The nanocrystalline, bright, ternary Zn–Ni–Fe alloy electrodeposit has been developed using additives such as tetradecyltrimethylammonium bromide and thiosemicarbazide on mild steel. The microstructure, corrosion resistance, hardness and tribological behaviour of bright Zn–Ni–Fe alloy deposit were analysed. The study revealed that additives modify the morphology, orientation and composition of the Zn–Ni–Fe alloy deposit. The morphological, orientation and chemical composition changes play a significant role by improving corrosion resistance and reducing wear and friction of deposit. Simultaneously, the effect of iron and TSC in plating bath on the corrosion resistance and microhardness of electrodeposited Zn–Ni–Fe coating has been investigated.
NayanaKO, VenkateshaTV.Effect of ethyl vanillin on ZnNi alloy electrodeposition and its properties. Bull Mater Sci. 2014;37:1137–1146. doi: 10.1007/s12034-014-0054-x
2.
FaidH, MentarL, KhelladiMR, Deposition potential effect on surface properties of Zn–Ni coatings. Surf Eng. 2017;33:529–535. doi: 10.1080/02670844.2017.1287836
3.
FengZ, RenL, ZhangJ, Influence of additives on microstructure, mechanical and tribological properties of nanocrystalline Zn-Ni coatings in a novel alkaline bath. RSC Adv. 2016;6:42029–42040. doi: 10.1039/C6RA02335E
4.
VenkatakrishnaK, Chitharanjan HegdeA, EliazN.Electrodeposition of bright Zn-Fe alloy on mild steel from acid chloride bath. Mater Sci Ind J. 2009;5(4):289–298.
5.
RameshSB, RajendraUK, HegdeAC.Development of layered Zn-Fe coatings for better corrosion protection. J Met Mater Miner. 2010;20:43–51.
6.
Abou-KrishaMM, AssafFH, El-NabySA.The influence of Fe2+ concentration and deposition time on the corrosion resistance of the electrodeposited zinc–nickel–iron alloys. Arabian J Chem. 2016;9:S1349–S1356. doi: 10.1016/j.arabjc.2012.02.014
7.
Abou-KrishaMM, AssafFH, El-NabySA.Electrodeposition behavior of zinc–nickel–iron alloys from sulfate bath. J Coat Technol Research. 2009;6:391–399. doi: 10.1007/s11998-008-9134-4
8.
KarahanAEIH.Structure and magnetic properties of electrodeposited ZnFeNi alloys. J Optoelectron Adv Mater Rapid Commun. 2008;2:746–750.
9.
HsiehJC, HuCC, LeeTC.The synergistic effects of additives on improving the electroplating of zinc under high current densities. J Electrochem Soc. 2008;155:D675–D681. doi: 10.1149/1.2967343
10.
HegdeAC, VenkatakrishnaK, EliazN.Electrodeposition of Zn–Ni, Zn–Fe and Zn–Ni–Fe alloys. Surf Coat Technol. 2010;2057:2031–2041. doi: 10.1016/j.surfcoat.2010.08.102
11.
KarahanIH, ÇetinkaraHA, GüderHS.Electrodeposition and characterisation of Zn, Zn–Fe and Zn–Fe–Ni coatings in presence of gelatin as additive. Trans Inst Met Finish. 2008;86:157–161. doi: 10.1179/174591908X304171
12.
KarahanIH, GuderHS.Electrodeposition and properties of Zn, Zn-Ni, Zn-Fe and Zn-Ni-Fe alloy from acidic chloride-sulphate electrolyte. Trans Met Finish. 2009;873:155–158. doi: 10.1179/174591909X438875
13.
YoussefKM, KochCC, FedkiwPS.Influence of pulse plating parameters on the synthesis and preferred orientation of nanocrystalline zinc from zinc sulfate electrolytes. Electrochim Acta. 2008;54:677–683. doi: 10.1016/j.electacta.2008.07.048
14.
El-SawafAK, WestDX.Iron(III), cobalt(II), nickel(II), copper(II) and zinc(II) complexes of 4-formylantipyrine thiosemicarbazone. Synth React Inorg Met Org Chem. 1997;27(8):1127–1147. doi: 10.1080/00945719708000252
15.
LiMC, JiangLL, ZhangWQ, Electrochemical corrosion behavior of nanocrystalline zinc coatings in 3.5% NaCl solutions. J Solid State Electrochem. 2007;11:1319–1325. doi: 10.1007/s10008-007-0293-5
16.
Punith KumarMK, VenkateshaTV, PavithraMK, The fabrication, characterization and electrochemical corrosion behavior of Zn-TiO2 composite coatings. Phys Scr. 2011;84:1–11. doi: 10.1088/0031-8949/84/03/035601
17.
ZhangY, ShiMH, LiC, The influence of grain size on the corrosion resistance of nanocrystalline zirconium metal. Mater Sci Eng A. 2007;448:259–263. doi: 10.1016/j.msea.2006.10.029
18.
Punith KumarMK, SrivastavaC.Enhancement of corrosion resistance of zinc coatings using green additives. J Mater Eng Perform. 2014;23:3418–3424. doi: 10.1007/s11665-014-1141-2
19.
KanagasabapathyM, JayakrishnanS.Textural and morphological studies on zinc–iron alloy electrodeposits. J Chem Sci. 2011;123:357–364. doi: 10.1007/s12039-011-0074-7
20.
SriramanKR, ManimundaP, ChromikRR, Effect of crystallographic orientation on the tribological behavior of electrodeposited Zn coatings. RSC Adv. 2016;6:17360–17372. doi: 10.1039/C5RA15490A
21.
LiQ, FengZ, RenL, Research on the tribological behavior of nanocrystalline zinc coating prepared by pulse reverse electrodeposition. RSC Adv. 2016;6:42029–42040. doi: 10.1039/C6RA02335E
