Corrosion of metals is a long-standing problem in many engineering fields. Recently, microporous and nanoporous materials, MOFs (metal-organic frameworks), have attracted much attention in the field of inorganic and organic chemistry. However, there are few studies on MOFs as protective coatings. This paper reviews (i) the basic structure, synthesis methods and types of MOFs, (ii) their growth patterns, (iii) research progress and functional mechanisms of MOFs in different fields (such as corrosion resistance, antibacterial and flame retardant), (iv) computational chemistry in the research field of MOFs to provide theoretical basis for designing MOFs with the best performance, determining the best synthesis conditions and operating parameters and (v) the application prospect of MOFs in the field of corrosion, and attempts to spread the application of MOFs to other fields.
ChenZ, JiangD, RenL, Facile preparation of wear-resistant and anti-corrosion films on magnesium alloy. Surf Eng. 2022;38:22–29.
2.
AkramM, ArshadN, BraemA.Nanoparticle-modified coatings by electrophoretic deposition for corrosion protection of magnesium. Surf Eng. 2022;38:430–439.
3.
OlajireA.Recent advances on organic coating system technologies for corrosion protection of offshore metallic structures. J Mol Liq. 2018;269:572–606.
4.
HikkuGS, ArthiC, Jeen RobertRB, Calcium phosphate conversion technique: a versatile route to develop corrosion resistant hydroxyapatite coating over Mg/Mg alloys based implants. J Magnes Alloy. 2022;10:1821–1845.
5.
SongJ, CuiX, GuoJ, Self-healing conversion coating with gelatin-chitosan microcapsules containing inhibitor on AZ91D alloy. Surf Eng. 2018;34:79–84.
6.
HeY, WangZ, WangH, Metal-organic framework-derived nanomaterials in environment related fields: fundamentals, properties and applications. Coord Chem Rev. 2020;429:213618.
7.
YeganehM, AsadiN, OmidiM, An investigation on the corrosion behavior of the epoxy coating embedded with mesoporous silica nanocontainer loaded by sulfamethazine inhibitor. Prog Org Coat. 2018;128:75–81.
Rajabalizadeh DSZ, KhodayariA, SohrabnezhadbS.Corrosion protection and mechanical properties of the electroless Ni-P-MOF nanocomposite coating on AM60B magnesium alloy. J Magnes Alloy. 2021;10:2280–2295.
10.
MaadaniSHJ, SaebMR, RamezanzadehB, Puglia. studying the corrosion protection behavior of an epoxy composite coating reinforced with functionalized graphene oxide by second and fourth generations of poly(amidoamine) dendrimers (GO-PAMAM-2, 4). Prog Color, Colorants Coat. 2020;13:261–273.
11.
JiangS, LiW, LiuJ, Zno@ZIF-8 core-shell structure nanorods superhydrophobic coating on magnesium alloy with corrosion resistance and self-cleaning. J Magnes Alloy. 2022. doi:10.1016/j.jma.2022.01.014
12.
ReddyR, LinJ, ChenY, Progress of nanostructured metal oxides derived from metal–organic frameworks as anode materials for lithium–ion batteries. Coord Chem Rev. 2020;420:213434.
13.
Mohammad Ebrahim Haji NaghiT, MohammadR, BahramR.Highly-effective/durable method of mild-steel corrosion mitigation in the chloride-based solution via fabrication of hybrid metal-organic film (MOF) generated between the active Trachyspermum Ammi bio-molecules-divalent zinc cations. Corros Sci2021;184:109383.
14.
AndreaeMO, RosenfeldD.Aerosol cloud precipitation interactions. Part 1. The nature and sources of cloud-active aerosols. Earth Sci Rev2008;89:13–41.
15.
HaoL, ZhaoJ, ZhangY, Research progress in the preparation and application of photonic crystals based on metal-organic framework. Acta Materiae Compositae Sinica. 2021;38:3162–3170.
16.
Steffi GieseKS.Structural principles in seven-coordinate subgroup compounds: the complex anions MoF7-, WF7-, and ReOF6-. Angew Chem Int Ed1994;33:461–463.
17.
LeiG, ChidambaramA, FonquerniePG, A highly water-stable meta -carborane-based copper metal–organic framework for efficient high-temperature butanol separation. J Am Chem Soc. 2020;142:8299–8311.
GeX, QinW, ZhangH, A three-dimensional porous Co@C/carbon foam hybrid monolith for exceptional oil–water separation. Nanoscale. 2019;11:12161–12168.
20.
RaoKP, HiguchiM, SumidaK, Design of superhydrophobic porous coordination polymers through the introduction of external surface corrugation by the use of an aromatic hydrocarbon building unit. Angew Chem Int Ed. 2014;126:8364–8369.
21.
YangSJ, ChoiJY, ChaeHK, Preparation and enhanced hydrostability and hydrogen storage capacity of CNT@MOF-5 hybrid composite. Chem Mater. 2009;21:1893–1897.
22.
HausdorfS, BaitalowF, SeidelJ, Gaseous species as reaction tracers in the solvothermal synthesis of the zinc oxide terephthalate MOF-5. J Phys Chem A. 2007;111:4259–4266.
23.
LiangS, ZhuL, GaiG, Synthesis of morphology-controlled ZnO microstructures via a microwave-assisted hydrothermal method and their gas-sensing property. Ultrason Sonochem. 2014;21:1335–1342.
24.
NiZ, MaselRI.Rapid production of metal−organic frameworks via microwave-assisted solvothermal synthesis. J Am Chem Soc. 2006;128:12394–12395.
25.
SabouniR, KazemianH, RohaniS.Microwave synthesis of the CPM-5 metal organic framework. Chem Eng Technol. 2012;35:1085–1092.
JungDW, YangDA, KimJ, Facile synthesis of MOF-177 by a sonochemical method using 1-methyl-2-pyrrolidinone as a solvent. Dalton T. 2010;39:2883–2887.
28.
JinL, LiuQ, SunW.An introduction to synthesis and application of nanoscale metal–carboxylate coordination polymers. Crystengcomm. 2014;16:3816–3828.
29.
WeiY, HanS, WalkerDA, Nanoparticle core/shell architectures within MOF crystals synthesized by reaction diffusion. Angew Chem Int Ed2012;51:7435–7439.
30.
FarhadipourA, AlizadehMH, EshghiH, Synthesis and characterization of first 3-D inorganic-organic hybrids based on Keggin polyoxometalate and melamine with three layers solvent diffusion method. J. Clust. Sci. 2015;26:1619–1631.
31.
Platero-PratsAE, GomezAB, SamainL, The first one-pot synthesis of metal–organic frameworks functionalised with two transition-metal complexes. Chem. Eur. J. 2015;21:861–866.
32.
KaurG, SudD.A comprehensive review on synthetic approaches for metal-organic frameworks: from traditional solvothermal to greener protocols. Polyhedron. 2021;193:114897.
33.
SaeedT, NaeemA, DinIU, Structure, nomenclature and viable synthesis of micro/nanoscale metal organic frameworks and their remarkable applications in adsorption of organic pollutants. Microchem. J. 2020;159:105579.
34.
PichonA, JamesSL.An array-based study of reactivity under solvent-free mechanochemical conditions-insights and trends. Crystengcomm. 2008;10:1839–1847.
35.
LiH, EddaoudiM.Design and synthesis of an exceptionally stable and highly porous metal-organic framework. Nature. 1999;402:276–279.
36.
BanerjeeR, PhanA, WangB, High-throughput synthesis of zeolitic imidazolate frameworks and application to CO2 capture. Science. 2008;319:939–943.
37.
ParkKS, ZhengN, CtéAP, Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. P Natl Acad Sci. 2006;103:10186–10191.
38.
GérardF, SerreC, Mellot-DraznieksC, A hybrid solid with giant pores prepared by a combination of targeted chemistry, simulation, and powder diffraction. Angew Chem Int Ed. 2004;43:6296–6301.
YangL, LiuY, ChenL, Stable dual-emissive fluorescin@ UiO-67 metal-organic frameworks for visual and ratiometric sensing of Al3+and ascorbic acid. Spectrochim Acta A: Mol Biomol Spectrosc. 2021;261:120068.
41.
ZhangR, JiaoJ, YangW, Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction. J Mater Chem A. 2019;7:26371–26377.
42.
MaS, SunD, SimmonsJ, Metal-organic framework from an anthracene derivative containing nanoscopic cages exhibiting high methane uptake. J Am Chem Soc. 2008;130:1012–1016.
43.
FangQ, ZhuG, XueM, Structure, luminescence, and adsorption properties of two chiral microporous metal−organic frameworks. Inorg Chem. 2006;45:3582–3587.
44.
SanaeiZ, BahlakehG, RamezanzadehB.Active corrosion protection of mild steel by an epoxy ester coating reinforced with hybrid organic/inorganic green inhibitive pigment. J Alloys Compd. 2017;728:1289–1304.
45.
MahmoodiA, EbrahimiM, KhosraviA, A hybrid dye-clay nano-pigment: synthesis, characterization and application in organic coatings. Dyes Pigm. 2017;147:234–240.
46.
YangQ, XuQ, JiangHL.Metal–organic frameworks meet metal nanoparticles: synergistic effect for enhanced catalysis. Chem Soc Rev. 2017;46:4774–4808.
47.
FangY, YangZ, LiH, MIL-100(Fe) and its derivatives: from synthesis to application for wastewater decontamination. Environ Sci Pollut. R. 2020;27:4703–4724.
48.
SlaB, XwA, QiY, A facile approach to fabricating graphene/waterborne epoxy coatings with dual functionalities of barrier and corrosion inhibitor. J Mater Sci Technol. 2021;112:263–276.
ZhuB, OuR, LiuJ, Fabrication of superhydrophobic surfaces with hierarchical structure and their corrosion resistance and self-cleaning properties. Surf Interfaces. 2022;28:101608.
51.
JiangL, DongY, YuanY, Recent advances of metal–organic frameworks in corrosion protection: from synthesis to applications. Chem Eng J. 2021;430:132823.
52.
RamezanzadehM, RamezanzadehB.Thermomechanical and anticorrosion characteristics of metal-organic frameworks. In: KhanA, VerpoortF, AsiriAM, et al., editors. Metal-organic frameworks for chemical reactions. India: Elsevier; 2021. p. 295–330.
53.
RamezanzadehM, TatiA, BahlakehG, Construction of an epoxy composite coating with exceptional thermo-mechanical properties using Zr-based NH2-UiO-66 metal-organic framework (MOF): experimental and DFT-D theoretical explorations. Chem Eng J. 2021;408:127366.
54.
RamezanzadehM, RamezanzadehB, MahdavianM, Development of metal-organic framework (MOF) decorated graphene oxide nanoplatforms for anti-corrosion epoxy coatings. Carbon N Y. 2020;161:231–251.
55.
RamezanzadehM, RamezanzadehB, BahlakehG, Development of an active/barrier bi-functional anti-corrosion system based on the epoxy nanocomposite loaded with highly-coordinated functionalized zirconium-based nanoporous metal-organic framework (Zr-MOF). Chem Eng J. 2021;408:127361.
56.
AlipanahN, YariH, MahdavianM, MIL-88A (Fe) filler with duplicate corrosion inhibitive/barrier effect for epoxy coatings: electrochemical, molecular simulation, and cathodic delamination studies. J Ind Eng Chem. 2021;97:200–215.
57.
LashgariSM, YariH, MahdavianM, Synthesis of graphene oxide nanosheets decorated by nanoporous zeolite-imidazole (ZIF-67) based metal-organic framework with controlled-release corrosion inhibitor performance: experimental and detailed DFT-D theoretical explorations. J Hazard Mater. 2021;404:124068.
58.
MotamediM, RamezanzadehM, RamezanzadehB, One-pot synthesis and construction of a high performance metal-organic structured nano pigment based on nanoceria decorated cerium (III)-imidazole network (NC/CIN) for effective epoxy composite coating anti-corrosion and thermo-mechanical properties improvement. Chem Eng J. 2020;382:122820.
59.
QiuS, SuY, ZhaoH, Ultrathin metal-organic framework nanosheets prepared via surfactant-assisted method and exhibition of enhanced anticorrosion for composite coatings. Corros Sci. 2021;178:109090.
60.
HuhtamakiT, TianX, KorhonenJT, Surface-wetting characterization using contact-angle measurements. Nat Protoc2019;14:2259.
61.
ChenH, FanH, SuN, Highly hydrophobic polyaniline nanoparticles for anti-corrosion epoxy coatings. Chem Eng J. 2021;420:130540.
62.
WangX, RobustLZ.Hydrophobic anti-corrosion coating prepared by PDMS modified epoxy composite with graphite nanoplatelets/nano-silica hybrid nanofillers. Surf Coat Tech. 2021;421:1277440.
63.
KooshksaraMM, MohammadiS.Investigation of the in-situ solvothermal reduction of multi-layered graphene oxide in epoxy coating by acetonitrile on improving the hydrophobicity and corrosion resistance. Prog Org Coat. 2021;159:106432.
64.
ZhangX, ZhangY, WangY, Preparation and corrosion resistance of hydrophobic zeolitic imidazolate framework (ZIF-90) film @Zn-Al alloy in NaCl solution. Prog Org Coat. 2018;115:94–99.
65.
LiuJ, LiR, ZuX, Photocatalytic conversion of nitrogen to ammonia with water on triphase interfaces of hydrophilic-hydrophobic composite Bi4O5Br2/ZIF-8. Chem Eng J. 2019;371:796–803.
66.
LiY, LuoQ, WangX, High-hydrophobic ZIF-8@PLA composite aerogel and application for oil-water separation. Sep Purif Technol. 2021;270:118794.
67.
YangF, WuJ, ZhuX, Enhanced stability and hydrophobicity of LiX@ZIF-8 composite synthesized environmental friendly for CO2 capture in highly humid flue gas. Chem Eng J. 2021;410:128322.
68.
LoiseauT, SerreC, HuguenardC, A rationale for the large breathing of the porous aluminum terephthalate (MIL-53) upon hydration. Chem Eur J. 2004;10:1373–1382.
69.
AnjaliA, MeshramS.Synthesis of highly stable nanoscale MIL-53 MOF and its application for the treatment of complex mixed dye solutions and real-time dye industry effluent. Sep Purif Technol. 2021;274:119073.
70.
CavkaJH, JakobsenS, OlsbyeU, A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability. J Am Chem Soc. 2008;130:13850–13851.
71.
AhmadijokaniF, MohammadkhaniR, AhmadipouyaS, Superior chemical stability of UiO-66 metal-organic frameworks (MOFs) for selective dye adsorption. Chem Eng J. 2020;399:125346.
72.
LiuX, YueT, QiK, Probe into metal-organic framework membranes fabricated via versatile polydopamine-assisted approach onto metal surfaces as anticorrosion coatings – ScienceDirect. Corros Sci. 2020;177:108949.
73.
Shahini MH, Eivazmohammadloo H, Mohammad R. Recent innovations in synthesis/characterization of advanced nano-porous metal-organic frameworks (MOFs); current/future trends with a focus on the smart anti-corrosion features. Mater Chem Phys. 2022;276:125420.
74.
ShchukinaE, WangH, ShchukinDG, Nanocontainer-based self-healing coatings: current progress and future perspectives. Chem Commun. 2019;55:3859–3867.
75.
ShahiniMH, TaheriN, MohammadlooHE, A comprehensive overview of nano and micro carriers aiming at curtailing corrosion progression. J Taiwan Inst. Chem E. 2021;126:252–269.
76.
GodaES, Gab-AllahMA, SinguBS, Halloysite nanotubes based electrochemical sensors: a review. Microchem J. 2019;147:1083–1096.
77.
KhanA, HassaneinA, HabibS, Hybrid halloysite nanotubes as smart carriers for corrosion protection. ACS Appl Mater Inter. 2020;12:37571–37584.
78.
HabibS, ShakoorRA, KahramanR.A focused review on smart carriers tailored for corrosion protection: developments, applications, and challenges. Prog Org Coat. 2021;154:106218.
79.
GuoY, WangJ, ZhangD, pH-responsive self-healing anticorrosion coatings based on benzotriazole-containing zeolitic imidazole framework. Colloid Surf A. 2019;561:1–8.
80.
XiaoS, CaoX, DongZ, A pH-responsive cerium-imidazole decorated ZIF-8 to achieve self-healing barrier property for epoxy coating on Al alloy by controlled release. Prog Org Coat. 2022;163:106640.
81.
ZhangH, ZhaoM, YangY, Hydrolysis and condensation of ZIF-8 in water. Micropor Mesopor Mat. 2019;288:109568.
82.
ZhengH, ZhangY, LiuL, One-pot synthesis of metal-organic frameworks with encapsulated target molecules and their applications for controlled drug delivery. J Am Chem Soc. 2016;138:962–968.
83.
Mohamadian-KalhorS, EdjlaliL, BasharnavazH, Aluminum fumarate metal–organic framework: synthesis, characterization, and application as a novel inhibitor against corrosion of AM60B magnesium alloy in ethylene glycol solution. J Mater Eng Perform2021;30:720–726.
84.
RenB, ChenYC, LiY, Rational design of metallic anti-corrosion coatings based on zinc gluconate@ZIF-8. Chem Eng J. 2019;384:123389.
85.
HaddadiSA, RamazaniS, MahdavianM, Fabrication and characterization of graphene-based carbon hollow spheres for encapsulation of organic corrosion inhibitors. Chem Eng J. 2018;352:909–922.
86.
LiuY, XuJ, ZhangJ, Electrodeposited silica film interlayer for active corrosion protection. Corros Sci. 2017;120:61–74.
87.
SongG, AtrensA.Corrosion mechanisms of magnesium alloys. Adv Eng Mater. 1999;1:11–33.
88.
SongG, AtrensA.Understanding magnesium corrosion – a framework for improved alloy performance. Adv Eng Mater. 2003;5:837–858.
BrunettoPS, SlentersTV, FrommKM.In vitro biocompatibility of new silver(I) coordination compound coated-surfaces for dental implant applications. Materials. 2011;4:355–367.
96.
ZhangY, ShenX, MaP, Composite coatings of Mg-MOF74 and Sr-substituted hydroxyapatite on titanium substrates for local antibacterial, anti-osteosarcoma and pro-osteogenesis applications. Mater Lett. 2019;241:18–22.
97.
JingZ, ZhiL, LuZ, Bimetallic metal-organic frameworks and graphene oxide nano-hybrids for enhanced fire retardant epoxy composites: a novel carbonization mechanism. Carbon. 2019;153:407–416.
98.
PanapitiyaNP, WijenayakeSN, YuH, Stabilization of immiscible polymer blends using structure directing metal organic frameworks (MOFs). Polymer. 2014;55:2028–2034.
99.
LiX, YeJ, LinY, Facile synthesis and flame retardant performance of NaAl(OH)2CO3 whiskers. Powder Technol. 2011;206:358–361.
100.
KashiwagiT, FangmingDU, DouglasJF, Nanoparticle networks reduce the flammability of polymer nanocomposites. Nat Mater. 2005;4:928–933.
101.
XuW, WangX, WuY, Functionalized graphene with Co-ZIF adsorbed borate ions as an effective flame retardant and smoke suppression agent for epoxy resin. J Hazard Mater. 2019;363:138–151.
102.
HouY, HuW, GuiZ, A novel Co(Ⅱ)–based metal-organic framework with phosphorus-containing structure: build for enhancing fire safety of epoxy. Compos Sci Technol. 2017;152:231–242.
103.
HouY, LiuL, QiuS, DOPO-modified two-dimensional co-based metal-organic framework: preparation and application for enhancing fire safety of poly(lactic acid). ACS Appl Mater Inter. 2018;10:8274–8286.
104.
WuN, DingC, YangR.Effects of zinc and nickel salts in intumescent flame-retardant polypropylene. Polym Degrad Stabil. 2010;95:2589–2595.
105.
ZhangJ, LiZ, QiX, Size tailored bimetallic metal-organic framework (MOF) on graphene oxide with sandwich-like structure as functional nano-hybrids for improving fire safety of epoxy. Compos Part B: Eng. 2020;188:107881.
106.
MunueraC, ShekhahO, WangH, The controlled growth of oriented metal-organic frameworks on functionalized surfaces as followed by scanning force microscopy. Phys Chem Chem Phys. 2008;10:7257–7261.
CaoF, JuE, LiuC, Encapsulation of aggregated gold nanoclusters in a metal–organic framework for real-time monitoring of drug release. Nanoscale. 2017;9:4128–4134.
109.
ThompsonRW.Comments on the autocatalytic nucleation of (Na, TPA)-ZSM-5. Zeolites. 1992;12:837–840.
110.
LiuY, LiY, YangW.Fabrication of highly b-oriented MFI film with molecular sieving properties by controlled In-plane secondary growth. J Am Chem Soc. 2010;132:1768–1769.
ShearerGC, ChavanS, BordigaS, Defect engineering: tuning the porosity and composition of the metal–organic framework UiO-66 via modulated synthesis. Chem Mater. 2016;28:3749–3761.
113.
ZhuY, CistonJ, ZhengB, Unravelling surface and interfacial structures of a metal–organic framework by transmission electron microscopy. Nat Mater. 2017;16:532–536.
114.
CliffeMJ, WeiW, ZouX, Correlated defect nanoregions in a metal–organic framework. Nat Commun. 2014;5:1–8.
115.
GuZG, HeinkeL, WollC, Experimental and theoretical investigations of the electronic band structure of metal-organic frameworks of HKUST-1 type. Appl Phys Lett. 2015;107:183301.
116.
BennettTD, TodorovaTK, BaxterEF, Connecting defects and amorphization in UiO-66 and MIL-140 metal–organic frameworks: a combined experimental and computational study. Phys Chem Chem Phys. 2016;18:2192–2201.
117.
WangZ, WeidlerPG, AzucenaC, Negative, anisotropic thermal expansion in monolithic thin films of crystalline metal-organic frameworks. Micropor Mesopor Mat. 2016;222:241–246.
118.
RolandA, FischerCW.Layer-by-layer liquid-phase epitaxy of crystalline coordination polymers at surfaces. Angew Chem Int Ed2009;48:6205–6208.
119.
ShekhahO, WangH, ZacherD, Growth mechanism of metal–organic frameworks: insights into the nucleation by employing a step-by-step route. Angew Chem Int Ed2009;48:5038–5041.
120.
ChenY, YaoW, WuL, Effect of microstructure on layered double hydroxides film growth on Mg-2Zn-xMn alloy. Coatings. 2021;11:59.
121.
YaoW, ChenY, ChenY, Development of slippery liquid-infused porous surface on AZ31 Mg alloys for corrosion protection. Acta Metall. Sin.2022: 1–8.
122.
YaoW, ChenY, WuL, Preparation of slippery liquid-infused porous surface based on MgAlLa-layered double hydroxide for effective corrosion protection on AZ31 Mg alloy. J Taiwan Inst Chem. E. 2022;131:104176.
123.
YaoW, ChenY, WuL, Effective corrosion and wear protection of slippery liquid-infused porous surface on AZ31 Mg alloy. Surf Coat Tech. 2022;429:127953.
124.
ZhouC, PanM, LiS, Metal organic frameworks (MOFs) as multifunctional nanoplatform for anticorrosion surfaces and coatings. Adv Colloid Interface Sci. 2022;305:102707.
125.
ZhangX, LvY, TanS, Microstructure and corrosion behaviour of wire Arc additive manufactured AA2024 alloy thin wall structure. Corros Sci. 2021;186:109453.
126.
XiongL, YuM, LiY, Modified salicylaldehyde@ZIF-8/graphene oxide for enhancing epoxy coating corrosion protection property on AA2024-T3. Prog Org Coat. 2020;142:105562.
127.
CaiG, XiaoS, DengC, Ceo2 grafted carbon nanotube via polydopamine wrapping to enhance corrosion barrier of polyurethane coating. Corros Sci. 2021;178:109014.
128.
CaoK, YuZ, YinD, Fabrication of BTA-MOF-TEOS-GO nanocomposite to endow coating systems with active inhibition and durable anticorrosion performances. Prog Org Coat. 2020;143:105629.
129.
YanH, CaiM, WangJ, Insight into anticorrosion/antiwear behavior of inorganic-organic multilayer protection system composed of nitriding layer and epoxy coating with Ti3C2Tx MXene. Appl Surf Sci. 2021;536:147974.
130.
LiB, YinX, XueS, Facile fabrication of graphene oxide and MOF-based superhydrophobic dual-layer coatings for enhanced corrosion protection on magnesium alloy. Appl Surf Sci. 2022;580:152305.
131.
WangX, HuangJ, GuoZ.Overview of the development of slippery surfaces: lubricants from presence to absence. Adv Colloid Interface Sci. 2022;301:102602.
132.
LiH, YanM, ZhaoW.Designing a MOF-based slippery lubricant-infused porous surface with dual functional anti-fouling strategy. J Colloid Interf Sci. 2022;607:1424–1435.
133.
YinX, MuP, WangQ, Superhydrophobic ZIF-8-based dual-layer coating for enhanced corrosion protection of Mg alloy. ACS Appl Mater Inter. 2020;12:35453–35463.
134.
HuangG, YangQ, XuQ, Polydimethylsiloxane coating for a palladium/MOF composite: highly improved catalytic performance by surface hydrophobization. Angew Chem. 2016;128:7505–7509.
135.
KaurN, TiwariP, KapoorKS, Metal–organic framework based antibiotic release and antimicrobial response: an overview. CrystEngComm. 2020;22:7513–7527.
136.
LiP, LiJ, FengX, Metal-organic frameworks with photocatalytic bactericidal activity for integrated air cleaning. Nat Commun. 2019;10:2177.
137.
ShenM, ForghaniF, KongX, Antibacterial applications of metal–organic frameworks and their composites. Compr Rev Food Sci F. 2020;19:1397–1419.
HuW, YounisMR, ZhouY, In situ fabrication of ultrasmall gold nanoparticles/2D MOFs hybrid as nanozyme for antibacterial therapy. Small. 2020;16:2000553.
140.
YangY, WuX, HeC, Metal–organic framework/Ag-based hybrid nanoagents for rapid and synergistic bacterial eradication. ACS Appl Mater Inter. 2020;12:13698–13708.
ShenX, ZhangY, MaP, Fabrication of magnesium/zinc-metal organic framework on titanium implants to inhibit bacterial infection and promote bone regeneration. Biomaterials. 2019;212:1–16.
145.
HouY, HuW, GuiZ, Preparation of metal–organic frameworks and their application as flame retardants for polystyrene. Ind Eng Chem Res. 2017;56:2036–2045.
146.
HouY, HuW, ZhouX, Vertically aligned nickel 2-methylimidazole metal–organic framework fabricated from graphene oxides for enhancing fire safety of polystyrene. Ind Eng Chem Res. 2017;56:8778–8786.
147.
GaoY, WuJ, WangQ, Flame retardant polymer/layered double hydroxide nanocomposites. J Mater Chem A. 2014;2:10996–11016.
148.
MuX, ZhanJ, FengX, Novel melamine/o-phthalaldehyde covalent organic frameworks nanosheets: enhancement flame retardant and mechanical performances of thermoplastic polyurethanes. ACS Appl Mater Inter. 2017;9:23017–23026.
149.
QiX, ZhouD, ZhangJ, Simultaneous improvement of mechanical and fire-safety properties of polymer composites with phosphonate-loaded MOF additives. ACS Appl Mater Inter. 2019;11:20325–20332.
