fabrication of graphenes. Nat Rev Chem2017; 2: 0100.
89.
LiangXChangASPZhangY, et al.Electrostatic force assisted exfoliation of pre- patterned few-layer graphenes into device sites. Nano Lett2009; 9(1): 919.
90.
ShuklaAKumarRMazherJ, et al.Graphene made easy: High quality, large-area samples. Solid State Commun2009; 149: 718–721.
91.
YangSLoheMRMüllenK, et al.New-generation graphene from electrochemical approaches: production and applications. Adv Mater2016; 28: 6213–6221.
92.
YangSBrüllerSWuZ-S, et al.Organic radical-assisted electrochemical exfoliation for the scalable production of high-quality graphene. J Am Chem Soc2015; 137: 13927–13932.
93.
YangSRicciardulliAGLiuS, et al.Ultrafast delamination of graphite into high- quality graphene using alternating currents. Angew Chem Int Ed Engl2017; 56: 6669–6675.
94.
HernandezYNicolosiVLotyaM, et al.High-yield production of graphene by liquid-phase exfoliation of graphite. Nat Nanotechnol2008; 3: 563–568.
95.
NovoselovKSFal′koVIColomboL, et al.A roadmap for graphene. Nature2012; 490: 192–200.
96.
NiuLColemanJNZhangH, et al.Production of two-dimensional nanomaterials via liquid-based direct exfoliation. Small2016; 12(3): 272–293.
97.
HernandezYLotyaMRickardD, et al.Measurement of multicomponent solubility parameters for graphene facilitates solvent discovery. Langmuir2010; 26(5): 3208–3213.
ParkSRuoffRS. Chemical methods for the production of graphenes. Nat Nanotechnol2009; 4: 217–224.
100.
WidenkvistEBoukhvalovDWRubinoS, et al.Mild sonochemical exfoliation of bromine-intercalated graphite: a new route towards graphene. J Phys D Appl Phys2009; 42(11): 112003.
101.
LiNWangZShiZ. Synthesis of Graphenes with Arc-Discharge Method. In: MikhailovS (ed). Physics and Applications of Graphene – Experiments. InTech Open, 2011, pp. 23–36. Chapter 2.
102.
KaneSFBarryAHChérifSM. Bone Tumors: Multiple Myeloma. FP Essent2020; 493: 30–35.
103.
WangZLiNShiZ, et al.Low-cost and large-scale synthesis of graphene nanosheets by arc discharge in air. Nanotechnology2010; 21: 175602.
104.
SubrahmanyamKSPanchakarlaLSGovindarajA, et al.Simple method of preparing graphene flakes by an arc-discharge method. J Phys Chem C2009; 113(11): 4257–4259.
105.
WuXLiuYYangH, et al.Large-scale synthesis of high-quality graphene sheets by an improved alternating current arc-discharge method. RSC Adv2016; 6: 93119–93124.
106.
BrodieBC. On the atomic weight of graphite. Philosphical Transections of the Royal Society Lond1859; 149: 249–259.
107.
StaudenmaierL. Verfahren zur Darstellung der Graphitsäure. Ber Dtsch Chem Ges1898; 31(2): 1481–1487.
108.
HummersWOffemanRE. Preparation of graphitic oxide. J Am Chem Soc1958; 80(6): 1339.
109.
MaLWangJDingF. Recent progress and challenges in graphene nanoribbon synthesis. ChemPhysChem2013; 14(1): 47–54.
110.
Cano-MárquezAGRodríguez-MacíasFJCampos-DelgadoJ, et al.Ex-MWNTs: graphene sheets and ribbons produced by lithium intercalation and exfoliation of carbon nanotubes. Nano Lett2009; 9(4): 1527–1533.
111.
WangHWangYHuZ, et al.Cutting and unzipping multiwalled carbon nanotubes into curved graphene nanosheets and their enhanced supercapacitor performance. ACS Appl Mater Interfaces2012; 4(12): 6827–6834.
112.
AkhavanOGhaderiE. Differentiation of human neural stem cells into neural networks on graphene nanogrids. J Mater Chem B2013; 1(45): 6291–6301.
113.
SilvaAAPinheiroRARodriguesAC, et al.Graphene sheets produced by carbon nanotubes unzipping and their performance as supercapacitor. Appl Surf Sci2018; 446: 201–208.
AniMHKamarudinRamlanMAAHIsmailE, et al.A critical review on the contributions of chemical and physical factors toward the nucleation and growth of large-area graphene. J Mater Sci2018; 53: 7095–7111.
116.
LinLLiJRenH, et al.Surface engineering of copper foils for growing centimeter- sized single-crystalline graphene. ACS Nano2016; 10(2): 2922–2929.
117.
XuXZhangZDongJ, et al.Ultrafast epitaxial growth of metre-sized single-crystal graphene on industrial Cu foil. Sci Bull2017; 62: 1074–1080.
118.
WuTZhangXYuanQ, et al.Fast growth of inch-sized single-crystalline graphene from a controlled single nucleus on Cu-Ni alloys. Nat Mater2016; 15(1): 43–47.
119.
KimKSZhaoYJangH, et al.Large-scale pattern growth of graphene films for stretchable transparent Electrodes. Nature2009; 457: 706–710.
120.
NorimatsuWKusunokiM. Epitaxial graphene on SiC {0001}: Advances and perspectives. Phys Chem Chem Phys2014; 16: 3501–3511.
121.
BriggsNGebeyehuZMVeraA, et al.Epitaxial graphene/silicon carbide intercalation: a minireview on graphene modulation and unique 2D materials. Nanoscale2019; 11(33): 15440–15447.
122.
El EssawyNAAliSMFaragHA, et al.Green synthesis of graphene from recycled PET bottle wastes for use in the adsorption of dyes in aqueous solution. Ecotoxicol Environ Saf2017; 145: 57–68.
123.
ChoucairMThordarsonPStrideJA. Gram-scale production of graphene based on solvothermal synthesis and sonication. Nat Nanotechnol2009; 4(1): 30–33.
124.
PrekodravacJRKepicDPColmenaresJC, et al.A comprehensive review on selected graphene synthesis methods: from electrochemical exfoliation through rapid thermal annealing towards biomass pyrolysis. J Mater Chem C Mater2021; 9: 6722–6748.
125.
TangLLiXJiR, et al.Bottom-up synthesis of large-scale graphene oxide nanosheets. J Mater Chem2012; 22: 5676–5683.
126.
ZeitounMAdelMAbulfotouhF, et al.Thermophysical properties enhancement of octadecane using reduced graphene oxide and graphene oxide nanoplatelets. J Energy Storage2021; 38: 102512–102521.
127.
AdelMEl-MaghrabyAEl-ShazlyO, et al.Production of reduced graphene oxide from glucose via hydrothermal route: the crucial role of the evolved byproduct gases in deoxygenating the graphitic structure. J Mater Res2021; 36: 896–905.
128.
MohamedMAAElessawyNACarrasco-MarínF, et al.A novel one-pot facile economic approach for the mass synthesis of exfoliated multilayered nitrogen-doped graphene-like nanosheets: new insights into the mechanistic study. Phys Chem Chem Phys2019; 21: 13611–13622.
129.
SinghDKIyerPKGiriPK. Improved Chemical Synthesis of Graphene Using a Safer Solvothermal Route. Int J Nanosci2011; 10: 39–42.
130.
IsmailZ. Green Reduction of Graphene Oxide by plant extracts: A short review. Ceram Int2019; 45(18): 23857–23868.
131.
ManchalaSTandavaVJampaiahD, et al.A Novel Strategy for Sustainable Synthesis of Soluble-Graphene by a Herb Delphinium denudatum Root Extract for Use as Light- Weight Supercapacitors. ChemistrySelect2020; 5: 2701–2709.
132.
BoZShuaiXMaoS, et al.Green preparation of reduced graphene oxide for sensing and energy storage applications. Sci Rep2014; 4: 4684.
133.
MoosaAAJaafarJN. Green Reduction of Graphene Oxide Using Tea Leaves Extract with Applications to Lead Ions Removal from Water. J Nanosci Nanotechnol2017; 7(2): 38–47.
134.
AkhavanOGhaderiEAghayeeS, et al.The use of a glucose-reduced graphene oxide suspension for photothermal cancer therapy. J Mater Chem2012; 22(27): 13773–13781.
135.
HaghighiBTabriziMA. Green-synthesis of reduced graphene oxide nanosheets using rose water and a survey on their characteristics and applications. RSC Adv2013; 3(32): 13365–13371.
136.
HatamieSAkhavanOSadrnezhaadSK, et al.Curcumin-reduced graphene oxide sheets and their effects on human breast cancer cells. Mater Sci Eng C Mater Biol Appl2015; 55: 482–489.
137.
El-BrolossyTAAbdallahTTalaatH. Pulsed versus continuous-wave Laser deoxygenation of graphene oxide suspensions. IOP Conf Ser Mater Sci Eng2020; 956: 012009.
138.
LiuCHuG. Highly efficient reduction of graphene oxide by sub/supercritical water and their application for thermal interface materials. Appl Therm Eng2015; 90: 193–198.
139.
AkhavanOAzimiradRGholizadehHT, et al.Hydrogen-rich water for green reduction of graphene oxide suspensions. Int J Hydrogen Energy2015; 40(16): 5553–5560.
140.
RuanGSunZPengZ, et al.Growth of Graphene from Food, Insects, and Waste. ACS Nano2011; 5: 7601–7607.
141.
Tajul ArifinNFYusofNIsmailAF, et al.Graphene from waste and bioprecursors synthesis method and its application: A review. Malays J Fundam Appl Sci2020; 16(3): 342–350.
142.
KhanMShaikMRAdilSF, et al.Facile synthesis of Pd@graphene nanocomposites with enhanced catalytic activity towards Suzuki coupling reaction. Sci Rep2020; 10(1): 11728.
143.
LucherelliMARayaJEdelthalhammerK, et al.A Straightforward Approach to Multifunctional Graphene. Chemistry (Basel)2019; 25(57): 13218–13223.
144.
ImaniRPrakashSValiH, et al.Microencapsulated Multifunctionalized Graphene Oxide Equipped with Chloroquine for Efficient and Sustained siRNA Delivery. BioMed Res Int2022; 2022: 5866361.
AdilSFAshrafMKhanM, et al.Advances in Graphene/Inorganic Nanoparticle Composites for Catalytic Applications Composites for Catalytic Applications. Chem Rec2022; 22: e202100274.
147.
ShaoPSunKZhuP, et al.Enhancing the Strengthening Effect of Graphene-Nanoplates in Al matrix composites by heterogeneous matrix design. Nanomaterials2022; 12: 1833.
148.
Morales-FlórezVDomínguez-RodríguezA. Mechanical properties of ceramics reinforced with allotropic forms of carbon. Prog Mater Sci2022; 128: 100966.
149.
LiuGQiMZhangY, et al.Nanocomposites of gold nanoparticles and graphene oxide towards an stable label-free electrochemical immunosensor for detection of cardiac marker troponin-I. Anal Chim Acta2016; 909: 1–8.
150.
ZhouXYuanCQinD, et al.Pd Nanoparticles on Functionalized Graphene for Excellent Detection of Nitro aromatic Compounds. Electrochim Acta2014; 119: 243–250.
151.
YinZChenJQinZ, et al.Superior thermal conductivity of layered RGO/Cu composites by multi-step electrodeposition. J Alloys Compd2022; 918: 165634.
152.
MahyariMLaeiniMSShaabaniA, et al.Gold nanoparticles supported on three- dimensional nitrogen-doped graphene: an efficient catalyst for selective aerobic oxidation of hydrocarbons under mild conditions. Appl Organomet Chem2015; 29: 456–461.
153.
OuyangLYaoLZhouT, et al.Accurate SERS detection of malachite green in aquatic products on basis of graphene wrapped flexible sensor. Anal Chim Acta2018; 1027: 83–91.
154.
AkhtarAJ. Graphene-Based Materials for Supercapacitor. In: TashimaDSamantaraAK (eds). Supercapacitors for next generation. InTech Open, 2021. Chapter 4.
155.
Uma ShankarVSenthil KumarPGovindarajanD, et al.Ruthenium dioxide anchored on reduced graphene oxide nanocomposite for 1.2 V symmetric supercapacitor devices. Sustain Energy Technol Assessments2022; 53: 102444.
156.
AssalMEShaikMRKuniyilM, et al.A highly reduced graphene oxide/ZrOx- MnCO3 or –Mn2O3 nanocomposite as an efficient catalyst for selective aerial oxidation of benzylic alcohols. RSC Adv2017; 7: 55336–55349.
157.
LiJLiFYangQ, et al.Tailoring collaborative N–O functionalities of graphene oxide for enhanced selective oxidation of benzyl alcohol. Carbon2021; 182: 715–724.
158.
LiZLiuYGuoD, et al.Room-temperature synthesis of CuO/reduced graphene oxide nanohybrids for high-performance NO2 gas sensor. Sensor Actuator B Chem2018; 271: 306–310.
159.
TobaldiDMDvoranováDLajaunieL, et al.Graphene-TiO2 hybrids for photocatalytic aided removal of VOCs and nitrogen oxides from outdoor environment. Chemical Engineering journal2021; 405: 126651.
160.
Abo El-YazeedWSEl-HakamSASalahAA, et al.Fabrication and characterization of reduced graphene-BiVO4 nanocomposites for enhancing visible light photocatalytic and antibacterial activity. J Photochem Photobiol Chem2021; 417: 113362.
161.
López-PerníaCGallardo-LópezÁMorales-RodríguezA, et al.Graphene nanoplatelets for electrically conductive 3YTZP composites densified by pressureless sintering. J Eur Ceram Soc2019; 39(14): 4435–4439.
162.
WangYHeZYangJ, et al.Effects of graphene dispersion in hot pressing UO2- graphene nanosheet ceramic matrix composites. Ceram Int2022; 48(20): 30779–30787.
163.
JeonI-YBaekJ-B. Nanocomposites Derived from Polymers and Inorganic Nanoparticles. Materials2010; 3: 3654–3674.
164.
AdelMEl-ShazlyOEl-WahidyEF, et al.Eco-friendly Produced Lightweight Structural Graphene/Polyamide 12 nanocomposite: mechanical performance and the controlling microstructural mechanisms. Polym Eng Sci2018; 58(7): 1201–1212.
165.
KumarPYuSShahzadF, et al.Ultrahigh electrically and thermally conductive self-aligned graphene/polymer composites using large-area reduced graphene oxides. Carbon2016; 101: 120–128.
166.
TotoELaurenziSSantonicolaMG. Recent Trends in Graphene/Polymer Nanocomposites for Sensing Devices: Synthesis and Applications in Environmental and Human Health Monitoring. Polymers2022; 14: 1030.
167.
Thermoplastics Vs. Thermoset materials. Plastics manufacturing (advancedplastiform.com). (Last accessed June 2023).
168.
Thermoset vs Thermoplastic. Definition and their Differences (rapiddirect.com ((Last accessed June 2023).
169.
Chinna ReddyPChaitanyaKSCMadhusudan RaoY. A review on bioadhesive buccal drug delivery systems: current status of formulation and evaluation methods. Daru2011; 19(6): 385–403.
WangJSongFDingY, et al.The incorporation of graphene to enhance mechanical properties of polypropylene self-reinforced polymer composites. Mater Des2020; 195: 109073.
174.
WangW-YMaXShaoY-W, et al.Flexible, multifunctional, and thermally conductive nylon/graphene nanoplatelet composite papers with excellent EMI shielding performance, improved hydrophobicity and flame resistance. J Mater Chem A Mater2021; 9: 5033–5044.
175.
NieH-JZhangY-JYangY-R, et al.Investigation on impact performance and Dimensional stability of polypropylene composites in cryogenic environment. J Appl Polym Sci2021; 138: e50743.
176.
SabetMSoleimaniH. Influence of graphene oxide on the mechanical, thermal and roughness of polyethersulphone. Bull Mater Sci2022; 45: 42.
177.
ShiXPanYWangY, et al.Synergistic effects of graphene and ammonium polyphosphate modified with vinyltrimethoxysilane on the properties of high-impact polystyrene composites. Polymers2021; 13: 881.
OjijoVRaySS. Processing of Thermoset-Based Nanocomposites. In: RaySS (ed). Processing of Polymer-based Nanocomposites. Processing-Structure-Property-Performance Relationships. Cham, Switzerland: Springer Nature, 2018, pp. 107–131. Chapter 4.
180.
NguyenQTNgoTDTranP, et al.Influences of clay and manufacturing on fire resistance of organoclay/thermoset nanocomposites. Composites Part A2015; 74: 26–37.
181.
ZhangN. Largely improved mechanical properties of polyurethane nanocomposites via in situ polymerization with low loading of graphene oxide. J Macromol Sci, Part B: Phys2022; 61(4-5): 571–583.
182.
OunAManaloAAlajarmehO, et al.Influence of elevated temperature on the mechanical properties of hybrid flax-fiber-epoxy composites incorporating graphene. Polymers2022; 14: 1841.
183.
SerenariFMadineheiMMoghimianN, et al.Development of reinforced polyester/graphene nanocomposite showing tailored electrical conductivity. Polymers2020; 12: 2358.
184.
JiangGChenLJiangS, et al.Establishment of highly effective flame-retardant unsaturated polyester resin system based on multiple strategies. Adv Polym Technol2018; 37(7): 2674–2686.
185.
JiaoDWangJYuW, et al.Biocompatible reduced graphene oxide stimulated bmscs induce acceleration of bone remodeling and orthodontic tooth movement through promotion on osteoclastogenesis and angiogenesis. Bioact Mater2022; 15: 409–425.
186.
MolaparastMMalekinejadHRahimiM, et al.Biocompatible functionalized graphene nanosheet for delivery of doxorubicin to breast cancer cells. J Drug Deliv Sci Technol2022; 70: 103234.
187.
ZhaoZLiuZZhongQ, et al.In situ synthesis of trifluoroacetic acid-doped polyaniline/reduced graphene oxide composites for high-performance all-solid- state supercapacitors. ACS Appl Energy Mater2020; 3(9): 8774–8785.
188.
KongXZhangLLiuB, et al.Graphene/Si Schottky solar cells: a review of recent advances and prospects. RSC Adv2019; 9(2): 863–877.
189.
TaleBNemadeKRTekadePV. Graphene based nano-composites for efficient energy conversion and storage in Solar cells and Supercapacitors : A Review. Polymer-Plastics Technology and Materials2021; 60(7): 784–797.
190.
BalqisFPrakosoBHawariNH, et al.Recent development of polyaniline/graphene composite electrodes for flexible supercapacitor devices. ChemNanoMat2022; 8(7): e202200151.
191.
EsteghamatAAkhavanO. Graphene as the ultra-transparent conductive layer in developing the nanotechnology-based flexible smart touchscreens. Microelectron Eng2023; 267-268: 111899.
192.
GuptaP. Polymer-graphene composites as sensing materials. In: RahamanMNayakLHusseinIA, et al. (eds). Polymer Nanocomposites Containing Graphene. Preparation, Properties and Applications. Woodhead Publishing, 2022, pp. 401–424. Chapter 15.
193.
NegahdariRRafieeEKordrostamiZA. Sensitive biosensor based on Plasmonic- graphene configuration for detection of COVID-19 Virus. Plasmonics, 2023. In press.
194.
WangYZhangSXuT, et al.Ultra-sensitive and ultra-fast detection of whole unlabeled living cancer cell responses to paclitaxel with a graphene-based biosensor. Sensor Actuator B Chem2018; 263: 417–425.
195.
WeiWYiYSongJ, et al.Tunable graphene/nitrocellulose temperature alarm sensors. ACS Appl Mater Interfaces2022; 14(11): 13790–13800.
196.
OpreaMVoicuSI. Cellulose Composites with Graphene for Tissue Engineering Applications. Materials2020; 13: 5347.
197.
TabatabaeeSBaheiraeiNSalehniaM. Fabrication and characterization of PHEMA–gelatin scaffold enriched with graphene oxide for bone tissue engineering. J Orthop Surg Res2022; 17: 216.
198.
Adibi-MotlaghBHashemiEAkhavanO, et al.Immobilization of modular peptides on graphene cocktail for differentiation of human mesenchymal stem cells to hepatic- like cells. Front Chem2022; 10: 943003.
199.
AkhavanOGhaderiE. Graphene nanomesh promises extremely efficient in vivo photothermal therapy. Small2013; 9: 3593–3601.
200.
LebepeTCOluwafemiOS. Thermal and medium stability study of polyvidone- modified graphene oxide-coated gold nanorods with high photothermal efficiency. Nanomaterials2022; 12(19): 3382.
201.
ZhangXKongHYangG, et al.Graphene-Based functional hybrid membranes for antimicrobial applications: a review. Appl Sci2022; 12: 4834.
202.
ZhangPGuoZChenC, et al.Uncertainties in the antibacterial mechanisms of graphene family materials. Nano Today2022; 43: 101436.
203.
JannesariMAkhavanOMadaah HosseiniHR, et al.Graphene/CuO2 Nanoshuttles with Controllable Release of Oxygen Nanobubbles Promoting Interruption of Bacterial Respiration. ACS Appl Mater Interfaces2020; 12(32): 35813–35825.
204.
EbrahimiMAsadiMAkhavanO. Graphene-based nanomaterials in fighting the most challenging viruses and immunogenic disorders. ACS Biomater Sci Eng2022; 8(1): 54–81.
205.
KukobatRSakaiMTanakaH, et al.Ultrapermeable 2D-channeled graphene- wrapped zeolite molecular sieving membranes for hydrogen separation. Sci Adv2022; 8: eabl3521.
206.
VoicuSIThakurVK. Graphene-based composite membranes for nanofiltration: performances and future perspectives. Emergent Mater2022; 5: 1429–1441.
207.
GoswamiMYadavAKChauhanV, et al.Facile development of graphene-based air filters mounted on a 3D printed mask for COVID-19. J Sci: Advanced Materials and Devices2021; 6(3): 407–414.
208.
ZhangXFanZXuW, et al.Thin film composite nanofiltration membrane with nanocluster structure mediated by graphene oxide/metal-polyphenol nanonetwork scaffold interlayer. J Membr Sci2023; 669: 121330.
209.
NgZCLauWJLaiGS, et al.Facile fabrication of polyethyleneimine interlayer-assisted graphene oxide incorporated reverse osmosis membranes for water desalination. Desalination2022; 526: 115502.
210.
AbdelhamidAEEl-SayedAAKhalilAM. Polysulfone nanofiltration membranes enriched with functionalized graphene oxide for dye removal from wastewater. J Polym Eng2020; 40(10): 833–841.
211.
LiZZhangZFeiM-e., et al.Upcycling waste mask PP microfibers in portland cement paste: Surface treatment by graphene oxide. Mater Lett2022; 318: 132238.
212.
CierpiszMMcPhedranJHeY, et al.Characterization of graphene-filled fluoropolymer coatings for condensing heat exchangers. J Compos Mater2021; 55(29): 4305–4320.
213.
DashtkarAJohansenNF-JJrLM, et al.Graphene/sol–gel modified polyurethane coating for wind turbine blade leading edge protection: Properties and performance. Polym Polym Compos2022; 30: 1–18.
214.
AkhavanOSaadatiMJannesariM. Graphene jet nanomotors in remote controllable self-propulsion swimmers in pure water. Nano Lett2016; 16(9): 5619–5630.
215.
ErgünerAÖzkanRKocaK, et al.Improvement of Mechanical Behaviour of Wind Turbine Blade using Nanofluid-Graphene and/or Glass Fiber in Epoxy Resin. Sigma J Eng Nat Sci2022; 39(1): 58–69.
216.
SunCevikYETurenYAhlatciH, et al.Influence of GNPs and B4C reinforcements on mechanical, thermal and wear properties of magnesium matrix composite produced by powder metallurgy. J Compos Mater2021; 55(26): 3881–3891.
217.
TongPAsifMAjmalM, et al.A Multicomponent Polymer-Metal-Enzyme System as Electrochemical Biosensor for H2O2 Detection. Front Chem2022; 10: 874965.
218.
SajjadMAhmadFAli ShahL, et al.Designing graphene oxide/silver nanoparticles based nanocomposites by energy efficient green chemistry approach and their physicochemical characterization. Mater Sci Eng, B2022; 284: 115899.
219.
Sustainable adhesives for renewable materials - 2D fab(Last accessed June 2023).
220.
Levidian and Adamant to collaborate on development of graphene-enhanced compositematerials | Graphene-Info(Last accessed June 2023).
