The Use of Titanate Coupling Agents in Urethanes

S.J. Monte and P.F. Bruins , "New Coupling Agent for Filled Polyethylene," pp. 68-72, Modern Plastics, Dec. 1974.

Jpn. Kokai Tokkyo Koho JP 82 23,628,06 Feb. 1982, Teijin Ltd.

German Offen. 27 58 112, July 13, 1978.

S.J. Monte and G. Sugerman , "United States and Japanese Applications of Titanate Coupling Agents in Polyolefins," Poly.-Plast. Technol. Eng., 17(1), 95-122 (1981).

S. African Patent No. 81/8917, 23 Dec. 1981, Aerofoam Industries (Pty) Ltd. and Polyeth Marketing (Pty) Ltd.

J 5 6 145-149, MABV 04.04.80, Marubishi Yuka Kogyo KK.

Modern Plastics, Design & Application News, pp. 36, May 1982, Vol. 59, No. 5.

SPI Reinforced Plastics/Composites Institute , Paper 14-C, 1979, "Silane Effects and Machine Processing in Reinforced High Modulus RIM Urethane Composites," E. G. Schwarz , F. E. Critchfield , L. P. Tackett and P. M. Tarin , Union Carbide. Co.

A. Damusis , P. Patel , Polymer Institute, University of Detroit, (27 July 1981 ), personal communication .

SPI Urethane Division , November 1981, "Application of Titanate Coupling Agents in Mineral and Glass Fiber Filled RIM Urethane Systems," S. J. Monte and G. Sugerman, Ph.D., KPI and A. Damusis, Ph.D. and P. Patel Polymer Institute, University of Detroit.

Modern Plastics, Special Report — Fillers and Reinforcements , Surface Modifiers, p. 51, July 1982, Vol. 59, No. 7.

Reference Manual, Bulletin No. KR-0278-7, Rev. #2, Kenrich Petrochemicals, Inc.

J.J. Jakubowski and R.V. Subramanian , "Electrochemical Coating for Prevention of Carbon Fibre Release from Polymer Composites — Thermogravimetric Analysis of Organophosphorus Coatings on Carbon Fibres," pp. 161-168, Composites , July 1980.

C.D. Han , T. Van Den Weghe , P. Shete , and J.R. Haw , "Effects of Coupling Agents on the Rheological Properties, Processabihty and Mechanical Properties of of Filled Polypropylene," pp. 196-204, Polymer Engineering and Science, Vol. 21, (No. 4), (March 1981).

U.S. Patent 4,207,226, 10 June 1980, " Ceramic Composition Suited to be Injection Molded and Sintered," Roger S. Storm, The Carborundum Co., Niagara Falls, NY.

C.D. Han , C. Sanford , H.J. Yoo , "Effects of Titanate Coupling Agents on the Rheological and Mechanical Properties of Filled Polyolefins," Polymer Engineering and Science, Vol. 18, (No. 11), (August 1978).

S.J. Monte , G. Sugerman , "The Effect of Titanate Coupling Agents on: Non-Black Reinforcing Agents; A New Vulcanizing Agent System for Polyepichlorohydrin Elstomers; Azodicarbonamide Sponged Polyphosphazene Homopolymers; and Property Maintenance of Lower Mooney Rubber Compounds," Paper #43, ACS Rubber Division, October, 1979, Cleveland, OH.

K. Hayashida , T. Kamei and E. Kagoshima , "Influence of Coupling Agent upon the Flow Properties of Low Density Polyethylene Melts Mixed with Calcium Carbonate or Barium Sulfate," Kyoto University of Industrial Arts and Textile Fibers, Vol. 9, No. 2, 1980.

C.D. Han , H.L. Luo and J. Mijovic , "Effects of Coupling Agents on the Rheological Behavior and Mechanical Properties of Filled Nylon 6," pp. 82-83, May, 1982, SPE ANTEC Proceedings.

Japan Synthetic Rubber, 21.02.79-JA-017978 (+ 118753).

S.J. Monte and G. Sugerman , "Titanate Coupling Agents — Developments of 1981," SPI RP/C Instit., Jan. 11-15, 1982, Paper 22-B.

Spencer Kellogg, Division of Textron Inc., Bulletin TD-79116, Revised 10/1/80, "Spensol L44 — Water Dispersed Polyurethane Elastomer."

German Patent No. 3038646, 13 Oct. 1980, Sony Corp.

Jpn. Kokai Tokkyo Koho 034053, 22 Mar. 1979, Fuji Kagakushi Kog.

S.J. Monte and G. Sugerman , "Use of Titanate Coupling Agents as Conductivity and Adhesion Promoters ," Circuit Expo '82, Oct. 19-21, 1982, Worcester, MA.

Reinhart, T.J. , U.S. Air Force Wright Aeronautical Laboratories, (22 January 1980) personal communication.

Reinhart, T.J. , U.S. Air Force Wright Aeronautical Laboratories, (12 March 1980) personal communication.

S.J. Monte and G. Sugerman , "Adhesion Promotion and Polymer Composite Performance with Titanate Coupling Agents," Abstract No. 139, The Electrochemical Society, Inc. Symposium on Adhesion Aspects of Polymeric Coatings, Minneapolis, Minnesota, 14 May 1981.

S.J. Monte and G. Sugerman , "The Potential of Titanate Coupling Agents in Solid Rocket Fuel Systems ," 1 June 1982, Joint Symposium on Compatability of Plastics/Materials with Explosives, Propellants and Pyrotechnics and Processing of Explosives, Propellants and Ingredients, Phoenix, Arizona, Sponsored by the American Defense Preparedness Association.

E.R. Boodman , Superior Industries, Inc., Van Nuys, CA, (11 Jan. 1977), personal communication .

G. Hutchins , R. Spell , LNP Corp., Malvern, PA, (Sept. 1981), personal communication .

T. Skidmore , Siecor Corp., Hickory, NC, (Feb. 1981), personal communication .

T. Baker , Raytheon Corp., Sudbury, MA, (March 1982), personal communication.

Dept. of the Navy, Chief of Naval Research (Code 302), Arlington, VA 22217, Serial No. 288,598, 30 July 1981, C. R. Hegedus, K. G. Clark.

M. Briggs , Colebrand Ltd., Rossendale U.K., (March 1981) personal communication.

P. Westerman , BP Research Ltd., Middlesex U.K., (April 1981), personal communication .

N. Eickman , Celanese Research, Summit, NJ, (May 1982), personal communication .

J. Gabbert , Monsanto Co., St. Louis, MO, (March 1981), personal communication .

K. Geddes , University of Lowell, Lowell, MA, (June 1981), personal communication.

A. Chattopadhyay , De Soto, Inc., DesPlaines, IL, (July 1981), personal communication .

H. Stedler , Small Precision Tools, San Rafael, CA 94903, (Jan. 1981), personal communication.

R. Irizarry , Imperial Coatings Inc., New Orleans, LA 70129, (January, 1981), personal communication.

S.J. Monte , G. Sugerman and D.J. Seeman , "Titanate Coupling Agents — Current Applications (V," May 5, 1977, Paper No. 40, ACS Rubber Div. Mtg., Chicago, IL.

Modern Plastics, July 1977, " New Developments in Coupling Agents."

U.S. Patent 4,269,756, 26 May 1981, "Use of Organotitanate in the Encapsulation of Electrical Components," Tsung-Yuan Su, Union Carbide Corp.

R.S. Storm , U.S. Patent 4,207,226, June 10, 1980, The Carborundum Co.

W. Olson , 3M Company, St. Paul, MN, 55101, (July 1979), personal communication.

P.S. Dupont , Hughes Aircraft Co., El Segundo, CA 90245, (September 1980), personal communication.

E. Cheng , Tufts University, Chem. Eng. Dept., Medford, MA 02155, (August 1980), personal commumcation .

H. Brown , Emerson & Cumings, Canton, MA 02021, (March 1981), personal communication.

C. Robart , General Research Inc., Sparta, MI 49345, (June 1980), personal communication.

L. Juving , CII Honeywell Bull, Belford, France, (May 1980) personal communication.

W T. Hicks, E.I. DuPont de Nemours & Co., Niagara Falls, NY 14302, (March 1980), personal communication .

J. Bishop , Ciba-Geigy Corp., Bonded Structure Div., U.K., (March 1982), personal communication.

T.R. Basel , Boeing Aerospace Inc., Kent, WA 98031, (March 1982), personal communication.

R. Jenkins , Kendall Lexington Laboratory, Lexington, MA 02173, (December 1981), personal communication .

R.L. Dieck , U.S. Patent 4,083,820, April 11, 1978, Armstrong Cork Co.

J. Ahnemiller , Uniroyal Inc., Naugatuck, CT, (November 18, 1976), Company Log Evaluation Results, IOC Job No. 5260, Problem No. 4-917.

A. Nersasian , E.I. DuPont , Fluoroelastomers Dept., Wilmington, DE (March 1977), personal communication.

M. Mihlfeith , Thiokol/Wasatch Div., Brigham City , Utah 84302 (December 1976), personal communication.

G.C. Rosenfield , Bermite Corporation, Saugus, CA 91350, (October 1980), personal communication.

Jpn. Kokai Tokkyo Koho 81,999,266, 10 Aug. 1981, Dainippon Toryo Co., Ltd.

U.S. Patent 4,308,298, 29 Dec. 1981, "Upgrading of Cellulosic Boards," Yang-Hsien Chen, International Paper Co., New York, NY.

U.S. Patent 4,110,135, 29 Aug. 78, "Control of Cure Rate of Polyurethane Resin Based Propellants," W. H. Graham, Thiokol Corp., Newton, PA.

U.S. Patent 4,098,626, 4 July 78, "Hydroxy Terminated Polybutadiene Based Polyurethane Bound Propellant Grains," W. H. Graham, Thiokol Corp., Newton, PA.