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Abstract

We developed nanoscale ex situ thermal impulse (i.e., the temperature and duration of a heating event) sensors for structural fire forensics using a mixture of two lanthanide-doped oxide precursors (precursor Eu:ZrO₂ and precursor Dy:Y₂O₃) that undergo irreversible phase changes when heated. These changes are probed using photoluminescence (PL) spectroscopy with the PL spectra being dependent on the thermal impulse (TI) experienced by the sensors. By correlating the PL spectra to different in-lab TIs, we are able to produce a spectroscopic calibration for our sensors. This calibration allows us to determine an unknown TI of a heating event using only the PL spectrum of the heated TI sensors. In this study, we report on the calibration of these sensors for isothermal heating durations up to 600 s and isothermal temperatures up to 1273 K. Using this calibration, we also demonstrate their ability to determine an unknown TI and demonstrate their functionality when dispersed into paint, which is heated in the presence of drywall.

Keywords

Temperature sensors lanthanides photoluminescence spectroscopy lanthanide-doped oxides irreversible phase changes structural fire forensics arson investigation

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References

National Fire Protection Association. NFPA 921 Guide for Fire and Explosion Investigations, Quincy, MA: NFPA, 2004.

Lentini

“The Evolution of Fire Investigation and Its Impact on Arson Cases”. Criminal Justice 2012; 27: 12.

Lentini

Scientific protocols for fire investigation, 2nd ed. Boca Raton, FL: Taylor & Francis, 2006.

Cox

Chitty

“Some Stochastic Properties of Fire Plumes”. Fire and Materials 1982; 6: 127–134.

Fristrom

Flame Structure and Process, New York, NY: Oxford University Press, 1995.

Gaydon

Wolfhard

Flames: Their Structure, Radiation and Temperature, 3rd ed. London: Chapman & Hall, 1970.

Anderson

B.R.

Gunawidjaja

Price

Eilers

“Spectroscopic Determination of Thermal Impulse in Sub-Second Heating Events Using Lanthanide-Doped Oxide Precursors and Phenomenological Modeling”. J. Appl. Phys 2016; 120: 083102.

Myint

Gunawidjaja

Eilers

“Fast Pyroprobe-Heating-Induced Structural Changes of Y₂O₃:Eu Precursors and Their Optical Signatures”. J. Phys. Chem. C 2012; 116: 1687–1693.

Gunawidjaja

Myint

Eilers

“Correlation of Optical Properties and Temperature-Induced Irreversible Phase Transitions in Europium-Doped Yttrium Carbonate Nanoparticles”. J. Solid State Chem 2011; 184: 3280–3288.

10.

Myint

Gunawidjaja

Eilers

“Spectroscopic Properties of Nanophase Eu-Doped ZrO₂ and Its Potential Application for Fast Temperature Sensing Under Extreme Conditions”. J. Phys. Chem. C 2012; 116: 21629–21634.

11.

Gunawidjaja

Myint

Eilers

“Stabilization of Tetragonal Phase in ZrO₂:Eu by Rapid Thermal Heating”. Chem. Phys. Lett 2011; 515: 122–126.

12.

Gunawidjaja

Myint

Eilers

“Temperature-Dependent Phase Changes in Multicolored Er_xYb_y

{Zr}_{1 - x - y}

O₂/

{Eu}_{0.02} Y_{1.98}

O₃ Core/Shell Nanoparticles”. J. Phys. Chem. C 2013; 117: 14427–14434.

13.

Gunawidjaja

Myint

Eilers

“Optical and Morphological Characterization of

{Tb}_{0.01} {Zr}_{0.99}

O₂/(Precursor

{Eu}_{0.02} Y_{1.98}

O₃) Core/Shell Nanoparticles as Temperature Sensors in Fast Heating Events”. J. Phys. Chem. C 2014; 118: 5563–5569.

14.

Gunawidjaja

Diez-y-Riega

Eilers

“Irreversible Phase Transitions Due to Laser-Based T-Jump Heating of Precursor Eu:ZrO₂/Tb:Y₂O₃ Core/Shell Nanoparticles”. J. Solid State Chem 2015; 229: 350–357.

15.

Myint

Gunawidjaja

Eilers

“Light-Induced Structural Changes in Eu-Doped (Pb,La)(Zr,Ti)O₃ Ceramics”. App. Phys. Lett 2011; 98: 171906.

16.

Gunawidjaja

Myint

Eilers

“Synthesis of Silver/SiO₂/Eu:Lu₂O₃ Core-Shell Nanoparticles and their Polymer Nanocomposites”. Powder Tech 2011; 210: 157–166.

17.

J. Munoz-Santiuste, U. Rodriguez-Mendoza, J. Gonzalez-Platas, V. Lavin. “Structural Study of the Eu³⁺ Environments in Fluorozirconate Glasses: Role of the Temperature-Induced and the Pressure-Induced Phase Transition Processes in the Development of a Rare Earth s Local Structure Model”. J. Chem. Phys. 2009. 130: 154501.

18.

J.-C.G. Bünzli, S.V. Eliseeva. “Basics of lathanide photophysics,” in “Lanthanide Luminescence: Photophysical, Analytical and Biological Aspects”. In: P. Hanninen, H. Harma, (eds.). Berlin: Springer-Verlag, 2010. Pp. 1–45.

19.

K. Binnemans. “Lanthanide-Based Luminescent Hybrid Material”. Chem. Rev. 2009. 109: 4283.

20.

K. Binnemans, C. Gorllerwalrand. “A Simple Model for Crystal Field Splittings of the

^{7} F_{1}

and

^{5} D_{1}

Energy Levels of Eu³⁺”. Chem. Phys. Lett. 1995. 245: 75.

21.

B. Bihari, H. Eilers, B. Tissue. “Spectra and Dynamics of Monoclinic Eu

_{2} O_{3}

and Eu

^{3 +}

_{2} O_{3}

Nanocrystals”. J. Lumin. 1997. 75: 1.

22.

J. Bünzli. “Luminescent Probes”. In: J. Bunzli, G. Choppin, editors. Lanthanide Probes in Life Chemical and Earth Sciences: Theory and Practice. Amsterdam: Elsevier, 1989. Pp. 219–293.

23.

Eilers

Tissue

“Laser Spectroscopy of Nanocrystalline Eu₂O₃ and Eu³⁺:Y₂O₃”. Chem. Phys. Lett 1996; 251: 74–78.

24.

Tiseanu

Parvulescu

Sanchez-Dominguez

Boutonnet

“Spectral and Temporarily Resolve Luminesence Study of Short-Range Order in Nanostructured Amorphous zro₂”. J. Appl. Phys 2011; 110: 103521.

25.

Binnemans

Walrand

C.G.

“Application of the Eu³⁺ Ion for Site Symmetry Determination”. J. Rare Earth 1996; 14: 173–180.

26.

Srinivasan

Yogamalar

Elanchezhiyan

Joseyphus

Bose

“Structural and Optical Properties of Europium Doped Yttrium Oxide Nanoparticles for Phosphor Applications”. J. Alloy. Comp 2010; 496: 472–477.

27.

Huang

Chin

Gan

Chew

“Synthesis and Characterization of eu: Y₂o₃ Nanoparticles”. Nanotechnology 2002; 13: 318–323.

28.

Chien

“Synthesis of Y₂O₃: Eu Phosphors by Bicontinuous Cubic Phase Process”. J. Cryst. Growth 2006; 290: 554–559.

29.

G. Jia, C. Wang, S. Xu. “Local Site Symmetry Determination of Scheelite-Type Structures by Eu³⁺ Spectroscopy”. J. Phys. Chem. C. 2010. 114: 17905.

30.

Turmanova

S.C.

Genieva

S.D.

Dimitrova

A.S.

Vlaev

L.T.

“Non-Isothermal Degradation Kinetics of Filled with Rise Husk Ash Polypropene Composites”. Express Polymer Letters 2008; 2: 133–146.

31.

Avramov

“Kinetics of Distribution of Infections in Networks”. Phys. Stat. Mech. Appl 2007; 379: 615–620.

32.

Avrami

“Kinetics of Phase Change. I General Theory”. J. Chem. Phys 1939; 7: 1103–1112.

33.

Avrami

“Kinetics of Phase Change. II Transformation-Time Relations for Random Distribution of Nuclei”. J. Chem. Phys 1940; 8: 212–224.

34.

Avrami

“Granulation, Phase Change, and Microstructure Kinetics of Phase Change. III”. J. Chem. Phys 1941; 9: 177–184.

35.

Dickinson

Heal

“Solid-Liquid Diffusion Controlled Rate Equations”. Thermochim. Acta 1999; 340–341: 89–103.

36.

Ramis

Cadenato

Salla

Morancho

Valles

et al.

“Thermal Degradation of Polypropylene/Starch-Based Materials with Enhanced Biodegradability”. Polymer Degrad. Stabil 2004; 86: 483–491.

37.

Vlaev

Georgieva

Genieva

“Products and Kinetics of Non-Isothermal Decomposition of Vandium(iv) Oxide Compounds”. Journal of Thermal Analysis and Calorimetry 2007; 88: 805–812.

38.

Chen

Wang

“Thermal Oxidative Degradation Kinetics of Flame-Retarded Polypropylene with Intumescent Flame-Retardant Master Batches In Situ Prepared in Twin-Screw Extruder”. Polymer Degrad. Stabil 2007; 92: 280–291.

39.

Zhang

Wang

“Modeling Study on the Combustion of Intumescent Fire-Retardant Polypropylene”. eXPRESS Polymer Letters 2007; 1: 157–165.

Nanoscale Ex Situ Thermal Impulse Sensors for Structural Fire Forensics

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