The influence of functionalised multi-layer graphene (FMLG) on anti-corrosion behaviour of zinc-rich primer (ZRP) was investigated. Electrochemical impedance spectroscopy, salt spray, cathodic delamination, pull-off adhesion tests and scanning electron microscopy analysis were evaluated. Samples were prepared using 0.25, 0.5, 0.75 and 1 wt-% of FMLG substituted by the same amount of zinc particles in epoxy containing 75 wt-% of zinc dust. Results revealed that sacrificial and barrier performances of ZRP were improved in the presence of FMLG. In addition, the adhesion and cathodic disbondment resistance showed significant improvement. The best results were obtained for ZRP containing 0.75 wt-% of FMLG.
MeroufelATouzainS.EIS characterization of new zinc rich powder coatings. Prog Org Caot. 2007; 59 (3): 197–205. doi: 10.1016/j.porgcoat.2006.09.005
2.
WicksZWJr.JonesFNPappasSPOrganic coatings: science and technology. 3rd ed. New York: Wiley; 1994.
3.
ParkSShonMY.Effects of multi-walled carbon nano tubes on corrosion protection of zinc rich epoxy resin coating. J Ind Eng Chem. 2015; 21 (3): 1258–1264. doi: 10.1016/j.jiec.2014.05.042
4.
SchaeferKMiszczykA.Improvement of electrochemical action of zinc-rich paints by addition of nanoparticulate zinc. Corros Sci. 2013; 66: 380–391. doi: 10.1016/j.corsci.2012.10.004
5.
ArianpouyaMNematollahiMArianpouyaNNovel properties of a conductive polymeric coating with an insulating nano additive. Prog Org Caot. 2016; 90: 369–379. doi: 10.1016/j.porgcoat.2015.07.018
6.
ShreepathiSBajajPMallikBP.Electrochemical impedance spectroscopy investigations of epoxy zinc rich coatings: role of Zn content on corrosion protection mechanism. Electrochim Acta. 2010; 55 (18): 5129–5134. doi: 10.1016/j.electacta.2010.04.018
7.
KalendovaA.Effects of particle sizes and shapes of zinc metal on the properties of anticorrosive coatings. Prog Org Coat. 2003; 46 (4): 324–332. doi: 10.1016/S0300-9440(03)00022-5
8.
MeroufelADeslouisCTouzainS.Electrochemical and anticorrosion performances of zinc-rich and polyaniline powder coatings. Electrochim Acta. 2008; 53 (5): 2331–2338. doi: 10.1016/j.electacta.2007.09.056
9.
BarrancoVFeliuSJRFeliuS.EIS study of the corrosion behavior of zinc based coatings on steel in quiescent 3% NaCl solution. Part 1: directly exposed coatings. Corros Sci. 2004; 46 (9): 2203–2220. doi: 10.1016/j.corsci.2003.09.032
10.
BerendsenAM.Ship painting: current practice and systems in Europe. Prot Coat Europe. 1998; 4: 24–33.
11.
WalknerSHasselAW.Combined chemical and EIS study of the reaction of zinc coatings under alkaline conditions. Electrochim Acta. 2014; 131: 130–136. doi: 10.1016/j.electacta.2013.12.177
12.
CubidesYCastanedaH.Corrosion protection mechanisms of carbon nanotube and zinc-rich epoxy primers on carbon steel in simulated concrete pore solutions in the presence of chloride ions. Corros Sci. 2016; 109: 145–161. doi: 10.1016/j.corsci.2016.03.023
13.
MarcheboisHSavallCBernardJElectrochemical behavior of zinc-rich powder coatings in artificial sea water. Electrochim Acta. 2004; 49 (17-18): 2945–2954. doi: 10.1016/j.electacta.2004.01.053
14.
JaliliMRostamiMRamezanzadehB.An investigation of the electrochemical action of the epoxy zinc-rich coatings containing surface modified aluminium nanoparticle. Appl Surf Sci. 2015; 328: 95–108. doi: 10.1016/j.apsusc.2014.12.034
15.
GergelyAPfeiferÉBertótiICorrosion protection of cold-rolled steel by zinc-rich epoxy paint coatings loaded with nano-size alumina supported polypyrrole. Corros Sci. 2011; 53 (11): 3486–3499. doi: 10.1016/j.corsci.2011.06.014
16.
CiudiceCBenitezJCLinaresMM.Zinc-rich epoxy primers based on lamellar zinc dust. Surf Coat Int. 1997; 80 (6): 279–284. doi: 10.1007/BF02692668
17.
JagtapRNNambiarRHassanSZPredictive power for life and residual life of the zinc rich primer coatings with electrical measurement. Prog Org Coat. 2007; 58 (4): 253–258. doi: 10.1016/j.porgcoat.2006.08.015
18.
ArianpouyaNShishesazMArianpouyaMEvaluation of synergistic effect of nanozinc/nanoclay additives on the corrosion performance of zinc-rich polyurethane nanocomposite coatings using electrochemical properties and salt spray testing. Surf Coat Tech. 2013; 216: 199–206. doi: 10.1016/j.surfcoat.2012.11.036
19.
ZhangLMaAJiangJAnti-corrosion performance of waterborne Zn rich coating with modified silicon-based vehicle and lamellar Zn (Al) pigments. Prog Natur Sci Mater Int. 2012; 22 (4): 326–333. doi: 10.1016/j.pnsc.2012.07.001
20.
KakaeiMNDanaeeIZaareiD.Investigation of corrosion protection afforded by inorganic anticorrosive coatings comprising micaceous iron oxide and zinc dust. Corros Eng Sci Technol. 2013; 48 (3): 194–198. doi: 10.1179/1743278212Y.0000000060
21.
ArmanSYRamezanzadehBFarghadaniSApplication of the electrochemical noise to investigate the corrosion resistance of an epoxy zinc-rich coating loaded with lamellar aluminum and micaceous iron oxide particles. Corros Sci. 2013; 77: 118–127. doi: 10.1016/j.corsci.2013.07.034
22.
HayatdavoudiHRahseparM.Smart inhibition action of layered double hydroxide nano containers in zinc-rich epoxy coating for active corrosion protection of carbon steel substrate. J Alloy Compd. 2017; 711: 560–567. doi: 10.1016/j.jallcom.2017.04.044
23.
JangBZZhamuA.Processing of nanographene platelets (NGPs) and NGP nanocomposites: a review. J Mater Sci. 2008; 43 (15): 5092–5101. doi: 10.1007/s10853-008-2755-2
24.
SenguptaRBhattacharyaMBandyopadhyaySA review on the mechanical and electrical properties of graphite and modified graphite reinforced polymer composites. Prog Polym Sci. 2011; 36 (5): 638–670. doi: 10.1016/j.progpolymsci.2010.11.003
MohammadiSAfshar TaromiFShariatpanahiHElectrochemical and anticorrosion behavior of functionalized graphite nanoplatelets epoxy coating. J Ind Eng Chem. 2014; 20 (6): 4124–4139. doi: 10.1016/j.jiec.2014.01.011
28.
AkbarinezhadE.Synthesis of conductive polyaniline-graphite nanocomposite in supercritical CO2 and its application in zinc-rich epoxy primer. J Supercrit Fluid. 2014; 94: 8–16. doi: 10.1016/j.supflu.2014.06.018
29.
RamezanzadehBMohamadzadeh MoghadamMHShohaniNEffects of highly crystalline and conductive polyaniline/graphene oxide composites on the corrosion protection performance of a zinc-rich epoxy coating. Chem Eng J. 2017; 320: 363–375. doi: 10.1016/j.cej.2017.03.061
30.
HayatdavoudiHRahseparM.A mechanistic study of the enhanced cathodic protection performance of graphenereinforced zinc rich nanocomposite coating for corrosion protection of carbon steel substrate. J Alloy Compd. 2017; 727: 1148–1156. doi: 10.1016/j.jallcom.2017.08.250
31.
DingRZhengYYuHStudy of water permeation dynamics and anti-corrosion mechanism of graphene/zinc coatings. J Alloy Compd. 2018; 748: 481–495. doi: 10.1016/j.jallcom.2018.03.160
32.
MargaritICPMattosOR.About coatings and cathodic protection: properties of the coatings influencing delamination and cathodic protection criteria. Electrochim Acta. 1998; 44: 363–371. doi: 10.1016/S0013-4686(97)10193-1
33.
FreguiaKRabaeyKYuanZNon-catalyzed cathodic oxygen reduction at graphite granules in microbial fuel cells. Electrochim Acta. 2007; 53 (2): 598–603. doi: 10.1016/j.electacta.2007.07.037
34.
WuYWangYZhangDStudies on the electrochemical reduction of oxygen catalyzed by reduced graphene sheets in neutral media. J Power Sources. 2011; 196 (3): 1141–1144. doi: 10.1016/j.jpowsour.2010.07.087
