Coordination polymers of [2,2'-(ethandiylidenedinitrilo) diphenol) have been prepared with the metal ions Cu(II), Ni(1I) and Cr(III). They were characterized by elemental analysis, IR and electronic spectra. The metal content in all polymers was found to be consistent with a 1:1 (metal:ligand) stoichiometry. The thermal behaviour of these coordination polymers has been studied by thermogravimetric and DSC analyses in air up to 500 C. The crystallinity of the formed polymers was determined by x-ray analysis. The morphological structures of these polymers were determined by scanning electron microscopy.
Get full access to this article
View all access options for this article.
References
1.
[1] Burke P J and McMillin D R1980J. Chem. Soc., Dalton Trans.91794-1794
2.
[2] Deshpand U G and Shah J R1983Angew. Makromol. Chem.17751-51
3.
[3] Paliwal L J and Kharat R B1989J. Macromol. Sci. Chem.A 26843-843
4.
[4] Ran R and Fu D1990J. Macromol. Sci. Chem.A 27625-625
5.
[5] Patel M N and Jani B M1985J. Macromol. Sci. Chem.A 221517-1517
6.
[6] Deshpande U G and Shah J R1986J. Macromol. Sci. Chem.A 2397-97
7.
[7] Ebraheen K A, Al-Duhan J A and Hamdi S T1985Eur. Polym. J.2197-97
8.
[8] Bailar J C Jr1978Organometallic Polymers ed C E Carraher Jr et al (New York: Academic)
9.
[9] Hassan M K, Abd-Alla M A and Hassan R M1990J. Macromol. Sci. Chem.A 271501-1501
10.
[10] Silverstein R M and Basler G C1967Spectroscopic Identification of Organic Compounds2nd edn (New York: Wiley)
11.
[11] Nakamoto K and McCarthy P J1968Spectroscopy and Structure of Metal Chelate Compounds (New York: Wiley)
12.
[12] Natarajanand and Palaniandauar M1983J. Indian Chem. Soc.601-1
13.
[13] Nikolaev A V, Logvineko V A and Myachina L I1969Thermal Analysis vol 2 (New York: Academic)
