Abstract
LARC™ MPEI-1 (Langley Research Center™ modified phenylethynyl imide-1) phenylethynyl containing aromatic polyimide, is based on the reaction of biphenyl dianhydride (BPDA), 3,4′-oxydianiline (3,4′-ODA), 1,3-bis(3-aminophenoxy)benzene (APB), 2,4,6-triaminopyrimidine (TAP) and 4-phenylethynyl phthalic anhydride (PEPA), presumably resulting in a mixture of linear, branched and star shaped phenylethynyl containing imides which was evaluated as a matrix for high-performance composites. The poly(amid acid) solution of MPEI-1 in N-methypyrrolidinone was synthesized at 35% and 42% solids. Unidirectional prepreg was fabricated from these solutions and Hercules IM7 carbon fibre utilizing NASA-Langley’s multipurpose prepreg machine. The temperature-dependent volatile depletion rates, thermal crystallization behaviour and resin rheology were characterized. Based on this information, a composite moulding cycle was developed which yielded well consolidated, voidfree laminates. Composite mechanical properties such as short beam shear strength, longitudinal and transverse flexural strength and flexural modulus, longitudinal tensile strength and notched and unnotched compression strengths were measured at room temperature (RT) and elevated temperatures. These mechanical properties are compared with those of IM7/LARC™ PETI-5 composites.
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