A compact dual-gas sensor based on the two near-infrared distributed feedback diode lasers and a multipass cell has been established for the simultaneous measurement of methane (CH4) and acetylene (C2H2). The time division multiplexing calibration-free direct absorption spectroscopy is used to eliminate the cross interference in the application of multicomponent gas sensors. A wavelength stabilization technique based on the proportion integration differentiation feedback control is developed to suppress laser wavelength drift and an H-infinity (H∞) filter algorithm to reduce the system noise. The results show that the detection sensitivity of CH4 and C2H2 reaches 39.9 parts per billion (ppb) and 47.3 ppb in the optimal integration time of 556 s and 312 s, respectively. In addition, the 31 consecutive hours measured results of CH4 in outdoor ambient air show that the proposed detection technology is very suitable for high-precision in-situ measurement of trace gases.
LiJ.DengH.SunJ.YuB.FischerH.. “Simultaneous Atmospheric CO, N2O, and H2O Detection Using a Single Quantum Cascade Laser Sensor Based on Dual-Spectroscopy Techniques”. Sens. Actuators, B. 2016. 231: 723–732. https://doi.org/10.1016/j.snb.2016.03.089
2.
WangG.MeiJ.TianX.LiuK., et al. “Laser Frequency Locking and Intensity Normalization in Wavelength Modulation Spectroscopy for Sensitive Gas Sensing”. Opt. Express. 2019. 27(4): 4878. https://doi.org/10.1364/OE.27.004878
3.
ZhouT.WuT.WuQ.YeC., et al. “Real-Time Measurement of CO2 Isotopologue Ratios in Exhaled Breath by a Hollow Waveguide Based Mid-Infrared Gas Sensor”. Opt. Express. 2020. 28(8): 10970. https://doi.org/10.1364/OE.385103
4.
ShemshadJ.AminossadatiS.M.KizilM.S.. “A Review of Developments in Near Infrared Methane Detection Based on Tunable Diode Laser”. Sens. Actuators, B. 2012. 171–172: 77–92. https://doi.org/10.1016/j.snb.2012.06.018
5.
DengH.SunJ.YuB.LiJ.. “Near Infrared Diode Laser Absorption Spectroscopy of Acetylene Between 6523 and 6587 cm–1”. J. Mol. Spectrosc. 2015. 314: 1–5. https://doi.org/10.1016/j.jms.2015.05.004
6.
YeW.XiaZ.HuL.LuoW., et al. “Infrared Dual-Gas CH4/C2H2 Sensor System Based on Dual-Channel Off-Beam Quartz-Enhanced Photoacoustic Spectroscopy and Time-Division Multiplexing Technique”. Spectrochim. Acta, Part A. 2023. 285: 121908. https://doi.org/10.1016/j.saa.2022.121908
7.
ZouM.SunL.WangX.. “Multigas Sensing Based on Wavelength Modulation Spectroscopy Using Frequency Division Multiplexing Combined with Time Division Multiplexing”. IEEE Sen. J.2022. 22(13): 12930–12938. https://doi.org/10.1109/JSEN.2022.3178948
8.
RazaM.XuK.LuZ.RenW.. “Simultaneous Methane and Acetylene Detection Using Frequency-Division Multiplexed Laser Absorption Spectroscopy”. Opt. Laser Technol. 2022. 154: 108285. https://doi.org/10.1016/j.optlastec.2022.108285
9.
Y. Chen, Z. Wang, Z. Li, H. Zheng, J. Dai. “Development of an Online Detection Setup for Dissolved Gas in Transformer Insulating Oil”. Appl. Sci. 2021. 11(24): 12149. https://doi.org/10.3390/app112412149
10.
T. Chen, F. Ma, Y. Zhao, Y. Zhao, et al. “Portable ppb-Level Acetylene Photoacoustic Sensor for Transformer On-Field Measurement”. Optik. 2021. 243: 167440. https://doi.org/10.1016/j.ijleo.2021.167440
XuL.LiuK.LiangJ.LiJ.ZhouS.. “Micro-Quartz Crystal Tuning Fork-Based Photodetector Array for Trace Gas Detection”. Anal. Chem. 2023. 95(17): 6955–6961. https://doi.org/10.1021/acs.analchem.3c00318
13.
Q. Huang, Y. Wei, J. Li. “Simultaneous Detection of Multiple Gases Using Multi-Resonance Photoacoustic Spectroscopy”. Sens. Actuators, B. 2022. 369: 132234. https://doi.org/10.1016/j.snb.2022.132234
14.
LiuN.XuL.ZhouS.ZhangL.LiJ.. “Simultaneous Detection of Multiple Atmospheric Components Using an NIR and MIR Laser Hybrid Gas Sensing System”. ACS Sens. 2020. 5(11): 3607–3616. https://doi.org/10.1021/acssensors.0c01910
15.
LuoL.LiT.ZhaoR.XuL.. “A Compact Single-Ended Optical Sensor for Temperature Measurements via Laser Absorption Spectroscopy”. Appl. Therm. Eng. 2024. 249: 123382. https://doi.org/10.1016/j.applthermaleng.2024.123382
16.
WangJ.TianX.DongY.ZhuG., et al. “Enhancing Off-Axis Integrated Cavity Output Spectroscopy (OA-ICOS) with Radio Frequency White Noise for Gas Sensing”. Opt. Express. 2019. 27(21): 30517–30529. https://doi.org/10.1364/OE.27.030517
17.
WangY.DingB.WangK.MeiJ., et al. “Wide Dynamic Detection Range of Methane Gas Based on Enhanced Cavity Absorption Spectroscopy”. Chin. Phys. B. 2022. 31(4): 040705. https://doi.org/10.1088/1674-1056/ac2484
18.
ZhengK.YuL.ZhengC.XiZ., et al. “Vehicle-Deployed Off-Axis Integrated Cavity Output Spectroscopic CH4/C2H6 Sensor System for Mobile Inspection of Natural Gas Leakage”. ACS Sens. 2022. 7(6): 1685–1697. https://doi.org/10.1021/acssensors.2c00373
19.
ZhenW.DuY.-J.DingY.-J.LuJ.-F.PengZ.-M.. “Wide-Range and Calibration-Free H2S Volume Fraction Measurement Based on Combination of Wavelength Modulation and Direct Absorption Spectroscopy with Cavity Ringdown Spectroscopy”. Acta Phys. Sin. 2022. 71(18): 184205. https://doi.org/10.7498/aps.71.20220742
20.
SongZ.XuL.XieH.CaoZ.. “Random Vibration-Driven Continuous-Wave CRDS System for Calibration-Free Gas Concentration Measurement”. Opt. Lett. 2020. 45(3): 746–749. https://doi.org/10.1364/OL.382697
21.
PatraI.ChakrabortyS.PalA.PradhanM.. “High-Resolution Investigation of the Spin-Rotation Doublets of 14NO2 at 6.2 mm Mid-Infrared Region Using Cavity Ring-Down Spectroscopy”. Infrared Phys. Technol. 2024. 139: 105317. https://doi.org/10.1016/j.infrared.2024.105317
22.
FengY.ChangJ.ChenX.ZhangQ., et al. “Application of TDM and FDM Methods in TDLAS Based Multi-Gas Detection”. Opt. Quantum Electron. 2021. 53(4): 195. https://doi.org/10.1007/s11082-021-02844-9
23.
S.GuoLiJ.WeiY.YangY., et al. “A Multi-Laser Hybrid Absorption Sensor for Simultaneous Measurement of NH3, NO, and Temperature in Denitrification Flue Gas”. Infrared Phys. Technol. 2024. 136: 105034. https://doi.org/10.1016/j.infrared.2023.105034
24.
DuY.LiuN.WuX.LiuK.LiJ.. “Frequency Division Multiplexing and Wavelength Stabilized 2f/1f Wavelength Modulation Spectroscopy for Simultaneous Trace CH4 and CO2 Detection”. Spectrochim. Acta, Part A. 2024. 305: 123453. https://doi.org/10.1016/j.saa.2023.123453
25.
DengB.SimaC.XiaoY.WangX., et al. “Modified Laser Scanning Technique in Wavelength Modulation Spectroscopy for Advanced TDLAS Gas Sensing”. Opt. Laser Eng. 2022. 151: 106906. https://doi.org/10.1016/j.optlaseng.2021.106906
26.
R. Yu, H. Xia, T. Pang, B. Wu, et al. “Simultaneous Detection of CO2/CH4 Based on Off-Axis Integrated Cavity Output Spectroscopy and Time-Division-Multiplexing-Based Wavelength Modulation Spectroscopy”. Opt. Commun. 2023. 545: 129731. https://doi.org/10.1016/j.optcom.2023.129731
27.
T. Zhang, J. Kang,D. Meng, H.Wang, et al. “Mathematical Methods and Algorithms for Improving Near-Infrared Tunable Diode-Laser Absorption Spectroscopy”. Sensors. 2018. 18(12): 4295.
28.
ZhangG.HaoH.WangY.JiangY., et al. “Optimized Adaptive Savitzky–Golay Filtering Algorithm Based on Deep Learning Network for Absorption Spectroscopy”. Spectrochim. Acta, Part A. 2021. 263: 120187. https://doi.org/10.1016/j.saa.2021.120187
29.
TianL.SunJ.ZhangS.KolomenskiiA.A., et al. “Near-Infrared Methane Sensor with Neural Network Filtering”. Sens. Actuators, B.2022. 354: 131207. https://doi.org/10.1016/j.snb.2021.131207
30.
TongC.SimaC.ChenM.ZhangX., et al. “Laser Linewidth Analysis and Filtering/Fitting Algorithms for Improved TDLAS-Based Optical Gas Sensor”. Sensors (Basel). 2023. 23: 5130. https://doi.org/10.3390/s23115130
31.
S. Kireev, A. Kondrashov, S. Shnyrev, N. Frolov. “Kalman’s Method To Improve Accuracy of Online 13C16O2 Measurement in the Exhaled Human Breath Using Tunable Diode Laser Absorption Spectroscopy”. Laser Phys. Lett. 2018. 15(9): 095701.
32.
JiJ.HuangY.PiM.ZhaoH., et al. “Performance Improvement of On-Chip Mid-Infrared Waveguide Methane Sensor Using Wavelet Denoising and Savitzky–Golay Filtering”. Infrared Phys. Technol. 2022. 127: 104469. https://doi.org/10.1016/j.infrared.2022.104469
33.
HaneeshK.RaghunathanT.. “Robust Control of DFIG Based Wind Energy System Using an H∞ Controller”. J. Electr. Eng. Technol. 2021. 16: 1693–1707. https://doi.org/10.1007/s42835-021-00699-4
34.
XiaJ.GaoS.ZhongY.QiX., et al. “Moving-Window-Based Adaptive Fitting H-Infinity Filter for the Nonlinear System Disturbance”. IEEE Access. 2020. 8: 7663–76157. https://doi.org/10.1109/ACCESS.2020.2988793
35.
DongH.WangZ.HoD.W.C.GaoH.. “Variance-Constrained H∞ Filtering for a Class of Nonlinear Time-Varying Systems with Multiple Missing Measurements: The Finite-Horizon Case”. IEEE T. Signal Process. 2010. 58(5): 2534–2543.
36.
GordonI.E.RothmanL.S.HargreavesR.J.HashemiR., et al. “The HITRAN2020 Molecular Spectroscopic Database”. J. Quant. Spectrosc. Radiat. Transfer. 2022. 277: 107949. https://doi.org/10.1016/j.jqsrt.2021.107949
37.
MaH.SunM.ZhanS.ZhangQ., et al. “Compact Dual-Gas Sensor for Simultaneous Measurement of Atmospheric Methane, and Water Vapor Using a 3.38 mm Antimonide-Distributed Feedback Laser Diode”. Spectrochim. Acta, Part A. 2020. 226: 117605. https://doi.org/10.1016/j.saa.2019.117605
38.
J. Xia, C. Feng, F. Zhu, S. Ye, et al. “A Sensitive Methane Sensor of a ppt Detection Level Using a Mid-Infrared Interband Cascade Laser and a Long-Path Multipass Cell”. Sens. Actuators, B. 2021. 334: 129641. https://doi.org/10.1016/j.snb.2021.129641
39.
WuX.DuY.ShiS.JiangC., et al. “Simultaneous Detection of CO2 and CH4 Using a DFB Diode Laser-Based Absorption Spectrometer”. Chemosensors. 2022. 10(10): 390. https://doi.org/10.3390/chemosensors10100390
40.
HuZ.ShiY.NiuM.LiT., et al. “Triple-Range Adjustable Plane-Concave Multipass Gas Cell for High-Precision Trace Gas Detection Based on TDLAS”. Opt. Laser Eng.2024. 175: 108023. https://doi.org/10.1016/j.optlaseng.2024.108023
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