Sage Journals: Discover world-class research

Abstract

Nanoscale zerovalent iron (nZVI) has shown great promise for water treatment and soil remediation. However, the rapid aggregation of nZVIs significantly affects their mobility and reactivity, which considerably limits the practical applications. Montmorillonite- (Mt-) supported nZVI (Mt-nZVI) has received increasing attention for the past decade because it can prevent the aggregation of nZVI and incorporate the advantages of both nZVI and Mt in soil and water treatment. This work thus had a comprehensive review on the use of Mt-nZVI for soil and water treatment. We first summarized existing methods used to prepare Mt-nZVI, indicating the advantages of using Mt to support nZVI (e.g., increase of the dispersion and mobility of nZVI, reduction of the size and oxidation tendency of nZVI). We then presented the reaction mechanisms of Mt-nZVI for contaminant removal and evaluated the critical factors that influence the removal (e.g., pH, temperature, and dosage of the adsorbent). We further presented examples of applications of Mt-nZVI for the removal of typical contaminants such as heavy metals and organic compounds in soil and water. We finally discussed the limitations of the use of Mt-nZVI for water treatment and soil remediation and presented future directions for the application of nZVI technology for soil and water treatment.

1. Introduction

Water and soil contaminations are becoming more and more severe during the past few decades, which seriously damage the natural ecological balance and threaten human health [1]. Various techniques such as ion exchange, filtration, chemical precipitation, and electrochemical treatment have been employed to address the water and soil contaminations [2–4]. However, these techniques have a series of limitations including high cost, secondary pollution, and complicated operations [5]. Recently, the fabrication of adsorption materials with low cost and high performance for the treatment of soil and water has become a promising way [6]. Particularly, the use of nanoscale zerovalent iron (nZVI) has received focused attention [7].

The nZVIs refer to nanoscale iron particles with amorphous structures, which have been widely applied to remove various contaminants because of their large specific surface area (SSA), strong adsorption activity, and reduction ability [8, 9]. However, nZVI tends to agglomerate into larger particles due to van der Waals and magnetic forces, which decreases the SSA and limits its adsorption capacity and mobility [10]. Moreover, nZVI is readily oxidized before reaching the target contaminants during in situ soil remediation, resulting in low longevity [11]. An effective approach to overcome the aforementioned problems is to load nZVI particles onto templates such as biochar [12], zeolite [13], and polymers [14]. Nevertheless, these templates need to be manufactured and/or are relatively expensive, and the fabrications are often complex [15]. Therefore, it is desirable to find low-cost load materials and develop more efficient methods of immobilization of nZVI on templates to take advantage of the real potential of nZVI [16].

Montmorillonite (Mt) is a typical 2 : 1 layered silicate clay mineral with low cost, high cation exchange, and adsorption capacity (Figure 1) [17]. It is usually composed of an interlayer with a thickness of 0.1-0.8 nm due to the isomorphous substitution within the layers (e.g., Si⁴⁺ replaced by Al³⁺ in the tetrahedral sheet and Al³⁺ replaced by Mg²⁺ in the octahedral sheet) (Figure 1). Hence, the Mt layers have permanent negative charges, which can be exchanged by other cations residing at and/or near the Mt surfaces [18]. This structure creates an ideal template to support nZVI particles (Figure 2) [19]. For example, bentonite (Bt) is a kind of natural clay mainly composed of Mt, which has been extensively used as a supporting material for nZVI [20]. Compared to nZVI or Mt, Mt-supported nZVI (Mt-nZVI) had higher removal efficiency for inorganic and organic contaminants [21–23]. This is because Mt can improve the dispersion and mobility of nZVI and reduce the particle size and oxidation tendency of nZVI [24–26]. Therefore, the Mt-nZVI composites have shown great potential for application in water and soil treatment.

Figure 1

Structure of Mt. Modified from Reinholdt et al. [110].

Figure 2

Schematic representation of the sectional structure of Mt-nZVI. Modified from Wu et al. [43].

To date, various papers have made reviews on the synthesis, characteristic, application, or modification of nZVI (Table 1) [1, 27, 28]. For instance, Li et al. [8] presented the synthesis, characterization, and applications of nZVI for the treatment of organic and inorganic contaminants. O’Carroll et al. [29] reviewed the application of nZVI and bimetallic particles. Lefevre et al. [30] summarized the impacts of nZVI applications on microbial communities. Ezzatahmadi et al. [31] reported an overview of different types of clay-supported nZVIs (e.g., Mt, kaolinite, zeolite, sepiolite, and palygorskite) for the remediation of contaminated aqueous solutions. However, no review has exclusively addressed the use of Mt-nZVI for soil and water remediation to date.

Table 1

Summary of some key review papers on nZVI for water and soil treatments.

Publication date	Material	Focus area	Reference
2006	nZVI	Synthesis, characterization, and applications of nZVI for the treatment of organic and inorganic contaminants	[8]
2012	nZVI	Synthesis and applications of nZVI for water treatment	[27]
2013	nZVI/bimetallic nanometals	Application of nZVI/bimetallic nanometals for the in situ remediation of chlorinated solvents and heavy metals	[29]
2013	nZVI	Reactivity, stability, and effects of nZVI amendment on the biogeochemical environment	[52]
2016	nZVI	Impacts of nZVI applications on microbial communities	[30]
2016	nZVI	The toxicity of nZVIs prior to the process of remediation and their effect on living organisms after application	[28]
2016	nZVI	Synthesis, applications, and properties of stabilized nZVI	[47]
2017	Clay-supported nZVI	Reaction mechanisms and removal efficiencies of clay-supported nZVI for the remediation of contaminated aqueous solutions	[31]
2019	Biochar-supported nZVI	Synthesis, properties, and applications of biochar-supported nZVI for water and soil treatment	[12]
2019	nZVI	Synthesis of nZVI-based materials and reaction mechanisms and influential factors between nZVIs and antibiotics	[46]

This paper provides an overview of the current knowledge of Mt-nZVI composites in water and soil applications. We firstly present the preparation methods of Mt-nZVI and discuss the advantages and disadvantages of the different methods. We highlight the benefits of using Mt as supporting material for nZVI. We then show in detail the reaction mechanisms of Mt-nZVI for contaminant removal and the main influencing factors on the removal using the Mt-nZVI. We further give examples of the applications of Mt-nZVI in soil and water remediation. We finally demonstrate the limitations of Mt-nZVI composites and show future research directions. Our work has important implications to improve the Mt-nZVI composites for application in water treatment and soil remediation.

2. Fabrication Methods of Mt-nZVI

2.1. Methods of Synthesizing Modified Mt

The properties of Mt have a great influence on the application of Mt-nZVI. The pristine Mt is commonly Ca-Mt, which has a permanent negative charge. Positively charged hydrated cations (e.g., K⁺, Na⁺, and Ca²⁺) can be adsorbed in the layers to maintain charge balance [32]. These cations can be exchanged by other organic/inorganic cations, making Mt an efficient adsorbent for cationic contaminants [33].

2.1.1. Inorganic Modified Mt

Na-Mt has better physicochemical properties compared to Ca-Mt, such as strong cation exchangeability, high dispersion in the water medium, large expansion capacity, and great thermal stability [34]. Therefore, Na-Mt is frequently used as the raw material to prepare Mt-nZVI. Alternatively, K-Mt [21] and Al-Mt [33] have also been used to synthesize Mt-nZVI.

Due to electrostatic interaction, the negatively charged Na-Mt-supported nZVI normally favors the adsorption of cationic contaminants [33, 35], while the positively charged K-Mt- and Al-Mt-supported nZVIs favor the adsorption of anionic contaminants [21, 33, 36]. For example, Sheng et al. [25] revealed that the removal efficiency of U(VI) (100 mg L^-1) by Na-Bt-supported nZVI (0.2 g L^-1) reached 99.2% after 90 min, which was higher than that by Al-Bt-supported nZVI (65.6%) (Table 2). Li et al. [35] found that Na-Bt-supported nZVI had higher removal efficiency for Ni(II) (98.5%) compared to Al-Bt-supported nZVI (45.4%) under the same condition (Table 2). However, the removal efficiency of K-Mt-supported nZVI and Al-Mt-supported nZVI for Cr(VI) was higher than that of Na-Mt-supported nZVI [21]. The method of inorganic modification of Mt is relatively simple, which can improve the adsorption of Mt-nZVI to target inorganic contaminants.

Table 2

Representative studies dealing with contaminant removal from water by Mt-nZVI.

Adsorbents	Particle size (nm)	SSA (m² g^-1)	Target contaminants	Operational conditions	Adsorption capacity (mg·g⁻¹)	Efficiency	Reference
Bt-nZVI	—	39.94	Cr(VI)	$C_{0} = 50 mg L^{- 1}, C = 4 g L^{- 1}, pH = 5$	—	100% in 180 min	[81]
Mt-nZVI	—	—	Cr(VI)	$C_{0} = 20 mg L^{- 1}, C = 2.75 g L^{- 1}, pH = 5.5$	31.65	99.75% in 240 min	[15]

Mt-nZVI	—	—	Cr(VI)	$C_{0} = 50 mg L^{- 1}, C = 0.33 g L^{- 1}, pH = 5$	90.9	—	[43]
Hexadecyltrimethylammonium bromide-modified Mt-supported nZVI	—	—	Cr(VI)	$C_{0} = 50 mg L^{- 1}, C = 0.33 g L^{- 1}, pH = 5$	109.9	—	[43]

Bt-nZVI	53.2	—	Cr(VI)	$C_{0} = 50 mg L^{- 1}, C = 1 g L^{- 1}, pH = 9$	—	56.8% in 60 min	[95]
Bt-supported organosolv lignin-stabilized nZVI	20.1	—	Cr(VI)	$C_{0} = 50 mg L^{- 1}, C = 1 g L^{- 1}, pH = 9$	—	62.3% in 60 min	[95]

Zeolite-supported nZVI	11.7	29.1	Pb(II)	$C_{0} = 200 mg L^{- 1}, C = 2.5 g L^{- 1}, pH = 3 ‐ 6$	$115.1 \pm 11.0$	99% in 40 min	[77]
Mt-nZVI	9.3	20.9	Pb(II)	$C_{0} = 200 mg L^{- 1}, C = 2.5 g L^{- 1}, pH = 3 ‐ 6$	$105.5 \pm 9.0$	99% in 40 min	[77]

Bt-nZVI	20-50	24.3-46.5	Pb(II)	$C_{0} = 200 mg L^{- 1}, C = 1 g L^{- 1}, pH = 7$	—	95% in 240 min	[50]

Na-Mt-supported nZVI		31.8	U(VI)	$C_{0} = 100 mg L^{- 1}, C = 0.2 g L^{- 1}$ , initial pH		99.2% in 90 min	[25]
Al-Mt-supported nZVI		46.9	U(VI)	$C_{0} = 100 mg L^{- 1}, C = 0.2 g L^{- 1}$ , initial pH		65.6% in 90 min	[25]

Mt-nZVI	—	91.42	U(VI)	$C_{0} = 0.1 mg L^{- 1}, C = 0.1 g L^{- 1}, pH = 3$	—	97.8% in 3 min	[32]
Mt-nZVI	—	40.1	Zn(II)	$C_{0} = 50 mg L^{- 1}, C = 5 g L^{- 1}, pH = 5$	10.33	—	[34]

Bt-nZVI	—	42.88	Cu(II)	$C_{0} = 100 mg L^{- 1}, C = 1 g L^{- 1}, pH = 5 \pm 0.3$	73.37	71% in 16 h	[88]
Bt- and graphene oxide-supported nZVIs	42.35	47.32	Cu(II)	$C_{0} = 100 mg L^{- 1}, C = 1 g L^{- 1}, pH = 5 \pm 0.3$	83.89	82% in 16 h	[88]

Na-Mt-supported nZVI	—	46.9	Ni(II)	$C_{0} = 200 mg L^{- 1}, C = 0.25 g L^{- 1}, pH = 6$	—	98.5% in 120 min	[35]
Al-Mt-supported nZVI	—	31.8	Ni(II)	$C_{0} = 200 mg L^{- 1}, C = 0.25 g L^{- 1}, pH = 6$	—	45.4% in 120 min	[35]

Bt-nZVI	30-70	29.8	NO₃ ^-	$C_{0} = 50 mg L^{- 1}, C = 0.5 g L^{- 1}, pH = 7$	—	100% in 120 min	[86]
Mt-nZVI	—	11.78	NO₃ ^-	$C_{0} = 60 mg L^{- 1}, C = 0.67 g L^{- 1}, pH = 7.0 \pm 0.3$	—	32.6±1.9% in 24 h	[99]

Mt-nZVI	30-170	—	Se(VI)	$C_{0} = 200 mg L^{- 1}, C = 2.5 g L^{- 1}, pH = 7$	34.21	42.76% in 24 h	[76]
Mt-nZVI	30-170	—	As(V)	$C_{0} = 200 mg L^{- 1}, C = 2.5 g L^{- 1}, pH = 7$	54.75	68.43% in 24 h	[76]

Mt-nZVI	—	36.97	As(III)	$C_{0} = 5 mg L^{- 1}, C = 1 g L^{- 1}, pH = 7$	59.9	—	[82]
Mt-nZVI	—	36.97	As(V)	$C_{0} = 5 mg L^{- 1}, C = 1 g L^{- 1}, pH = 7$	45.5	—	[82]

Bt-nZVI	10-60	66.5	Co(II)	$C_{0} = 100 mg L^{- 1}, C = 1.25 g L^{- 1}$ , initial pH	—	90.0% in 120 min	[49]
N,N,N-trimethyl-1-dodecanaminium salt-modified Mt-supported nZVI	<5	—	2,4-Dichlorophenol	$C_{0} = 20 mg L^{- 1}, C = 15 mg L^{- 1}$ , initial pH	—	>99% in 10 h	[19]

Mt-nZVI	—	—	Trichloroethylene	$C_{0} = 250 mg L^{- 1}, C = 4 g L^{- 1}$ , initial pH	—	78.7% in 12 h	[102]
Mt-nZVI	—	—	Trichloroethylene	$C_{0} = 250 mg L^{- 1}, C = 4 g L^{- 1}$ , initial pH	—	56.1% in 12 h	[102]

Cetyltrimethylammonium bromide- (CTMAB-) modified Mt-supported nZVI	30–90	36.431	Decabromodiphenyl ether	$C_{0} = 2 mg L^{- 1}, C = 0.6 g L^{- 1}, pH = 5.5$	—	98.02% in 24 h	[73]
Tetramethylammonium-modified Mt-supported nZVI	0.5	—	Decabromodiphenyl ether	$C_{0} = 2.5 mg L^{- 1}, C = 4 g L^{- 1}, pH = 9.6$	—	>80% in 90 min	[42]

Cetyltrimethylammonium bromide- (CTMAB-) modified Mt-supported nZVI	—	29.5	Pentachlorophenol	$C_{0} = 53 mg L^{- 1}, C = 0.6 g L^{- 1}, pH = 6$	—	96.2% in 120 min	[40]
Mt-nZVI	—	47.4	Pentachlorophenol	$C_{0} = 53 mg L^{- 1}, C = 0.6 g L^{- 1}, pH = 6$	—	49.6% in 120 min	[40]

Mt-nZVI	84	—	Bisphenol A	$C_{0} = 25 mg L^{- 1}, C = 0.4 g L^{- 1}, pH = 3$	—	99.3% in 30 min	[64]
CTMAB-modified Mt-supported nZVI	—	36.4	Tetrabromobisphenol A	$C_{0} = 10 mg L^{- 1}, C = 0.1 g L^{- 1}, pH = 7$	—	98.6% in 60 min	[26]
CTMAB-modified Mt-supported nZVI	—	36.4	Bisphenol A	$C_{0} = 10 mg L^{- 1}, C = 0.1 g L^{- 1}, pH = 7$	—	94.7% in 60 min	[26]
Bt-nZVI	—	39.94	Acid violet red B	$C_{0} = 800 mg L^{- 1}, C = 2.8 g L^{- 1}$ , initial pH	—	95.6% in 9 min	[74]
Bt-nZVI	—	39.94	Methyl orange	$C_{0} = 100 mg L^{- 1}, C = 1 g L^{- 1}, pH = 5.6$		99.80% in 40 min	[24]
Mt-nZVI	—	—	Rhodamine 6G	$C_{0} = 5000 mg L^{- 1}, C = 10 g L^{- 1}$ , initial pH	500	100% in 15 min	[78]

Bt-nZVI	40–120	47.4	Nitrobenzene	$C_{0} = 200 mg L^{- 1}, C = 0.3 g L^{- 1}, pH = 6$	—	87.2% in 90 min	[41]
Cetyltrimethylammonium-modified Bt-supported nZVI	40-90	31.4	Nitrobenzene	$C_{0} = 200 mg L^{- 1}, C = 0.3 g L^{- 1}, pH = 6$	—	98.2% in 60 min	[41]

CTMAB-modified Mt-supported nZVI	—	—	Sulfamethazine	$C_{0} = 20 mg L^{- 1}, C = 1.5 mM, pH = 6.8$	—	92% in 5 min	[44]
Mt-nZVI	—	—	Sulfamethazine	$C_{0} = 20 mg L^{- 1}, C = 1.5 mM, pH = 6.8$	—	76% in 5 min	[44]
Mt-nZVI	—	—	Oxytetracycline	$C_{0} = 100 mg L^{- 1}, C = 0.6 g L^{- 1}, pH = 5$	—	99% in 20 min	[75]
Bt-nZVI	—	—	Amoxicillin	$C_{0} = 20 mg L^{- 1}, C = 4 g L^{- 1}$ , initial pH	5.5	93.5% in 40 min	[91]

SSA denotes the specific surface area; $C_{0}$ and $C$ denote the concentration of contaminants and adsorbents, respectively.

2.1.2. Organic Modified Mt

While Mt is hydrophilic and negatively charged, organic contaminants are usually hydrophobic [37]. Consequently, some nonionic or anionic organic compounds have poor adsorption affinity with Mt-nZVI [38]. To overcome the limitations, cationic surfactants have been used as modifiers of Mt [39]. Quaternary ammonium salt cations are common cationic surfactants such as cetyltrimethylammonium (CTMA) [40, 41], cetyltrimethylammonium bromide (CTMAB) [26, 42], and hexadecyltrimethylammonium bromide (HDTMA) [43].

The advantages of using organic modified Mt-supported nZVI to remove organic compounds have been reported. Substituting the inorganic cations (e.g., Na⁺) with organic ammonium cations (e.g., DTA⁺) in the Mt interlayer can further increase the layer spacing and enhance the adsorption capacity of organic contaminants on Mt by changing the surface of Mt from hydrophilic to hydrophobic [19, 42, 44]. For example, Li et al. [40] reported that the efficiency of pentachlorophenol (53 mg L^-1) removed by CTMA-modified Bt-supported nZVI (0.6 g L^-1) reached 96.2% within 120 min at pH 6, which was higher than that by Bt-nZVI (49.6%). Moreover, the degradation efficiency of decabromodiphenyl ether (DBDE) by tetramethylammonium- (TMA-) modified smectite-supported nZVI was 10 times greater than that by nZVI. Note that the organic modified Mt can also inhibit the rapid consumption of nZVI by forming a hydrophobic environment in the clay interlayer. For example, Jia and Wang [19] used N,N,N-trimethyl-1-dodecanaminium salt- (DTA⁺-) modified smectite-supported nZVI to remove 2,4-dichlorophenol (2,4-DCP) and found that almost 100% of 2,4-DCP could be dechlorinated even after five cycles on organo-smectite-supported nZVI, but smectite-supported nZVI only dechlorinated twice.

2.2. Methods of Synthesizing Mt-nZVI

2.2.1. Liquid-Phase Reduction

Wang and Zhang [45] were the first to develop a liquid-phase reduction method to prepare nZVI. This technique has then become the most widely used method to prepare nZVI in laboratories [46]. In this approach, nZVI is synthesized by reduction of Fe³⁺ or Fe²⁺ in aqueous solutions using NaBH₄ under N₂ atmosphere (Equations (1) and (2)) [31, 47]: $\begin{matrix} (1) & 4 F e^{3 +} + 3 B {H_{4}}^{-} + 9 H_{2} O ⟶ 4 F e^{0} + 3 B {O_{3}}^{-} + 12 H^{+} + 6 H_{2} \\ (2) & 2 F e^{2 +} + {BH}_{4}^{-} + 3 H_{2} O ⟶ 2 F e^{0} + {BO}_{3}^{-} + 4 H^{+} + 3 H_{2} \end{matrix}$

The Mt-nZVI is synthesized by a slightly modified liquid-phase reduction method with Mt as support [21]. Briefly, Mt-nZVI is typically prepared under N₂ atmosphere by using NaBH₄ to reduce Fe³⁺ or Fe²⁺ to Fe⁰ in the presence of Mt as the supporting material (Figure 3(a)). The Mt is used as a layered template to limit the size of the nZVI formed at the nanoscale (60-80 nm) and direct the distribution of nZVI clusters [19, 48–50]. The scanning electron microscope (SEM) images of Bt-supported nZVI (Bt-nZVI) (Figure 4(a)) synthesized by the aforementioned method showed that the aggregation of nZVI particles was decreased due to Bt [51]. Various organic or inorganic modifiers can be used to modify Mt before the preparation of Mt-nZVI to improve its adsorption performance and dispersibility in organic media [33], which are detailed later in the paper.

Figure 3

Illustration of the synthesis process of Mt-nZVI by different methods: (a) liquid-phase reduction; (b) heteroaggregates of Mt with nZVIs; (c) green synthesis method; (d) thermal reduction method.

(b)

(c)

(d)

Figure 4

SEM images of (a) Bt-nZVI [51] synthesized by liquid-phase reduction and (b) heteroaggregates of Mt with nZVIs [15]. TEM images of (c) Bt and (d) Bt-supported “green” nZVI synthesized by green synthesis [60]. SEM images of (e) Fe-Mt and (f) Fe-Mt-H₂ synthesized by thermal reduction method [64].

(b)

(c)

(d)

(e)

(f)

There exist several drawbacks to the liquid-phase reduction method. First, it is relatively expensive due to the high cost of NaBH₄ [52]. Second, NaBH₄ may destroy some chemical bonds in Mt or Bt, resulting in a change of the proportion of Mt or Bt [50]. Third, the nZVI is hard to be evenly distributed on the template surfaces. For example, Wang et al. [53] prepared Mt-nZVI and observed that more nZVI particles were dispersed at the edge of the Mt, and few particles were distributed in the middle part of Mt. This ununiform distribution of nZVI on template surfaces could affect the mobility of the composite in the environment because the distribution morphology of nZVI on the template surfaces influences the interaction energy between the composite and the collector surfaces and accordingly the attachment.

2.2.2. Heteroaggregates of Mt with nZVIs

Yin et al. [15] presented a novel technique to prepare Mt-nZVI based on the liquid-phase reduction method. Specifically, nZVI colloidal suspension was first synthesized by the liquid-phase reduction reaction [54], and the nZVIs were allowed to attach to surfaces of Mt in solutions in a monolayer (Figure 3(b)). The Mt solution was prepared by sedimentation siphon separation [55]. The SEM images of Mt-nZVI synthesized by this method showed that the nZVI particles were evenly distributed on the Mt surfaces in a monolayer (Figure 4(b)) [15].

In this approach, the sizes of nZVI particles could be changed via the liquid-phase reduction method and the concentration of the attached nZVI particles on Mt could be controlled by varying experimental conditions (e.g., the ratio of concentrations of Mt and nZVI in suspension) [15]. The fabricated heteroaggregates of nZVIs with Mt had a unique micro/nanostructure. This structure favors the heteroaggregates to attach to collector surfaces and then detach even with a minor change of system conditions [56, 57]. Therefore, the Mt-nZVI has great mobility in the subsurface environments through continuous capture and release, showing the promise for the in situ treatment of contaminants in soil [15]. Note that the previous method can also change the sizes of nZVI particles by changing experimental conditions.

2.2.3. Green Synthesis

The chemical synthesis methods of Mt-nZVI may lead to toxic chemicals (e.g., borohydride) absorbed on their surfaces [58]. Alternatively, the green synthesis method used plant extracts containing naturally derived polyphenolic compounds (instead of NaBH₄) as reducing agents to synthesize Mt-nZVI [59]. For example, Soliemanzadeh and Fekri [60] used green tea extracts to prepare Bt-loaded “green” nZVI. The green tea extract solution was prepared by heating the plant extracts to a temperature close to the boiling point, and then it was mixed with the Bt and Fe²⁺ solution (Figure 3(c)). The transmission electron microscope (TEM) images (Figures 4(e) and 4(f)) indicated that nZVIs were successfully supported on the Bt surface. Moreover, the composite material prepared by this method was found to be effective for the adsorption of Cr(VI) in contaminated soil and aqueous environments.

The green synthesis method has the following advantages. First, plant extracts can better stabilize the reaction surface of nanoparticles than NaBH₄ and decrease their biotoxicity [52]. Second, excess polyphenols in solution during preparation could encapsulate the synthesized Mt-nZVI and prevent its further oxidation [58]. Third, the use of natural active biological components can reduce the total cost of the synthesis process [61]. However, it should be noted that plant extracts may not completely reduce iron to nZVI, resulting in other forms of iron on template surfaces. Moreover, the preparation method of “green” extracts is relatively complicated, and the disposal of residues after extraction needs to be addressed [62]. These limitations decrease the application of green synthesis [28].

2.2.4. Thermal Reduction Method

Mt-nZVI can also be obtained through the thermal reduction of iron compounds [28]. In this method, the thermal energy and gaseous reducing agents were adopted to drive the reduction of iron oxide or hydrous Fe²⁺ at elevated temperatures in the presence of Mt [63]. For instance, Yang et al. [64] added an aqueous dispersion of Mt to the mixture of ferric nitrate and sodium carbonate to synthesize iron-pillared Mt (Fe-Mt) [65] and obtained Fe⁰-Mt composites (Fe-Mt-H₂) through thermal reduction under mixed H₂ and N₂ atmosphere (Figure 3(d)). The SEM images of Fe-Mt showed that small needle-like Fe particles attached to the surface of Mt (Figure 4(e)). With high-temperature pyrolysis, small needle-like protrusions distributed on the Mt surfaces partially turned into large cube-like particles (Figure 4(f)). Compared with Mt-nZVI prepared by the aforementioned liquid-phase reduction, Fe-Mt-H₂ embedded more Fe⁰ in Mt with larger sizes, which might be more difficult to be oxidized.

The thermal reduction method is cheaper and energy-saving because it does not require NaBH₄ for Fe ion reduction compared to the liquid-phase reduction method. The production of toxic chemicals is also avoided [12]. The method is also environmentally friendly because only gaseous products are generated [28]. However, this method requires high-temperature conditions, which is energy-consuming and may bring potential risks during the preparation [31].

Although the cost of producing Mt-nZVI has been reduced, large-scale preparation and application are still expensive. Further improvement is thus necessary to produce high-quality, low-cost, and environmentally friendly Mt-nZVI. For example, it is vital to develop some cheap and environmentally friendly reducing agents to replace NaBH₄. Additionally, different modifying agents can be used to introduce various functional groups into the Mt interlayer to increase Mt-nZVI’s adsorption activity to target contaminants [66].

2.3. Advantages of Using Mt to Support nZVI

The clay minerals are nontoxic, low cost, and environmentally friendly. Moreover, they have a high surface area and adsorption ability [67, 68]. A number of studies demonstrated that the adsorption capacity of Mt was stronger than that of other clay minerals [69–71]. Furthermore, the combination of Mt and nZVI can result in a synergetic effect between adsorption by the Mt and removal by nZVI particles [31]. There are several advantages of using Mt to support nZVI, such as improvement of the dispersion and mobility and reduction of the particle size and oxidation tendency [21, 26]. These advantages will be elaborated on in detail in the following.

2.3.1. Increased Dispersion

Typically, the bare nZVI particles were spherical and formed prominent chainlike aggregates; adding Mt into nZVI can improve the dispersibility of nZVI [19]. Several possible reasons have been used to explain the increased dispersion of nZVI in Mt. First, during the preparation of the Mt-nZVI, Fe³⁺(or Fe²⁺) is uniformly absorbed into the interlayer of Mt through ion exchange [19]. This can control the nucleation of nZVI clusters produced by the reduction of Fe³⁺(or Fe²⁺) and limit the growth of particles, thereby preventing the aggregation of nZVI clusters [72]. Second, the interlaminar distance (between clay sheets) of Mt clay is between 0.1 and 0.8 nm, which creates an ideal template to carry nZVI clusters (Figure 2) [18]. Adding nZVI into Mt can increase its interlayer spacing. The basal spacing of Mt-nZVI calculated by Pang et al. [73] was 2.450 nm, which was 0.571 nm larger than that of Mt. This phenomenon might be explained by the fact that the hydration radius of Fe³⁺ was much larger than that of Na⁺, and when Na⁺ was replaced by Fe³⁺, the interlayer spacing of Mt was increased. In short, the nZVI clusters have intercalated the interlayers of Mt and acted as pillars, thus expanding the interlayer distance. In addition, the surface area of Mt is much larger than that of nZVI, which can significantly increase the surface dispersion of nZVI [21]. Third, as a 2 : 1 layer silicate due to the swelling of the interlayer, the layers in Mt are separated into discrete single-layer units, which make Mt highly accessible in the suspension to some extent, thereby enhancing the reactivity of Mt-nZVI [72, 74]. Notably, the nZVI aggregation decreased as Mt loadings increased [22, 68, 75].

2.3.2. Small nZVI Size

The presence of templates such as Mt or Bt can reduce particle sizes of nZVI [76]. For example, Arancibia-Miranda et al. [77] found that the average diameter of Mt-nZVI was 9.3 nm, which was smaller than that of nZVI (16.9 nm). The X-ray diffraction (XRD) patterns from Peng et al. [26] have shown that the peak value of the organo-Mt- (OMt-) supported nZVI (OMt-nZVI) was weaker and broader at 44.78° compared with that of bare nZVI (Figure 5(a)), indicating the smaller crystallite size of nZVI within OMt-nZVI. The sizes of nZVI can be further decreased with the increase of the mass ratios of Mt/iron [68, 75, 76].

Figure 5

XRD patterns of (a) (A) OMt, (B) OMt-nZVI, and (C) nZVI [26] and (b) (A) nZVI, (B) Mt-nZVI, (C) K-Mt-supported nZVI (K-Mt-nZVI), and (D) starch-stabilized K-Mt-nZVI [21].

(b)

Smaller size of nZVI means larger SSA and stronger adsorption capacity [34]. Compared with Mt, the SSA of Mt-nZVI is increased as a result of massive nZVI particles supported on the surface or interlayers of Mt [24, 36]. Although the SSA of Mt-nZVI is lower than that of nZVI, the stability and reactivity of nZVI are stronger after being monodispersed on Mt [68].

2.3.3. Improved nZVI’s Stability against Oxidization

The nZVI is easily oxidized when exposed to the air, which greatly affects its reducibility [72]. Mt can reduce the surface corrosion of nZVI and improve its stability [12]. According to the XRD results of Mt-nZVI by Zhang et al. [21] (Figure 5(b)), the characteristic peaks of iron oxide were not observed, indicating that the nZVI particles were not oxidized or only a small part of them was oxidized to form amorphous iron oxide. Rao et al. [78] investigated the antioxidant abilities of Mt-nZVI and nZVI by observing their color changes in the air at different time slots. The black nZVI solution totally turned yellow at 72 h, while only a small part of the Mt-nZVI solution turned yellow, revealing that nZVI loaded on Mt was more difficult to be oxidized compared to pristine nZVI. This phenomenon can be explained by the fact that Mt has a layered structure, and when the nZVIs are inserted in the interlayer of Mt, they were not readily available for oxidization [25].

Li et al. [79] found that fewer oxides were formed on Bt-nZVI compared to nZVI. The removal efficiency of Se(VI) by Bt-nZVI only decreased 3.7% after four cycle experiments. The results indicated that Bt-nZVI displayed much higher stability and reusability than nZVI, which was partly due to the fact that Bt inhibited the oxidation of nZVI. Another possible reason was the buffering effect of some particular functional groups of Bt [79]. Moreover, when Fe₂O₃ was formed and precipitated on the surfaces of nZVI during the reaction of Bt-nZVI with contaminants, Bt could help to transfer some precipitates from nZVI surfaces and prolong the reactivity of nZVI [65].

2.3.4. Other Advantages

Tomasevic et al. [67] and Kerkez et al. [69] demonstrated that the total pore volume of the Mt-nZVI was larger than that of Mt and nZVI. This is because of the formation of more mesoporous structures by the intercalated nZVI, which enhanced the diffusion and adsorption of contaminants [26]. In addition, the introduction of Mt may improve the sustainability of nZVI, inhibit the rapid consumption of nZVI, and ultimately enhance the service life of composite materials [19]. Finally, Bt-nZVI has higher stability (lower sedimentation) and greater mobility in porous media than nZVI [80]. For example, Shi et al. [68] conducted column experiments and revealed that the sedimentation rate of Mt-nZVI was greatly decreased and its mobility was significantly increased compared with that of bare nZVI. This is because the zeta potentials of nZVI particles changed from positive to negative after the addition of Mt, which led to the repulsive interaction between Bt-nZVI and quartz sand [80].

3. The Reaction Mechanisms of Mt-nZVI

There are four typical pathways to remove contaminants by Mt-nZVI (Figure 6), including adsorption [19, 81, 82], reduction [18, 26, 83], precipitation [16, 21], and oxidation [44]. These mechanisms can occur simultaneously or sequentially when using them to remove contaminants. Particularly, adsorption is commonly the major removal mechanism for Mt, while reduction is the main mechanism for the nZVI [18, 19]. These processes are described in detail in the following.

Figure 6

Schematic model of reaction mechanisms of Mt-nZVI with various contaminants.

Adsorption has been considered a typical reaction process for contaminant removal by Mt-nZVI. As mentioned above, Mt-nZVI has small particle sizes, large SSA, and abundant active sites due to functional groups, which have a great ability for adsorbing many contaminants [15]. Additionally, nZVI has a core-shell structure (Figure 6). Specifically, the core is mainly nZVI, and the shell is the product due to oxidation of the nZVI. The shell can be oxidized to Fe²⁺ (fast process) and further to Fe³⁺ (slower process) by dissolved oxygen in aqueous media according to Equations (3) and (4) [30]: $\begin{matrix} (3) & 2 F e^{0} + O_{2} + 2 H_{2} O ⟶ 2 F e^{2 +} + 4 O H^{-} \\ (4) & 4 F e^{2 +} + O_{2} + 4 H^{+} ⟶ 4 F e^{3 +} + 2 H_{2} O \end{matrix}$

The outer oxidized layer of nZVI will thicken once exposed in water or air even if this process is reduced due to the Mt. This positively charged layer can act as an efficient adsorbent for various contaminants with negative charges through electrostatic interaction [27]. Reduction was regarded to be the main mechanism of contaminant removal by Mt-nZVI, in which nZVI plays as an electron provider [33, 84]. Generally speaking, the removal mechanisms of Mt-nZVI on heavy metals depend on its $E^{0}$ (Table 3) [29]. The heavy metals with more positive standard redox potential ( $E^{0}$ ) than nZVI ( $E^{0} = - 0.44 V$ ) such as Pb(II) and Ni(II) can be removed by reduction and adsorption [85]. For example, Wang et al. [34] showed that Mt-nZVI could remove Pb(II) to Pb⁰ by reduction and adsorption. First, Pb(II) ions were absorbed on the surface of Mt-nZVI (Equations (5) and (6)). Then, it was converted to Pb⁰ through reduction by nZVI (Equation (7)) [34]: $\begin{matrix} (5) & {Pb}^{2 +} + Mt ⟶ {Pb}^{2 +} - Mt \\ (6) & {Pb}^{2 +} + {Fe}_{x} O_{y} H_{z} ⟶ {Pb}^{2 +} - {Fe}_{x} O_{y} H_{z} \\ (7) & {Pb}^{2 +} - Mt (or P b^{2 +} - {Fe}_{x} O_{y} H_{z}) + 2 e^{-} ⟶ {Pb}^{0} - Mt (or P b^{0} - {Fe}_{x} O_{y} H_{z}) \end{matrix}$

Table 3

The standard redox potentials ( $E^{0}$ ) of heavy metals at 25°C [29].

Heavy metal	$E^{0}$ (V)	Half reactions	Removal mechanism	Reference
Zn	-0.76	$Z n^{2 +} \leftrightarrow Z n^{2 +}$	Adsorption	[68]
Fe	-0.44	$F e^{2 +} + 2 e^{-} \leftrightarrow Fe$	Reduction	[29]
Ni	-0.23	$N i^{2 +} + 2 e^{-} \leftrightarrow Ni$	Reduction and adsorption	[85]
Pb	-0.13	$P b^{2 +} + 2 e^{-} \leftrightarrow Pb$	Reduction and adsorption	[108]
U	0.27	$U {O_{2}}^{2 +} + 4 H^{+} + 2 e^{-} \leftrightarrow U^{4 +} + 2 H_{2} O$	Reduction and precipitation	[25]
Cu	0.34	$C u^{2 +} + 2 e^{-} \leftrightarrow Cu$	Reduction and precipitation	[88]
As	0.56	$H_{3} As O_{4} + 2 H^{+} + 2 e^{-} \leftrightarrow HAs O_{2} + 2 H_{2} O$	Reduction and precipitation	[76]
Cr	1.36	$C r_{2} {O_{7}}^{2 -} + 14 H^{+} + 6 e^{-} \leftrightarrow 2 C r^{3 +} + 7 H_{2} O$	Reduction and precipitation	[16]

When the $E^{0}$ of the compound is smaller or similar to that of nZVI, Mt-nZVI removes it purely by adsorption. For example, due to the fact that $E^{0}$ of Zn(II) is much smaller than that of nZVI, Fe⁰ cannot reduce it into Zn⁰, but it is absorbed and deposited on the Mt-nZVI in the form of Zn(II) [53, 68, 81]. In contrast, the reduction reaction of Mt-nZVI occurs for heavy metals with higher $E^{0}$ (e.g., Cr(VI) is preferentially reduced in the presence of nZVI) [12]. Interestingly, Mt-nZVI can reduce nitrate to ammonium and nitrogen gas (Equations (8)–(10)) [86]: $\begin{matrix} (8) & {Fe}^{0} + {NO}_{3}^{-} + 2 H^{+} ⟶ {Fe}^{2 +} + H_{2} O + {NO}_{2}^{-} \\ (9) & 3 F e^{0} + {NO}_{2}^{-} + 8 H^{+} ⟶ 3 F e^{2 +} + 2 H_{2} O + {NH}_{4}^{+} \\ (10) & 3 F e^{0} + 2 N {O_{2}}^{-} + 8 H^{+} ⟶ 3 F e^{2 +} + 4 H_{2} O + N_{2} (g) \end{matrix}$

This means that Mt-nZVI may help to reduce the amount of total nitrogen in the water. Mt-nZVI can also provide electrons for the reduction of halogenated organics. The halogenated organics are reduced to the olefins and alkane by reductive dehalogenation (Equations (11) and (12)) [8]: $\begin{matrix} (11) & {Fe}^{0} ⟶ {Fe}^{2 +} + 2 e^{-} \\ (12) & R - X + H^{+} + 2 e^{-} ⟶ RH + X^{-} \end{matrix}$

The reaction involves the adsorption of contaminants onto the Mt-nZVI surface and subsequent breakage of the carbon-halogen bonds [52]. Based on the reductive dehalogenation, Mt-nZVI could remove chlorinated and brominated organics [19, 31].

The precipitation mechanism may occur between heavy metals and iron ions. This can significantly decrease the toxicity and mobility of heavy metals since the formed precipitation is stable [87]. For instance, Cr(VI) can be removed by Mt-nZVI through adsorption, reduction, and precipitation [16, 36, 43, 81]. The reaction includes (1) the adsorption of Cr(VI) on the surface of Mt-nZVI, (2) the reduction to Cr(III) with the oxidation of nZVI to Fe³⁺, and (3) the formation of chromium hydroxide or chromium iron hydroxide precipitation (Equations (13) and (14)): $\begin{matrix} (13) & {Cr}_{2} {O_{7}}^{2 -} + 2 F e^{0} + 14 H^{+} ⟶ 2 C r^{3 +} + 7 H_{2} O + 2 F e^{3 +} \\ (14) & {Cr}^{3 +} + {Fe}^{3 +} + 6 O H^{-} ⟶ Cr {(OH)}_{3} + Fe {(OH)}_{3} \end{matrix}$

Mt-nZVI can also remove U(VI), Cu(II), Se(IV), and As(V) through above processes [25, 33, 82, 88]. In some special environmental remediation systems (e.g., the Fe⁰–H₂O mixture system), oxidation is also a possible reaction mechanism. Mt-nZVI can degrade and oxidize a series of organic compounds in the presence of oxidants. For example, Diao et al. [22, 23] used Bt-nZVI as a catalyst to activate persulfate for the removal of phenol. The results indicated that the presence of persulfate in Bt-nZVI could significantly promote the oxidation of phenol. The reaction mechanisms include the following: (1) SO₄ ^2- was formed by the reaction of aqueous Fe²⁺ with persulfate, and (2) phenol was degraded by SO₄ ^2- and hydroxyl radicals (^⋅OH). These processes can be described in the following equations: $\begin{matrix} (15) & 2 F e^{0} + O_{2} + 4 H^{+} ⟶ 2 F e^{2 +} + 2 H_{2} O \\ (16) & {Fe}^{2 +} + S_{2} {O_{8}}^{2 -} ⟶ {Fe}^{3 +} + {SO}_{4}^{-} + {SO}_{4}^{2 -} \\ (17) & H_{2} O + {SO}_{4}^{-} ⟶ {HSO}_{4}^{-} + {}^{•}O H \\ (18) & Phenol + {SO}_{4}^{-} / {}^{•}O H ⟶ oxidation product \end{matrix}$

Bao et al. [89] added H₂O₂ when using Mt-nZVI to remove bisphenol A. They found that the bisphenol A degradation mechanism might involve a couple of adsorption reactions with the Fenton-like reaction (e.g., a reaction system made up of H₂O₂ and Fe²⁺). The combination of H₂O₂ and Fe²⁺ could generate ^⋅OH, which had a strong capability to oxidize a variety of organic compounds (Equations (19) and (20)) [1]: $\begin{matrix} (19) & {Fe}^{0} + H_{2} O_{2} + 2 H^{+} ⟶ {Fe}^{2 +} + 2 H_{2} O \\ (20) & {Fe}^{2 +} + H_{2} O_{2} ⟶ {Fe}^{3 +} + {}^{•}O H + {OH}^{-} \end{matrix}$

Kerkez et al. [56] reported that the heterogeneous Fenton oxidation system was considerably superior in dye decolorization than the reduction degradation mechanism. Chen et al. [65] used Fe-pillared Mt as a heterogeneous photo-Fenton catalyst to enhance the degradation efficiency of dyes. However, under common natural environmental conditions, oxidation is rare for the removal of contaminants by Mt-nZVI [90].

The synergistic effect between nZVI and Mt on the removal of many contaminants has been reported [50, 79]. For example, the removal efficiency of Mt-nZVI for Cr(VI) (99%) is even better than the sum (72%) of individual removal efficiency of nZVI and Mt (66% and 6%, respectively) [81]. The synergistic effect is due to several reasons. First, as mentioned previously, the Mt can decrease the size of nZVI and enhance the dispersity of nZVI, thus providing more effective electron donors and active sites [18]. Second, the Mt of Mt-nZVI can facilitate the capture of contaminants from the solution on the Mt-nZVI surfaces through exchange and adsorption due to its high cation exchange capacity and SSA [50]. For example, the negatively charged Mt can attract cationic contaminants (such as Pb, Cd, and Cu) via electrostatic attraction and promote the mass transfer of these contaminants from the solution to the nZVI surface, thereby improving the removal efficiency [33]. Third, the pH buffering effect of silanol groups in the Mt may also promote the synergetic effect of Mt on the reduction of contaminants by nZVI [79]. Finally, the interlayer of raw Mt can be modified by cation exchange reaction. Therefore, the surface and structure of Mt can be adjusted to create properties compatible with various contaminants [33], which will be discussed in Section 5.

4. Factors Affecting Mt-nZVI Reactivity

When applying Mt-nZVI for water and soil remediation, the reactivity of Mt-nZVI with contaminants is dependent on a variety of environmental conditions (e.g., pH, temperature, and dosage of the adsorbent). The impact of environmental factors on the removal of contaminants by Mt-nZVI is frequently examined using experimental methods such as batch and column techniques [15]. Understanding the impact of environmental conditions is critical to optimizing the procedure for the removal of contaminants via Mt-nZVI.

4.1. pH

The pH value can change the surface properties of Mt-nZVI and species of the molecules or irons, thereby affecting the removal efficiency [90]. First, the surface equipotential point of Mt-nZVI and accordingly the affinity for contaminants change with pH [47]. When Mt is dispersed in the aqueous solution, the Si-O and Al-O bonds in the crystal lattice can be broken [50]. When the aqueous solution is acidic, the broken bond will adsorb H⁺ ions, resulting in positive charges of the crystal lattice. In contrast, the bond is adsorbed by the OH^- and the lattice is negatively charged under alkaline conditions [80, 83]. Hence, Mt-nZVI has a stronger adsorption capacity for cationic contaminants at higher pH values (e.g., Co(II) [49], U(VI) [25], Zn(II) [53], and Pb(II) [50, 77]). In addition, nZVI in the solution will form a passive film of iron hydroxide at a higher pH value, further enhancing the adsorption of cationic contaminants [36]. At a low pH value, Mt-nZVI has a stronger adsorption capacity for anionic contaminants (e.g., Cr(VI) [43, 53, 80], phenol [22, 89], halogenated organic contaminants [42, 73], nitrobenzene [70], and acid dyestuff [24, 69, 74, 78]). More H⁺ can promote the reaction and consume more nZVIs, and the nZVI corrosion produces abundant hydrogen at lower pH values, which may support the hydrogenation reaction between organic compounds and hydrogen [45]. Notably, the pH not only changes properties of Mt-nZVI but also affects the charges of target contaminants (e.g., HCrO₄ ⁻ ( $pH = 2 ‐ 5$ ), Cr₂O₇ ²⁻ or CrO₄ ²⁻ ( $pH > 5$ )) [62].

4.2. Temperature

Temperature can change the energy of the reaction system, thus influencing contaminant removal efficiency by Mt-nZVI [90]. For example, Shi et al. [81] found that 82.4% of Cr(VI) was removed by Mt-nZVI at 40°C, while only 73.4% of Cr(VI) was reduced at 25°C in 60 min. A possible explanation was that high temperature could facilitate the molecular thermodynamic movement and average kinetic energy of contaminants [46]. The increase in the removal efficiency with increasing temperature was observed for degradation of organic contaminants, such as sulfamethazine [44], methyl orange [24], and amoxicillin [91] by OMt-nZVI. Overall, increasing temperature has a positive effect on the ability of Mt-nZVI to adsorb contaminants, which favors in situ remediations of the environment.

The thermodynamic parameters (e.g., change in free energy ( $Δ G$ ), enthalpy change ( $Δ H$ ), and change in entropy ( $Δ S$ )) can reveal the reaction mechanisms [92]. For example, the thermodynamic study by Wang [92] demonstrated that the adsorption of rare earth elements by Mt-nZVI was spontaneous based on the negative $Δ G$ values and exothermic since the value of $Δ H$ was negative. In addition, the randomness of the system after adsorption was decreased (negative value of $Δ S$ ). Moreover, the adsorption reaction of Pb(II) and Cr(VI) on Mt-nZVI was spontaneous ( $Δ G < 0$ ) and exothermic ( $Δ H < 0$ ) [15, 34].

4.3. Dosage of the Adsorbent

The dosage of Mt-nZVI has a significant impact on the removal of contaminants. Shi et al. [51] presented that the removal efficiency of Cr(VI) by 3 g L^-1 of M-nZVI was 100% after contacting for 3 h at pH 5, while only 54.6% Cr(VI) was removed when Bt-nZVI concentration was 1 g L^-1. This observation could be explained by the fact that for a given condition, the increase in the dosage of Mt-nZVI increased the surface area and adsorption sites of Mt-nZVI, which promoted the reduction of contaminants [50, 60, 91, 93–95]. Using an optimum dosage of the adsorbent is also of great significance for saving application costs [90].

Wu et al. [44] observed that the sulfamethazine degradation increased from 58% to 97% with 10 min interaction when the OMt-nZVI dose increased from 0.15 mM to 1.5 mM. However, if the OMt-nZVI further increased from 1.5 mM to 12 mM, the degradation of sulfamethazine was reduced from 97% to 35%. Similarly, when the dose of Bt-nZVI exceeded 2 g L^-1, the removal efficiency of chemical oxygen decreased slightly in wastewater [96]. This is likely because more Mt-nZVI dosage would induce greater aggregation of the Mt-nZVI, causing the decrease of the SSA and its dispersibility [22, 69].

4.4. Other Factors

The initial concentration of contaminants influences the relative adsorption sites of Mt-nZVI [16, 32, 74, 83]. Dissolved oxygen controls the adsorption capacity of Mt-nZVI by controlling the oxidation degree of nZVI particles [24, 73]. In addition to these factors, inorganic anions [44], reaction time [73], ionic strength [16, 32, 60], natural organic matter (e.g., humic acid), and other ions [67] have an influence on the activity of Mt-nZVI. However, due to the complexity of soil and water environments, the factors that influence the removal of contaminants by Mt-nZVI are not fully elucidated to date. Hence, further research is still necessary to identify the impact factors and to reveal the coupled influence of these factors on the removal of the contaminants in soil and water environments.

5. Remediation of Contaminated Water and Soil

5.1. Remediation of Contaminated Water

5.1.1. Heavy Metals

Heavy metals enter the environment mainly through industrial production. They are difficult to be biodegraded and tend to accumulate in living organisms, thus posing a high potential risk to the ecosystem and human body [32]. Mt-nZVI has been applied to successfully remove heavy metals such as Pb(II), Zn(II), Cu(II), and particularly Cr(VI) in laboratory studies (Table 2).

Yin et al. [15] examined the removal of Cr(VI) by Mt-nZVI. They found that the adsorption data was well described by the Langmuir model and pseudo-second-order kinetics (Table 4). The Cr(VI) was retained on the Mt-nZVI surface in a monolayer through chemical adsorption [60]. However, Shi et al. [51] showed that the removal of Cr(VI) by Bt-nZVI followed pseudo-first-order reaction kinetics. To improve the removal efficiency of Cr(VI) by Mt-nZVI, Mt or nZVI was modified [43, 95]. For example, Wu et al. [43] reported better removal capacity for Cr(VI) (109.9 mg g^-1) by HDTMA-modified Mt-supported nZVI compared to Mt-nZVI (90.9 mg g^-1) (Table 2). Wang et al. [95] fabricated Bt-supported organosolv lignin-stabilized nZVI and found that lignin could improve the loaded quantity and dispersity of nZVI. The Cr(VI) removal efficiency could reach 62.3% when the dosage of this fabricated structure was 1.0 g L^-1 and initial Cr(VI) concentration was 50 mg L^-1, which was higher than that of Bt-nZVI (56.8%).

Table 4

Fitting results for the adsorption kinetic and isotherm models of contaminant removal by Mt-nZVI.

Material	Contaminants	Adsorption kinetic model	Adsorption isotherm model	Reference
Mt-nZVI	Cr(VI)	Pseudo-second-order	Langmuir	[15]
OMt-nZVI	Cr(VI)	Pseudo-second-order	—	[43]
Bt-nZVI	Cr(VI)	Pseudo-first-order	—	[51]
Bt-nZVI	Cr(VI)	Pseudo-second-order	Langmuir	[60]
Mt-nZVI	Pb(II)	Pseudo-second-order	Langmuir	[77]
Mt-nZVI	Pb(II)	Pseudo-second-order	Freundlich	[34]
Mt-nZVI	Zn(II)	Pseudo-second-order	Freundlich, Temkin, and Dubinin–Radushkevich	[34]
Bt-nZVI	Cu(II) and Zn(II)	Pseudo-first-order	—	[68]
Bt/graphene-supported nZVI	Cu(II)	Pseudo-second-order	—	[88]
Bt-nZVI	U(VI)	Langmuir–Hinshelwood	—	[25]
Mt-nZVI	U(VI)		Langmuir	[71]
Pillared Bt-supported nZVI	NO₃ ^-	Langmuir–Hinshelwood	—	[86]
Cetyltrimethylammonium bromide-modified Mt-supported nZVI	Decabromodiphenyl ether	Pseudo-first-order	—	[73]
Cetyltrimethylammonium-modified Bt-supported nZVI	Chlorophenols	Langmuir–Hinshelwood	Langmuir	[66]
Cetyltrimethylammonium-modified Bt-supported nZVI	Pentachlorophenol	Langmuir–Hinshelwood	—	[40]
Bt-nZVI	Acid violet red B	Pseudo-first-order	—	[74]
Bt-nZVI	Methyl orange	Pseudo-first-order	—	[24]
Mt-nZVI	Rhodamine 6G	Pseudo-first-order	—	[78]
Bt-nZVI	Se(VI)	Langmuir–Hinshelwood	—	[79]
Mt-nZVI	Se(VI)	Pseudo-first-order	Freundlich	[76]
Mt-nZVI	As(V)	Pseudo-second-order	Freundlich	[76]
Cetyltrimethylammonium-modified Bt-supported nZVI	Nitrobenzene	Langmuir–Hinshelwood	—	[41]

Arancibia-Miranda et al. [77] observed that the maximum Pb(II) adsorption capacity on Mt-nZVI was $115.1 \pm 11.0 mg g^{- 1}$ , and the reaction followed the pseudo-second-order kinetic model and the Langmuir model. Wang et al. [34] examined the adsorption of Zn(II) and Pb(II) by Mt-nZVI. The adsorption data of Zn(II) followed the Freundlich, Temkin, and Dubinin–Radushkevich isotherm models, meaning the copresence of physical and chemical adsorption. The Pb(II) adsorption process was chemisorption, and the reaction data was described by the Freundlich isotherm model. Shao et al. [88] presented that the removal efficiency of Cu(II) ( $C_{0} = 100 mg L^{- 1}$ ) was 82% in Bt- and graphene oxide-supported nZVIs (1 g L^-1) within 16 h. The adsorption data followed the pseudo-second-order kinetic model.

The applications of Mt-nZVI for the treatment of industrial wastewater have been reported. For example, Shi et al. [68] used Bt-nZVI to remediate electroplating wastewater and found that 100% Pb(II), 92.7% Cu(II), and 59.4% Zn(II) were removed within 1 h by 10 g L^-1 Bt-nZVI. Wang et al. [97] studied the remediation effect of Bt-nZVI on leachate wastewater originating from Cr-polluted soil. The results indicated that 90% Cr(VI) from leachate wastewater with an initial concentration of 52.89 mg L^-1 Cr(VI) could be removed within 10 min using 3 mg g^-1 of Bt-nZVI.

5.1.2. Uranium

U(VI), as a radioactive and toxic heavy metal, has relatively high solubility and mobility in the environment. Therefore, it readily invades the food chain [93]. Previous laboratory work demonstrated that soluble uranium compounds could be removed by using Mt-nZVI to reduce U(VI) to less-soluble U(IV) [25, 32, 33]. For example, Sheng et al. [25] revealed that the adsorption data of U(VI) on Bt-nZVI followed the Langmuir–Hinshelwood model, and the removal efficiency of U(VI) (100 mg L^-1) reached 99.2% after 90 min when using 0.2 g L^-1 Bt-nZVI. Kornilovych et al. [71] used clay (e.g., kaolinite, Mt, and palygorskite)-supported nZVI to remove U(VI) from mineralized groundwater. They found that the adsorption process was better described by the Langmuir model. Mt-nZVI had the highest adsorption capacity (about 120 mg g^-1), which might be related to the high dispersibility of the Mt sample in the aqueous solution. Xu et al. [32] reported 97.8% U(VI) (100 mg L^-1) removal by Mt-nZVI (0.1 g L^-1) within 30 min at $pH = 3.0$ . The aforementioned work indicated that Mt-nZVI was suitable for the removal of U(VI) from the aqueous solution.

5.1.3. Nitrate

Nitrate (NO₃ ^-) is widely presented in the surface and groundwater due to the widespread use of nitrogen fertilizers and improper treatment of industrial wastewater, causing deterioration of water quality, eutrophication of rivers, and toxicities to organisms [98]. Numerous laboratory studies have shown that the nitrate can be reduced by Mt-nZVI [20, 86, 99]. Zhang et al. [86] combined nZVI and pillared Bt (prepared by intercalation with poly(hydroxo Al(III)) cations) to remove NO₃ ^- from the aqueous solution. The adsorption data was fitted well to the Langmuir–Hinshelwood model. This composite could completely remove NO₃ ^- at pH 7.0 within 120 min. The nZVI could only remove 62.3% NO₃ ^- under the same condition. Zhao et al. [99] used Mt-nZVI immobilized in sodium alginate (SA/Mt-nZVI) as electron donor-acceptor compounds to enhance the nitrogen (NO₃ ^--N) removal from constructed wetland (CW). The removal efficiency of NO₃ ^--N ( $C_{0} = 60 mg L^{- 1}$ ) by 0.67 mg L^-1 SA/Mt-nZVI in CW was $32.60 \pm 1.9 %$ at pH 7, which was higher than that by CW without adding sodium alginate. The introduction of SA/Mt-nZVI could enhance the biological diversity and richness in CW. These results meant that it might be feasible to add SA/Mt-nZVI as a carbon source to treat low C/N-polluted water.

5.1.4. Halogenated Organic Compounds

Halogenated organic compounds are widely present in industrial wastewater. They have persistence, lipophilicity, high toxicity, and carcinogenicity [100]. They are difficult to be biodegraded and can be enriched in aquatic organisms [101]. Batch experiments have shown that Mt-nZVI could successfully degrade a large number of halogenated organics, such as chlorinated and brominated organics [19, 31]. For example, Pang et al. [73] demonstrated that the removal efficiency of decabromodiphenyl ether ( $C_{0} = 2 mg L^{- 1}$ ) by CTMAB-modified Mt-supported nZVI (0.6 g L^-1) was 98.02%. The adsorption data fitted well to pseudo-first-order reaction. Yu et al. [42] applied TMA-modified smectite-supported nZVI (4 g L^-1) to reduce 2.5 mg L^-1 of DBDE. After a 9 h reaction, >80% DBDE was removed. This composite was shown to be much faster and more efficient for debromination compared to nZVI. Li et al. [40] immobilized CTMA onto Bt to load nZVI. They found that this novel composite had good stability and reusability, which could quickly and completely dechlorinate chlorophenols. The equilibrium adsorption was well described by the Langmuir and Langmuir–Hinshelwood kinetic models.

Recently, nZVI was sulfurated to accelerate reduction efficiency for organochlorine compounds and maintain the stability of composite material in water [102]. For instance, Mt-supported sulfurated nZVI (Mt-S-nZVI) was synthesized [102] and exhibited higher removal efficiency for trichloroethylene (78.7%) than sulfurated nZVI and Mt-nZVI. Even aging for 30 days, Mt-S-nZVI could still retain 68.1% of trichloroethylene.

5.1.5. Dyes

Dyes include high levels of organic contaminants with deep colors. Their degradation products may be carcinogenic and toxic to mammals [69]. Reaction using Mt-nZVI composite materials to remove dyes has become a promising method [31]. Lin et al. [74] reported that the removal efficiency of acid violet red B on Bt-nZVI was 95.6% in 9 min under the condition of 2.8 g L^-1 of Bt-nZVI and 800 mg L^-1 acid violet red B solution. This was higher than that of nZVI (75.1%). The adsorption was well fitted to the pseudo-first-order model. The degradation of azo dye methyl orange by Bt-nZVI was also fitted well to the pseudo-first-order model [24]. Kerkez et al. [69] demonstrated that Bt-nZVI had a higher adsorption capacity on degrading industrial azo dye Rosso Zetanyl B-NG compared with kaolin- and native clay-supported nZVIs. This was probably because the SSA of Bt was three times that of kaolin and natural clay (Table 2).

Mt-nZVI has been combined with microwave treatment for the decolorization of dyes. Microwave treatment can directly heat the reactant molecules and provide more energy to the reaction system, accelerating the efficiency of the degradation reaction [103]. Rao et al. [78] applied Mt-nZVI to remove Rhodamine 6G (Rh 6G) through microwave treatment and revealed that the removal amount of Rh 6G reached 500 mg g^-1 when the initial Rh 6G concentration was 5000 mg L^-1 after degradation for 15 min by 10 g L^-1 Mt-nZVI.

5.1.6. Phenolic Compounds

Phenolic derivatives are frequently detected in the wastewater generated by the petrochemical, textile, and pharmaceutical industries [104]. They are highly toxic and harmful to organisms even at low concentrations [105]. Mt-nZVI composites have been proven to be highly efficient for removing phenolic compounds in the laboratory.

Mt-nZVI coupled with oxidants (e.g., O₃, H₂O₂, peroxymonosulfate, and persulfate) can enhance the degradation of phenolic compounds [22, 26, 64]. For instance, Bao et al. [89] reported that the adsorption capacity of bisphenol A on Bt-nZVI was increased in wastewater when H₂O₂ was added. Peng et al. [26] investigated tetrabromobisphenol A and bisphenol A removal using cetyltrimethylammonium bromide- (CTMAB-) modified Mt-supported nZVI in the aqueous solution. When O₃ (4 mg L^-1) was employed as an oxidant, this composite (0.1 g L^-1) could remove up to 98.6% of tetrabromobisphenol A and 94.7% of bisphenol A during 60 min at pH 7 with an initial contaminant concentration of 10 mg L^-1. Yang et al. [64] used Fe-Mt-H₂ (0.4 g L^-1) as an activator for peroxymonosulfate activation to remove bisphenol A (25 mg L^-1) and found that more than 99.3% bisphenol A was degraded within 3 h at pH 3.

5.1.7. Other Contaminants

Ren et al. [41] used CTMA-modified Bt to load nZVI. This composite could almost completely reduce nitrobenzene to aniline. The removal followed the Langmuir–Hinshelwood equation. Wu et al. [44] assessed the persulfate activated with OMt-nZVI-degraded sulfamethazine. Sulfamethazine (20 mg L^-1) was degraded by up to 97% in 10 min by using 1.5 mM OMt-nZVI and 4 mM persulfate at pH 6.8. Additionally, Mt-nZVI also could effectively degrade atrazine [106], amoxicillin [91], and oxytetracycline [75].

The Mt-nZVI is commonly used to treat a single type of contaminant in water. However, Suazo-Hernandez [76] investigated the coremoval of Se(VI) and As(V) using Mt-nZVI. The removal of Se(VI) was fitted well to pseudo-first-order reaction, while the removal of As(V) followed pseudo-second-order reaction. The adsorption of As(V) was the chemisorption process, and the adsorption of Se(VI) was mainly through the formation of bidentate inner-sphere complexes [107]. The removal efficiency of As(V) (68.43%) was higher compared with that of Se(VI) (42.76%). This work demonstrated that Mt-nZVI was effective to simultaneously remove both oxyanions (but with a marked preference for As(V)).

5.2. Remediation of Contaminated Soil

Although nZVI has excellent removal capability for various contaminants from water, the application of nZVI for soil remediation is challenging. Firstly, due to strong magnetic attractive forces, nZVIs often aggregate into micron-sized particles (homoaggregation) or are associated with minerals and organic colloids to form heteroaggregates. These aggregates frequently have low mobility in soils [29]. Secondly, the reactivity of nZVI may be decreased when it is released into the complex soil environment [47]. It is necessary to consider the interference of various soil components and the physicochemical properties of soil during the application of the nZVIs [12]. Finally, nZVI will be oxidized in the soil [108]. As mentioned previously, adding Mt into nZVI can improve the dispersibility of nZVI and reduce the surface corrosion of nZVI. Furthermore, loading nZVI on Mt can also increase the mobility of the nZVI. This is because the attraction between nZVI particles and soil grain surfaces can be eliminated by the strong repulsion between the Mt and the surfaces [15, 69].

The advantages of using Mt-nZVI to remove contaminants from soil have been reported. For example, Soliemanzadeh and Fekri [60] used Bt-nZVI for the treatment of soil with 200 mg Cr kg^-1. The soil samples were incubated at 25°C for 5 months and extracted with diethylenetriaminepentaacetic acid solutions. They found that the Cr was effectively removed by the composite, and the adsorption followed the Langmuir model with a maximum adsorption capacity of 66.10 mg g^-1. Yu et al. [109] added ethanol to the soil slurry as an organic cosolvent to promote the degradation of decachlorobiphenyl by Bt-nZVI. The results showed that 70% of decachlorobiphenyl from the soil-water slurry containing 30 mg L^-1 of decachlorobiphenyl could be dechlorinated within 13 h using 5 g L^-1 of Bt-nZVI when the water/ethanol volume ratio was 1 : 1. Only 18% of decachlorobiphenyl was removed when ethanol was not added. This is likely because ethanol could increase the degree of decachlorobiphenyl desorption into the liquid phase, thereby enhancing the decachlorobiphenyl dechlorination with nZVI.

Tomasevic et al. [67] used Bt-nZVI and kaolinite-supported nZVI to immobilize As, Pb, and Zn in the contaminated sediment from the Nadela river basin (Serbia). They showed that kaolinite and Bt could prevent the aggregation of nZVI and enhance their mobility in soil media and the treated sediment was safe for disposal. Liu et al. [94] assessed the removal of Cr(VI) by Bt-nZVI from soil suspended liquid. The maximum removal efficiency of Cr(VI) (15.68 mg L^-1) was 99.75% at 35°C when the dosage of Bt-nZVI was 6 g L^-1 and $pH = 5$ .

6. Conclusions and Future Challenges

The use of Mt-nZVI for the removal of contaminants from water and soil has received increasing attention. The common methods to prepare Mt-nZVI include the liquid-phase reduction method, green reduction method, and thermal reduction method. The nZVI particles have also been loaded on Mt surfaces in a monolayer to form a micro/nanostructure. The introduction of Mt can improve the dispersion and mobility of nZVI and reduce the particle size and oxidation tendency. The reaction mechanisms of Mt-nZVI with contaminants include adsorption, reduction, oxidation, and precipitation. The reaction is influenced by various environmental factors including pH, temperature, dosage of the adsorbent, and natural organic matter. Mt-nZVI has been shown to have high removal efficiency for contaminants such as heavy metals, uranium, nitrates, halogenated organic compounds, dyes, and phenolic compounds. While Mt-nZVI has been shown as a promising material for water and soil remediation, future work is still necessary to fulfill the large-scale application of Mt-nZVI, as shown in the following: (i)

More attention should be paid to exploring new preparation methods of Mt-nZVI with low cost. For example, it is desired to find some cheap and environmentally friendly reducing agents to replace NaBH₄ for producing nZVI. It is also desired to develop methods to improve the adsorption performance of Mt

(ii)

The underlying mechanisms between Mt-nZVI and target contaminants at a microscale are still not very clear and required to be further elucidated using modern analytical tools such as X-ray absorption spectroscopy and atomic force microscopy

(iii)

The critical factors that affect the removal of contaminants via Mt-nZVI in soil and sediments still need to be identified. The influence mechanisms of these factors are also necessary to be elucidated

(iv)

Although Mt can improve the mobility of nZVI in soil, it is still necessary to further improve the mobility of Mt-nZVI with novel methods to improve the in situ remediation efficiency. In addition, the efficiency of soil extraction is an important problem that needs to be addressed during the remediation of contaminated soils using Mt-nZVI

(v)

Field experiments are still lacking, which are critical to assess the performance of Mt-nZVI for the in situ remediation of water and soil. Larger-scale field studies are also useful to explore the application of Mt-nZVI at a commercial scale

(vi)

It is necessary to extend the reactivity of Mt-nZVI and increase its selectivity to target contaminants. For example, adding a hydrophobic coating to nZVI may extend the reactive lifetime of Mt-nZVI. Functionalization of chemical groups with Mt-nZVI can increase their selectivity to target contaminants

(vii)

It is vital to conduct risk assessments of Mt-nZVI to ensure that they are safe while achieving their full potential because it is still not clear where they can pose a potential threat to organisms. It is also useful to develop mathematic models to simulate the transport of Mt-nZVI

Footnotes

Data Availability

All the data used to support the findings of this study is included within the article.

Conflicts of Interest

The authors declare that they have no conflicts of interest.

Acknowledgments

We acknowledge the National Natural Science Foundation of China for financial support (grant no. 41922047).

References

F. L.

Dionysiou

D. D.

Liu

The use of zero-valent iron for groundwater remediation and wastewater treatment: a review

Journal of Hazardous Materials 2014 267

9340362

194 205

10.1016/j.jhazmat.2013.12.062

2-s2.0-84892638811

24457611

Leupin

O. X.

Hug

S. J.

Oxidation and removal of arsenic (III) from aerated groundwater by filtration through sand and zero-valent iron

Water Research 2005 39

9340362

9 1729 1740

10.1016/j.watres.2005.02.012

2-s2.0-19344368248

15899271

Oehmen

Viegas

Velizarov

Reis

M. A. M.

Crespo

J. G.

Removal of heavy metals from drinking water supplies through the ion exchange membrane bioreactor

Desalination 2006 199

9340362

1-3 405 407

10.1016/j.desal.2006.03.091

2-s2.0-33746854403

Meunier

Drogui

Montané

Hausler

Mercier

Blais

J. F.

Comparison between electrocoagulation and chemical precipitation for metals removal from acidic soil leachate

Journal of Hazardous Materials 2006 137

9340362

1 581 590

10.1016/j.jhazmat.2006.02.050

2-s2.0-33748589990

16600487

Zhang

Lin

X. Q.

Chen

Z. L.

Removal of Pb(II) from water using synthesized kaolin supported nanoscale zero-valent iron

Chemical Engineering Journal 2010 163

9340362

3 243 248

10.1016/j.cej.2010.07.056

2-s2.0-77956648460

Pan

B. J.

Pan

B. C.

Zhang

W. M.

Zhang

Zheng

Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters

Chemical Engineering Journal 2009 151

9340362

1-3 19 29

10.1016/j.cej.2009.02.036

2-s2.0-67349123836

Zhang

W. X.

Nanoscale iron particles for environmental remediation: an overview

Journal of Nanoparticle Research 2003 5

9340362

3/4 323 332

10.1023/A:1025520116015

2-s2.0-0041375359

X. Q.

Elliott

D. W.

Zhang

W. X.

Zero-valent iron nanoparticles for abatement of environmental pollutants: materials and engineering aspects

Critical Reviews in Solid State and Materials Sciences 2006 31

9340362

4 111 122

10.1080/10408430601057611

2-s2.0-33947106858

Fang

Z. Q.

Qiu

X. H.

Chen

J. H.

Qiu

Degradation of the polybrominated diphenyl ethers by nanoscale zero-valent metallic particles prepared from steel pickling waste liquor

Desalination 2011 267

9340362

1 34 41

10.1016/j.desal.2010.09.003

2-s2.0-78650247881

10.

Boparai

H. K.

Joseph

O’Carroll

D. M.

Kinetics and thermodynamics of cadmium ion removal by adsorption onto nano zero valent iron particles

Journal of Hazardous Materials 2011 1986

9340362

458 465

11.

Noubactep

Care

On nanoscale metallic iron for groundwater remediation

Journal of Hazardous Materials 2010 182

9340362

1-3 923 927

10.1016/j.jhazmat.2010.06.009

2-s2.0-77955571081

20594643

12.

Wang

S. S.

Zhao

M. Y.

Zhou

Y. C.

Wang

Gao

Sato

Feng

Yin

Igalavithana

A. D.

Oleszczuk

Wang

Y. S.

Biochar-supported nZVI (nZVI/BC) for contaminant removal from soil and water: a critical review

Journal of Hazardous Materials 2019 373

9340362

820 834

10.1016/j.jhazmat.2019.03.080

2-s2.0-85064072467

30981127

13.

Wang

Meng

Liu

Wang

Brookes

Zeolite-supported nanoscale zero-valent iron: new findings on simultaneous adsorption of Cd(II), Pb(II), and As(III) in aqueous solution and soil

Journal of Hazardous Materials 2018 344

9340362

1 11

10.1016/j.jhazmat.2017.09.036

2-s2.0-85030832930

29028493

14.

Zhao

Pan

B. C.

Zhang

Polymer-supported nanocomposites for environmental application: a review

Chemical Engineering Journal 2011 170

9340362

2-3 381 394

10.1016/j.cej.2011.02.071

2-s2.0-79957511496

15.

Yin

Y. R.

Shen

C. Y.

X. Y.

Removal of hexavalent chromium from aqueous solution by fabricating novel heteroaggregates of montmorillonite microparticles with nanoscale zero-valent iron

Scientific Reports 2020 10

9340362

1 12137

10.1038/s41598-020-69244-z

32699387

16.

L. M.

Liao

L. B.

G. C.

Qin

Stability and pH-independence of nano-zero-valent iron intercalated montmorillonite and its application on Cr(VI) removal

Journal of Contaminant Hhydrology 2015 179

9340362

1 9

10.1016/j.jconhyd.2015.05.001

2-s2.0-84929994513

26011800

17.

Allen

B. L.

Hajek

B. F.

Mineral occurrence in soil environments

Minerals in Soil Environments 1989 2nd

Madison, WI

Soil Science Society of America

199 278

18.

Jia

H. Z.

Wang

C. Y.

Comparative studies on montmorillonite-supported zero-valent iron nanoparticles produced by different methods: reactivity and stability

Environmental Technology 2013 34

9340362

1 25 33

10.1080/09593330.2012.679698

2-s2.0-84872569697

19.

Jia

H. Z.

Wang

C. Y.

Adsorption and dechlorination of 2,4-dichlorophenol (2,4-DCP) on a multi- functional organo-smectite templated zero-valent iron composite

Chemical Engineering Journal 2012 191

9340362

202 209

10.1016/j.cej.2012.03.004

2-s2.0-84862822285

20.

J. F.

Y. M.

Meng

Q. L.

Removal of nitrate by zero-valent iron and pillared bentonite

Journal of Hazardous Materials 2010 174

9340362

1-3 188 193

10.1016/j.jhazmat.2009.09.035

2-s2.0-71849119183

19883977

21.

Zhang

Y. Y.

Jiang

Zhang

Xie

J. F.

The dispersity-dependent interaction between montmorillonite supported nZVI and Cr(VI) in aqueous solution

Chemical Engineering Journal 2013 229

9340362

412 419

10.1016/j.cej.2013.06.031

2-s2.0-84880115875

22.

Diao

Z. H.

X. R.

Chen

Jiang

Yang

Y. X.

Kong

L. J.

Sun

Y. X.

Hao

Q. W.

Liu

Simultaneous removal of Cr(VI) and phenol by persulfate activated with bentonite-supported nanoscale zero-valent iron: reactivity and mechanism

Journal of Hazardous Materials 2016 316

9340362

186 193

10.1016/j.jhazmat.2016.05.041

2-s2.0-84969627646

27235826

23.

Diao

Z. H.

X. R.

Jiang

Kong

L. J.

Sun

Y. X.

Hao

Q. W.

Chen

Bentonite-supported nanoscale zero-valent iron/persulfate system for the simultaneous removal of Cr(VI) and phenol from aqueous solutions

Chemical Engineering Journal 2016 302

9340362

213 222

10.1016/j.cej.2016.05.062

2-s2.0-84969245549

24.

Chen

Z. X.

Jin

X. Y.

Chen

Z. L.

Megharaj

Naidu

Removal of methyl orange from aqueous solution using bentonite-supported nanoscale zero-valent iron

Journal of Colloid and Interface Science 2011 363

9340362

2 601 607

10.1016/j.jcis.2011.07.057

2-s2.0-80052622370

21864843

25.

Sheng

G. D.

Shao

X. Y.

Y. M.

Dong

Cheng

Gao

Huang

Enhanced removal of uranium(VI) by nanoscale zerovalent iron supported on Na-bentonite and an investigation of mechanism

The Journal of Chemical Physics 2014 118

9340362

16 2952 2958

10.1021/jp412404w

2-s2.0-84899545110

24730556

26.

Peng

X. X.

Tian

Liu

S. W.

Jia

Degradation of TBBPA and BPA from aqueous solution using organo- montmorillonite supported nanoscale zero-valent iron

Chemical Engineering Journal 2017 309

9340362

717 724

10.1016/j.cej.2016.10.075

2-s2.0-84994018815

27.

Crane

R. A.

Scott

T. B.

Nanoscale zero-valent iron: future prospects for an emerging water treatment technology

Journal of Hazardous Materials 2012 211–212

9340362

112 125

28.

Stefaniuk

Oleszczuk

Y. S.

Review on nano zerovalent iron (nZVI): from synthesis to environmental applications

Chemical Engineering Journal 2016 287

9340362

618 632

10.1016/j.cej.2015.11.046

2-s2.0-84949293138

29.

O’Carroll

Sleep

Krol

Boparai

Kocur

Nanoscale zero valent iron and bimetallic particles for contaminated site remediation

Advances in Water Resources 2013 51

9340362

104 122

10.1016/j.advwatres.2012.02.005

2-s2.0-84872900875

30.

Lefevre

Bossa

Wiesner

M. R.

Gunsch

C. K.

A review of the environmental implications of _in situ_ remediation by nanoscale zero valent iron (nZVI): behavior, transport and impacts on microbial communities

Science of the Total Environment 2016 565

9340362

889 901

10.1016/j.scitotenv.2016.02.003

2-s2.0-84958554961

26897610

31.

Ezzatahmadi

Ayoko

G. A.

Millar

G. J.

Speight

Yan

Zhu

Clay-supported nanoscale zero-valent iron composite materials for the remediation of contaminated aqueous solutions: a review

Chemical Engineering Journal 2017 312

9340362

336 350

10.1016/j.cej.2016.11.154

2-s2.0-85027952653

32.

J. L.

Y. L.

Jing

Zhang

Ning

Removal of uranium from aqueous solution using montmorillonite-supported nanoscale zero-valent iron

J. Radioanalytical and Nuclear Chemistry 2014 299

9340362

1 329 336

10.1007/s10967-013-2779-1

2-s2.0-84892803534

33.

B. W.

Ren

X. M.

Zhao

Sheng

Wang

Huang

X-ray absorption fine structure study of enhanced sequestration of U(VI) and Se(IV) by montmorillonite decorated with zero-valent iron nanoparticles

Environmental Science: Nano 2016 3

9340362

6 1460 1472

10.1039/c6en00421k

2-s2.0-85000843946

34.

Wang

Liu

G. J.

T. F.

Zhou

Physicochemical studies toward the removal of Zn(II) and Pb(II) ions through adsorption on montmorillonite-supported zero-valent iron nanoparticles

RSC Advances 2015 5

9340362

38 29859 29871

10.1039/C5RA02108A

2-s2.0-84928911543

35.

Z. F.

Dong

H. P.

Zhang

Y. L.

Enhanced removal of Ni(II) by nanoscale zero valent iron supported on Na- saturated bentonite

Journal of Colloid and Interface Science 2017 497

9340362

43 49

10.1016/j.jcis.2017.02.058

2-s2.0-85014415514

28260674

36.

Y. M.

J. F.

Zhang

Y. L.

Mechanism insights into enhanced Cr(VI) removal using nanoscale zerovalent iron supported on the pillared bentonite by macroscopic and spectroscopic studies

Journal of Hazardous Materials 2012 227-228

9340362

211 218

10.1016/j.jhazmat.2012.05.034

2-s2.0-84862664829

22633883

37.

Kang

Zhou

W. Z.

Gao

Fan

Shen

Adsorption of anionic dyes on poly(epicholorohydrin dimethylamine) modified bentonite in single and mixed dye solutions

Applied Clay Science 2009 45

9340362

4 280 287

10.1016/j.clay.2009.06.010

2-s2.0-67650568966

38.

Tian

S. L.

Zhu

L. Z.

Shi

Characterization of sorption mechanisms of VOCs with organobentonites using a LSER approach

Environmental Science & Technology 2004 38

9340362

2 489 495

10.1021/es034541a

2-s2.0-0347634509

14750724

39.

Liu

Ruan

Zhao

D. Y.

Fan

Feng

Enhanced adsorption of 2,4-dichlorophenol by nanoscale zero-valent iron loaded on bentonite and modified with a cationic surfactant

Industrial & Engineering Chemistry Research 2017 56

9340362

1 191 197

10.1021/acs.iecr.6b03864

2-s2.0-85017528251

40.

Y. M.

Zhang

J. F.

Zheng

Enhanced removal of pentachlorophenol by a novel composite: nanoscale zero valent iron immobilized on organobentonite

Environmental Pollution 2011 159

9340362

12 3744 3749

10.1016/j.envpol.2011.07.016

2-s2.0-80053654159

21906860

41.

Ren

C. X.

Y. M.

J. F.

Sheng

Zheng

Immobilization of nanoscale zero valent iron on organobentonite for accelerated reduction of nitrobenzene

Journal of Chemical Technology & Biotechnology 2014 89

9340362

12 1961 1966

10.1002/jctb.4283

2-s2.0-84911404479

42.

Boyd

S. A.

Liu

Sun

Teppen

B. J.

Rapid and extensive debromination of decabromodiphenyl ether by smectite clay-templated subnanoscale zero-valent iron

Environmental Science & Technology 2012 46

9340362

16 8969 8975

10.1021/es300516e

2-s2.0-84865471422

22846063

43.

P. X.

S. Z.

L. T.

Zhu

Dang

Mechanism of the reduction of hexavalent chromium by organo-montmorillonite supported iron nanoparticles

Journal of Hazardous Materials 2012 219-220

9340362

283 288

10.1016/j.jhazmat.2012.04.008

2-s2.0-84860735597

22521796

44.

J. X.

Wang

Blaney

Peng

Chen

Cui

Deng

Wang

Huang

Degradation of sulfamethazine by persulfate activated with organo- montmorillonite supported nano-zero valent iron

Chemical Engineering Journal 2019 361

9340362

99 108

10.1016/j.cej.2018.12.024

2-s2.0-85058406173

45.

Wang

C. B.

Zhang

W. X.

Synthesizing nanoscale iron particles for rapid and complete dechlorination of TCE and PCBs

Environmental Science & Technology 1997 31

9340362

7 2154 2156

10.1021/es970039c

2-s2.0-0031193606

46.

Zhou

Y. Z.

Wang

Zhi

Guo

Zhou

Nie

Huang

Yang

Huang

Luo

Applications of nanoscale zero-valent iron and its composites to the removal of antibiotics: a review

Journal of Materials Science 2019 54

9340362

19 12171 12188

10.1007/s10853-019-03606-5

2-s2.0-85064568415

47.

Zhao

Liu

Cai

Z. Q.

Han

Qian

Zhao

An overview of preparation and applications of stabilized zero-valent iron nanoparticles for soil and groundwater remediation

Water Research 2016 100

9340362

245 266

10.1016/j.watres.2016.05.019

2-s2.0-84968719121

27206054

48.

Zhu

R. L.

Chen

Q. Z.

Zhou

Zhu

Adsorbents based on montmorillonite for contaminant removal from water: a review

Applied Clay Science 2016 123

9340362

239 258

10.1016/j.clay.2015.12.024

2-s2.0-84961285540

49.

Shahwan

Üzüm

Ç.

Eroğlu

A. E.

Lieberwirth

Synthesis and characterization of bentonite/iron nanoparticles and their application as adsorbent of cobalt ions

Applied Clay Science 2010 47

9340362

3-4 257 262

10.1016/j.clay.2009.10.019

2-s2.0-75349086481

50.

Shao

J. C.

Cai

X. Q.

X. N.

Research on preparation of nanoscale iron supported by bentonite and its remediation of lead ions

Digest Journal of Nanomaterials and Biostructures 2018 13

9340362

1 31 38

51.

Shi

L. N.

Zhang

Chen

Z. L.

Removal of chromium (VI) from wastewater using bentonite-supported nanoscale zero-valent iron

Water Research 2011 45

9340362

2 886 892

10.1016/j.watres.2010.09.025

2-s2.0-78650414868

20950833

52.

Yan

W. L.

Lien

H. L.

Koel

B. E.

Zhang

W. X.

Iron nanoparticles for environmental clean-up: recent developments and future outlook

Environmental Science-Processes & Impacts 2013 15

9340362

1 63 77

10.1039/C2EM30691C

2-s2.0-84874506541

53.

Wang

Liu

G. J.

C. C.

Zhou

Synthesis and characterization of montmorillonite-supported zero-valent iron nanoparticles with application for preconcentration of zinc

Analytical Letters 2016 49

9340362

17 2766 2782

10.1080/00032719.2016.1159219

2-s2.0-85002551663

54.

Fang

Z. Q.

Qiu

X. H.

Chen

J. H.

Qiu

Degradation of metronidazole by nanoscale zero-valent metal prepared from steel pickling waste liquor

Applied Catalysis B: Environmental 2010 100

9340362

1-2 221 228

10.1016/j.apcatb.2010.07.035

2-s2.0-77957236068

55.

Xiong

Soil colloid (volume II): soil colloid research method 1984

Science press

56.

Shen

Zhang

S. W.

Huang

Heteroaggregation of microparticles with nanoparticles changes the chemical reversibility of the microparticles' attachment to planar surfaces

Journal of Colloid and Interface Science 2014 421

9340362

103 113

10.1016/j.jcis.2014.01.033

2-s2.0-84894030072

24594038

57.

Shen

Jin

Zhuang

Xing

Role and importance of surface heterogeneities in transport of particles in saturated porous media

Critical Reviews in Environmental Science and Technology 2020 50

9340362

3 244 329

10.1080/10643389.2019.1629800

2-s2.0-85067853644

58.

Singh

Jain

Upadhyay

M. K.

Khandelwal

Verma

H. N.

Green synthesis of silver nanoparticles using Argemone mexicana leafextract and evaluation of their antimicrobial activities

Digest Journal of Nanomaterials and Biostructures 2010 5

9340362

483 489

59.

Chrysochoou

Johnston

C. P.

Dahal

G. A.

Comparative evaluation of hexavalent chromium treatment in contaminated soil by calcium polysulfide and green-tea nanoscale zero-valent iron

Journal of Hazardous Materials 2012 201

9340362

33 42

60.

Soliemanzadeh

Fekri

The application of green tea extract to prepare bentonite-supported nanoscale zero-valent iron and its performance on removal of Cr(VI): effect of relative parameters and soil experiments

Microporous and Mesoporous Materials 2017 239

9340362

60 69

10.1016/j.micromeso.2016.09.050

2-s2.0-84989944043

61.

Senapati

Ahmad

Khan

M. I.

Sastry

Kumar

Extracellular biosynthesis of bimetallic Au–Ag alloy nanoparticles

Small 2005 1

9340362

5 517 520

10.1002/smll.200400053

2-s2.0-29244454809

17193479

62.

S. H.

Zhua

S. H.

Chang

J. S.

Recent advances in nanoscale-metal assisted biochar derived from waste biomass used for heavy metals removal

Bio/Technology 2017 246

9340362

123 134

63.

Hoch

L. B.

Mack

E. J. B. W.

Hydutsky

B. W.

Hershman

J. M.

Skluzacek

J. M.

Mallouk

T. E.

Carbothermal synthesis of carbon-supported nanoscale zero-valent iron particles for the remediation of hexavalent chromium

Environmental Science & Technology 2008 42

9340362

7 2600 2605

10.1021/es702589u

2-s2.0-41649088061

18505003

64.

Yang

S. H.

P. X.

Liu

J. Q.

Chen

Ahmed

Zhu

Efficient removal of bisphenol A by superoxide radical and singlet oxygen generated from peroxymonosulfate activated with Fe⁰-montmorillonite

Chemical Engineering Journal 2018 350

9340362

484 495

10.1016/j.cej.2018.04.175

2-s2.0-85048176628

65.

Chen

Q. Q.

Y. Y.

Zhu

Dang

Heterogeneous photo-Fenton photodegradation of reactive brilliant orange X-GN over iron-pillared montmorillonite under visible irradiation

Journal of Hazardous Materials 2009 168

9340362

2-3 901 908

10.1016/j.jhazmat.2009.02.107

2-s2.0-67649817119

19324495

66.

Y. M.

Zhang

J. F.

Sheng

Zheng

Enhanced reduction of chlorophenols by nanoscale zerovalent iron supported on organobentonite

Chemosphere 2013 92

9340362

4 368 374

10.1016/j.chemosphere.2013.01.030

2-s2.0-84878115418

23399303

67.

Tomašević

D. D.

Kozma

Kerkez

D. V.

Dalmacija

B. D.

Dalmacija

M. B.

Bečelić-Tomin

M. R.

Kukovecz

Á.

Kónya

Rončević

Toxic metal immobilization in contaminated sediment using bentonite- and kaolinite-supported nano zero-valent iron

Journal of Nanoparticle Research 2014 16

9340362

8 2548

10.1007/s11051-014-2548-2

2-s2.0-84904526508

68.

Shi

L. N.

Zhou

Chen

Z. L.

Megharaj

Naidu

Simultaneous adsorption and degradation of Zn²⁺ and Cu²⁺ from wastewaters using nanoscale zero-valent iron impregnated with clays

Environmental Science and Pollution Rresearch 2013 20

9340362

6 3639 3648

10.1007/s11356-012-1272-7

2-s2.0-84878111484

23114838

69.

Kerkez

D. V.

Tomašević

D. D.

Kozma

Bečelić-Tomin

M. R.

Prica

M. D.

Rončević

S. D.

Kukovecz

Á.

Dalmacija

B. D.

Kónya

Three different clay-supported nanoscale zero-valent iron materials for industrial azo dye degradation: a comparative study

Journal of the Taiwan Institute of Chemical Engineers 2014 45

9340362

5 2451 2461

10.1016/j.jtice.2014.04.019

2-s2.0-84905902764

70.

X. G.

Zhao

Mao

Gong

Peng

Liu

Removal of nitrobenzene by immobilized nanoscale zero-valent iron: effect of clay support and efficiency optimization

Applied Surface Science 2016 370

9340362

260 269

10.1016/j.apsusc.2016.01.141

2-s2.0-84959324908

71.

Kornilovych

Kovalchuk

Tobilko

Ubaldini

Uranium removal from groundwater and wastewater using clay-supported nanoscale zero-valent iron

Metals 2020 10

9340362

11 1421

10.3390/met10111421

72.

Fan

M. D.

Yuan

Chen

T. H.

H. P.

Yuan

A. H.

Chen

K. M.

Zhu

J. X.

Liu

Synthesis, characterization and size control of zerovalent iron nanoparticles anchored on montmorillonite

Chinese Science Bulletin 2010 55

9340362

11 1092 1099

10.1007/s11434-010-0062-1

2-s2.0-77952258981

73.

Pang

Z. H.

Yan

M. Y.

Jia

X. S.

Wang

Chen

Debromination of decabromodiphenyl ether by organo-montmorillonite-supported nanoscale zero-valent iron: preparation, characterization and influence factors

Journal of Environmental Sciences 2014 26

9340362

2 483 491

10.1016/S1001-0742(13)60419-2

2-s2.0-84893400493

74.

Lin

Y. M.

Chen

Z. X.

Chen

Z. L.

Megharaj

Naidu

Decoloration of acid violet red B by bentonite-supported nanoscale zero-valent iron: reactivity, characterization, kinetics and reaction pathway

Applied Clay Science 2014 93-94

9340362

56 61

10.1016/j.clay.2014.02.020

2-s2.0-84898448826

75.

Tran

M. L.

Deng

S. W.

C. C.

Juang

R. S.

Efficient removal of antibiotic oxytetracycline from water using optimized montmorillonite-supported zero-valent iron nanocomposites

Environmental Science and Pollution Research 2020 27

9340362

24 30853 30867

10.1007/s11356-020-09356-1

76.

Suazo-Hernández

Manquián-Cerda

de la Luz Mora

Molina-Roco

Angélica Rubio

Sarkar

Bolan

Arancibia-Miranda

Efficient and selective removal of Se^VI and As^V mixed contaminants from aqueous media by montmorillonite-nanoscale zero valent iron nanocomposite

Journal of Hazardous Materials 2021 403

9340362

123639

10.1016/j.jhazmat.2020.123639

77.

Arancibia-Miranda

Baltazar

S. E.

García

Muñoz-Lira

Sepúlveda

Rubio

M. A.

Altbir

Nanoscale zero valent supported by zeolite and montmorillonite: template effect of the removal of lead ion from an aqueous solution

Journal of Hazardous Materials 2016 301

9340362

371 380

10.1016/j.jhazmat.2015.09.007

2-s2.0-84942134664

26384998

78.

Rao

W. X.

Liu

G. H.

Wang

Liao

Effective degradation of Rh 6G using montmorillonite-supported nano zero-valent iron under microwave treatment

Materials 2018 11

9340362

11 2212

10.3390/ma11112212

2-s2.0-85056143661

30405090

79.

Y. M.

Cheng

Sheng

G. D.

Dong

Chen

Zhu

Synergetic effect of a pillared bentonite support on Se(VI) removal by nanoscale zero valent iron

Applied Catalysis B: Environmental 2015 174-175

9340362

329 335

10.1016/j.apcatb.2015.03.025

2-s2.0-84924974928

80.

Zhang

M. Y.

K. X.

Zhang

X. W.

Han

Liu

Tong

Modification of zero valent iron nanoparticles by sodium alginate and bentonite: enhanced transport, effective hexavalent chromium removal and reduced bacterial toxicity

Journal of Hazardous Materials 2020 388

9340362

121822

10.1016/j.jhazmat.2019.121822

81.

Shi

L. N.

Lin

Y. M.

Zhang

Chen

Z. L.

Synthesis, characterization and kinetics of bentonite supported nZVI for the removal of Cr(VI) from aqueous solution

Chemical Engineering Journal 2011 171

9340362

2 612 617

10.1016/j.cej.2011.04.038

2-s2.0-79959298161

82.

Bhowmick

Chakraborty

Mondal

van Renterghem

van den Berghe

Roman-Ross

Chatterjee

Iglesias

Montmorillonite-supported nanoscale zero-valent iron for removal of arsenic from aqueous solution: kinetics and mechanism

Chemical Engineering Journal 2014 243

9340362

14 23

10.1016/j.cej.2013.12.049

2-s2.0-84892847758

83.

Yuan

Fan

M. D.

Yang

Liu

Yuan

Zhu

J. X.

Chen

T. H.

Montmorillonite-supported magnetite nanoparticles for the removal of hexavalent chromium [Cr(VI)] from aqueous solutions

Journal of Hazardous Materials 2009 166

9340362

2-3 821 829

10.1016/j.jhazmat.2008.11.083

2-s2.0-67349241976

19135796

84.

Liu

Cao

Yuan

Zhang

Guo

Yang

Zhao

Insight into the kinetics and mechanism of removal of aqueous chlorinated nitroaromatic antibiotic chloramphenicol by nanoscale zero-valent iron

Chemical Engineering Journal 2018 334

9340362

508 518

10.1016/j.cej.2017.10.060

2-s2.0-85033463924

85.

Zarime

N. A.

Yaacob

W. Z. W.

Jamil

Removal of heavy metals using bentonite supported nano-zero valent iron particles 2018

AIP Conference Proceedings

10.1063/1.5027944

2-s2.0-85045660537

86.

Zhang

Y. M.

J. F.

Zheng

Enhanced removal of nitrate by a novel composite: nanoscale zero valent iron supported on pillared clay

Chemical Engineering Journal 2011 171

9340362

2 526 531

10.1016/j.cej.2011.04.022

2-s2.0-79959297944

87.

Dong

Deng

Xie

Zhang

Jiang

Cheng

Hou

Zeng

Stabilization of nanoscale zero-valent iron (nZVI) with modified biochar for Cr(VI) removal from aqueous solution

Journal of Hazardous Materials 2017 332

9340362

79 86

10.1016/j.jhazmat.2017.03.002

2-s2.0-85014827949

28285109

88.

Shao

J. C.

X. N.

Zhou

Cai

Nanoscale zero-valent iron decorated on bentonite/graphene oxide for removal of copper ions from aqueous solution

Materials 2018 11

9340362

6 945

10.3390/ma11060945

2-s2.0-85048119861

29867035

89.

Bao

Damtie

M. M.

Hosseinzadeh

Wei

Jin

Phong Vo

H. N.

J. S.

Liu

Wang

X. F.

Z. M.

Chen

Z. J.

Frost

R. L.

B. J.

Bentonite-supported nano zero-valent iron composite as a green catalyst for bisphenol A degradation: preparation, performance, and mechanism of action

Journal of Environmental Management 2020 260

9340362

110105

10.1016/j.jenvman.2020.110105

90.

Zou

Y. D.

Wang

X. X.

Khan

Wang

Liu

Alsaedi

Hayat

Wang

Environmental remediation and application of nanoscale zero-valent iron and its composites for the removal of heavy metal ions: a review

Environmental Science & Technology 2016 50

9340362

14 7290 7304

10.1021/acs.est.6b01897

2-s2.0-84978890742

27331413

91.

Weng

X. L.

Cai

W. L.

Lin

Chen

Degradation mechanism of amoxicillin using clay supported nanoscale zero- valent iron

Applied Clay Science 2017 147

9340362

137 142

10.1016/j.clay.2017.07.023

2-s2.0-85026608648

92.

Wang

Adsorption of aqueous neodymium, europium, gadolinium, terbium, and yttrium ions onto nZVI-montmorillonite: kinetics, thermodynamic mechanism, and the influence of coexisting ions

Environmental Science and Pollution Research 2018 25

9340362

33 33521 33537

10.1007/s11356-018-3296-0

2-s2.0-85054323518

30267348

93.

Chen

L. L.

Feng

S. J.

Zhao

D. L.

Chen

Efficient sorption and reduction of U(VI) on zero-valent iron-polyaniline- graphene aerogel ternary composite

Journal of Colloid and Interface Science 2017 490

9340362

197 206

10.1016/j.jcis.2016.11.050

2-s2.0-85000608381

27912118

94.

Liu

S. C.

Gao

H. J.

Cheng

Wang

Peng

Xie

Study on influencing factors and mechanism of removal of Cr(VI) from soil suspended liquid by bentonite-supported nanoscale zero-valent iron

Scientific Reports 2020 10

9340362

1 8831

10.1038/s41598-020-65814-3

32483261

95.

Wang

Chen

Wang

X. R.

Liu

Yang

Removal of hexavalent chromium by bentonite supported organosolv lignin- stabilized zero-valent iron nanoparticles from wastewater

Journal Cleaner Production 2020 267

9340362

122009

10.1016/j.jclepro.2020.122009

96.

Chi

Z. X.

Wang

Chu

H. Q.

Bin

Lucian

Bentonite-supported nanoscale zero-valent iron granulated electrodes for industrial wastewater remediation

RSC Advances 2017 7

9340362

70 44605 44613

10.1039/C7RA07584G

2-s2.0-85029679074

97.

Wang

F. Y.

Yang

W. W.

Zheng

F. Y.

Sun

Removal of Cr (VI) from simulated and leachate wastewaters by bentonite-supported zero-valent iron nanoparticles

International Journal of Environmental Research and Public Health 2018 15

9340362

10 2162

10.3390/ijerph15102162

2-s2.0-85054097411

30275389

98.

Milmile

S. N.

Pande

J. V.

Karmakar

Bansiwal

Chakrabarti

Biniwale

R. B.

Equilibrium isotherm and kinetic modeling of the adsorption of nitrates by anion exchange Indion NSSR resin

Desalination 2011 276

9340362

1-3 38 44

10.1016/j.desal.2011.03.015

2-s2.0-79959494635

99.

Zhao

Y. F.

Cao

Song

X. S.

Zhao

Wang

Lin

Chen

Zhang

Montmorillonite supported nanoscale zero-valent iron immobilized in sodium alginate (SA/Mt-NZVI) enhanced the nitrogen removal in vertical flow constructed wetlands (VFCWs)

Bio/Technology 2018 267

9340362

608 617

10.1016/j.biortech.2018.07.072

2-s2.0-85050406686

30056371

100.

Ahmed

M. J.

Theydan

S. K.

Adsorption of _p_ -chlorophenol onto microporous activated carbon from _Albizia lebbeck_ seed pods by one-step microwave assisted activation

Journal of Analytical and Applied Pyrolysis 2013 100

9340362

253 260

10.1016/j.jaap.2013.01.008

2-s2.0-84874105286

101.

Tobajas

Monsalvo

V. M.

Mohedano

A. F.

Rodriguez

J. J.

Enhancement of cometabolic biodegradation of 4-chlorophenol induced with phenol and glucose as carbon sources by _Comamonas testosteroni_

Journal of Environmental Management 2012 95

9340362

S116 S121

10.1016/j.jenvman.2010.09.030

2-s2.0-84856229693

20970917

102.

B. D.

D. C.

Qian

T. T.

Jiang

Boosting the activity and environmental stability of nanoscale zero-valent iron by montmorillonite supporting and sulfidation treatment

Chemical Engineering Journal 2020 387

9340362

124063

10.1016/j.cej.2020.124063

103.

Olmedo

Hourquebie

Jousse

Microwave absorbing materials based on conducting polymers

Advanced Materials 1993 5

9340362

5 373 377

10.1002/adma.19930050509

2-s2.0-0000496314

104.

Park

Ayoko

Horváth

Kurdi

Kristof

Frost

R. L.

Structural characterisation and environmental application of organoclays for the removal of phenolic compounds

Journal of Colloid and Interface Science 2013 393

9340362

319 334

10.1016/j.jcis.2012.10.067

2-s2.0-84873056633

23207051

105.

Olejniczak

Staniewski

Szymanowski

Extraction of phenols and phenyl acetates with diethyl carbonate

Analytica Chimica Acta 2005 535

9340362

1-2 251 257

10.1016/j.aca.2004.11.080

2-s2.0-15744404709

106.

Zhang

Y. M.

Zheng

X. M.

Removal of atrazine by nanoscale zero valent iron supported on organobentonite

Science of the Total Environment 2011 409

9340362

3 625 630

10.1016/j.scitotenv.2010.10.015

2-s2.0-78649842409

107.

Sun

Osseo-Asare

K. A.

Chen

Dempsey

B. A.

Reduction of As(V) to As(III) by commercial ZVI or As(0) with acid-treated ZVI

Journal of Hazardous Materials 2011 196

9340362

311 317

10.1016/j.jhazmat.2011.09.029

2-s2.0-80455176992

21978585

108.

Ponder

S. M.

Darab

J. G.

Mallouk

T. E.

Remediation of Cr(VI) and Pb(II) aqueous solutions using supported, nanoscale zero-valent iron

Environmental Science & Technology 2000 34

9340362

12 2564 2569

10.1021/es9911420

2-s2.0-0034659922

109.

Sheng

G. D.

McCall

Cosolvent effects on dechlorination of soil-sorbed polychlorinated biphenyls using bentonite clay-templated nanoscale zero valent iron

Environmental Science & Technology 2016 50

9340362

23 12949 12956

10.1021/acs.est.6b02933

2-s2.0-85021858095

27934265

110.

Reinholdt

Miehé-Brendlé

Delmotte

Tuilier

M. H.

le Dred

Cortès

Flank

A. M.

Fluorine route synthesis of montmorillonites containing Mg or Zn and characterization by XRD, thermal analysis, MAS NMR, and EXAFS spectroscopy

European Journal of Inorganic Chemistry 2001 2001

9340362

11 2831 2841

10.1002/1099-0682(200111)2001:11<2831::AID-EJIC2831>3.0.CO;2-6

A Review on Montmorillonite-Supported Nanoscale Zerovalent Iron for Contaminant Removal from Water and Soil

Abstract

1. Introduction

2. Fabrication Methods of Mt-nZVI

2.1. Methods of Synthesizing Modified Mt

2.1.1. Inorganic Modified Mt

2.1.2. Organic Modified Mt

2.2. Methods of Synthesizing Mt-nZVI

2.2.1. Liquid-Phase Reduction

2.2.2. Heteroaggregates of Mt with nZVIs

2.2.3. Green Synthesis

2.2.4. Thermal Reduction Method

2.3. Advantages of Using Mt to Support nZVI

2.3.1. Increased Dispersion

2.3.2. Small nZVI Size

2.3.3. Improved nZVI’s Stability against Oxidization

2.3.4. Other Advantages

3. The Reaction Mechanisms of Mt-nZVI

4. Factors Affecting Mt-nZVI Reactivity

4.1. pH

4.2. Temperature

4.3. Dosage of the Adsorbent

4.4. Other Factors

5. Remediation of Contaminated Water and Soil

5.1. Remediation of Contaminated Water

5.1.1. Heavy Metals

5.1.2. Uranium

5.1.3. Nitrate

5.1.4. Halogenated Organic Compounds

5.1.5. Dyes

5.1.6. Phenolic Compounds

5.1.7. Other Contaminants

5.2. Remediation of Contaminated Soil

6. Conclusions and Future Challenges

Footnotes

Data Availability

Conflicts of Interest

Acknowledgments

References