This work investigates the effect of Ta particle addition into a Ti6Al4V alloy processed by solid state sintering. The volume fraction of Ta ranged between 0 and 30 vol.-%. The sintering kinetics of powder mixes are evaluated by dilatometry. Sintered materials are characterised by SEM and XRD, and their mechanical properties are obtained from microhardness and compression tests. Sintering behaviour and final microstructure are affected by Ta particles, which slow down the densification, lower the temperature of α-to-β phase transition and stabilise the β phase. Mechanical properties, as microhardness, Young's modulus and yield stress, depend on the microstructure reached after sintering and on the residual porosity. An equation expressing the Young's modulus of Ti6Al4V/xTa alloy as function of x and porosity is proposed and validated. The materials with at least 20 vol.-% of Ta exhibited a high strength to modulus ratio, which is suitable for orthopaedic implants.
TurssiCP, de Moraes PurquerioB, SerraMC.Wear of dental resin composites: insights into underlying processes and assessment methods—a review. J Biomed Mater Res B. 2003;65(2):280–285. doi: 10.1002/jbm.b.10563
2.
KimY, KimEP, SongYB, Microstructure and mechanical properties of hot isostatically pressed Ti–6Al–4 V alloy. J Alloys Compd. 2014;603:207–212. doi: 10.1016/j.jallcom.2014.03.022
3.
BožićD, CvijovićI, VilotijevićMN, The influence of microstructural characteristics on the mechanical properties of Ti6Al4 V alloy produced by the powder metallurgy technique. J Serb Chem Soc. 2006;71(8–9):985–992. doi: 10.2298/JSC0609985B
4.
BandyopadhyayA, EspanaF, BallaVK, Influence of porosity on mechanical properties and in vivo response of Ti6Al4 V implants. Acta Biomater. 2010;6(4):1640–1648. doi: 10.1016/j.actbio.2009.11.011
5.
SouzaJC, HenriquesM, TeughelsW, Wear and corrosion interactions on titanium in oral environment: literature review. J Bio Tribo-Corros. 2015;1(2):1–13. doi: 10.1007/s40735-015-0013-0
6.
SouzaJCM, BarbosaSL, ArizaE, Simultaneous degradation by corrosion and wear of titanium in artificial saliva containing fluorides. Wear. 2012;292:82–88. doi: 10.1016/j.wear.2012.05.030
7.
BahraminasabM, SahariBB, EdwardsKL, Aseptic loosening of femoral components – a review of current and future trends in materials used. Mater Des. 2012;42:459–470. doi: 10.1016/j.matdes.2012.05.046
8.
NiinomiM, NakaiM.Titanium-based biomaterials for preventing stress shielding between implant devices and bone. Int J Biomater. 2011;2011:1–10. doi: 10.1155/2011/836587
9.
Cabezas-VillaJL, Lemus-RuizJ, BouvardD, Sintering study of Ti6Al4 V powders with different particle sizes and their mechanical properties. Int J Min Met Mater. 2018;25(12):1389–1401. doi: 10.1007/s12613-018-1693-5
10.
Torres-SanchezC, McLaughlinJ, FotticchiaA.Porosity and pore size effect on the properties of sintered Ti35Nb4Sn alloy scaffolds and their suitability for tissue engineering applications. J Alloys Compd. 2018;731:189–199. doi: 10.1016/j.jallcom.2017.10.026
11.
TorresY, LascanoS, BrisJ, Development of porous titanium for biomedical applications: a comparison between loose sintering and space-holder techniques. Mater Sci Eng C. 2014;37:148–155. doi: 10.1016/j.msec.2013.11.036
12.
Cabezas-VillaJL, OlmosL, BouvardD, Processing and properties of highly porous Ti6Al4 V mimicking human bones. J Mater Res. 2018;33(6):650–661. doi: 10.1557/jmr.2018.35
13.
CorreaDRN, KurodaPAB, LourençoML, Development of Ti-15Zr-Mo alloys for applying as implantable biomedical devices. J Alloys Compd. 2018;749:163–171. doi: 10.1016/j.jallcom.2018.03.308
14.
LeeCK.Fabrication, characterization and wear corrosion testing of bioactive hydroxyapatite/nano-TiO 2 composite coatings on anodic Ti–6Al–4 V substrate for biomedical applications. Mater Sci Eng B. 2012;177(11):810–818. doi: 10.1016/j.mseb.2012.03.034
15.
ChangJ-K, ChenCH, HuangKY, Eight-year results of hydroxyapatite-coated hip arthroplasty. J Arthroplasty. 2006;21(4):541–546. doi: 10.1016/j.arth.2005.04.043
16.
ArifinA, SulongAB, MuhamadN, Material processing of hydroxyapatite and titanium alloy (HA/Ti) composite as implant materials using powder metallurgy: a review. Mater Des. 2014;55:165–175. doi: 10.1016/j.matdes.2013.09.045
17.
ThianE, LohNH, KhorKA, Microstructures and mechanical properties of powder injection molded Ti-6Al-4V/HA powder. Biomaterials. 2002;23(14):2927–2938. doi: 10.1016/S0142-9612(01)00422-7
18.
NingC, ZhouY.In vitro bioactivity of a biocomposite fabricated from HA and Ti powders by powder metallurgy method. Biomaterials. 2002;23(14):2909–2915. doi: 10.1016/S0142-9612(01)00419-7
19.
RahmanHSA, ChoudhuryD, OsmanNAA, In vivo and in vitro outcomes of alumina, zirconia and their composited ceramic-on-ceramic hip joints. J Ceram Soc Jpn. 2013;121(1412):382–387. doi: 10.2109/jcersj2.121.382
20.
MatsunoH, YokoyamaA, WatariF, Biocompatibility and osteogenesis of refractory metal implants, titanium, hafnium, niobium, tantalum and rhenium. Biomaterials. 2001;22(11):1253–1262. doi: 10.1016/S0142-9612(00)00275-1
21.
LiuY, BaoC, WismeijerD, The physicochemical/biological properties of porous tantalum and the potential surface modification techniques to improve its clinical application in dental implantology. Mater Sci Eng C. 2015;49:323–329. doi: 10.1016/j.msec.2015.01.007
22.
SilvaR, WallsM, RondotB, Electrochemical and microstructural studies of tantalum and its oxide films for biomedical applications in endovascular surgery. J Mater Sci Mater Med. 2002;13(5):495–500. doi: 10.1023/A:1014779008598
23.
BlackJ.Biologic performance of tantalum. Clin Mater. 1994;16(3):167–173. doi: 10.1016/0267-6605(94)90113-9
24.
RahmatiB, SarhanAA, BasirunWJ, Ceramic tantalum oxide thin film coating to enhance the corrosion and wear characteristics of Ti 6Al 4V alloy. J Alloys Compd. 2016;676:369–376. doi: 10.1016/j.jallcom.2016.03.188
25.
XuG, ShenX, HuY, Fabrication of tantalum oxide layers onto titanium substrates for improved corrosion resistance and cytocompatibility. Surf Coat Technol. 2015;272:58–65. doi: 10.1016/j.surfcoat.2015.04.024
26.
WuCY, XinYH, WangXF, Effects of Ta content on the phase stability and elastic properties of β Ti–Ta alloys from first-principles calculations. Solid State Sci. 2010;12(12):2120–2124. doi: 10.1016/j.solidstatesciences.2010.09.009
27.
LiuY, LiK, WuH, Synthesis of Ti-Ta alloys with dual structure by incomplete diffusion between elemental powders. J Mech Behav Biomed Mater. 2015;51:302–312. doi: 10.1016/j.jmbbm.2015.07.004
28.
BallaVK, BanerjeeS, BoseS, Direct laser processing of a tantalum coating on titanium for bone replacement structures. Acta Biomater. 2010;6(6):2329–2334. doi: 10.1016/j.actbio.2009.11.021
29.
GillP, MunroeN, PulletikurthiC, Effect of manufacturing process on the biocompatibility and mechanical properties of Ti-30Ta alloy. J Mater Eng Perform. 2011;20(4):819–823. doi: 10.1007/s11665-011-9874-7
30.
YamabeY, UmedaJ, ImaiH, Tribological property of α- pure titanium strengthened by nitrogen solid-solution. Mater Trans. 2018;59(1):61–65. doi: 10.2320/matertrans.Y-M2017842
31.
DasK, DasS.A review of the Ti-Al-Ta (titanium-aluminum-tantalum) system. J Phase Equilib Diff. 2005;26:322–329. doi: 10.1007/s11669-005-0081-9
32.
ParkY, ButtDP.Composition dependence of the kinetics and mechanisms of thermal oxidation of titanium-tantalum alloys. Oxid Met. 1999;51(5–6):383–402. doi: 10.1023/A:1018883009343
33.
LangenkämperD, PaulsenA, SomsenC, On the Oxidation behavior and its influence on the martensitic transformation of Ti–Ta high-temperature shape memory alloys. Shape Memory Superelasticity. 2019;5(1):63–72. doi: 10.1007/s40830-018-00206-1
34.
XuX, NashP.Sintering mechanisms of Armstrong prealloyed Ti–6Al–4V powders. Mater Sci Eng A. 2014;607:409–416. doi: 10.1016/j.msea.2014.03.045
35.
ChávezJ, OlmosL, JiménezO, Sintering behaviour and mechanical characterisation of Ti64/x TiN composites and bilayer components. Powder Metall. 2017;60(4):257–266. doi: 10.1080/00325899.2017.1280585
36.
LuzhnikovLP, NovikovaVM, MareevAP.Solubility of β-stabilizers in α-titanium. Met Sci Heat Treat. 1963;5:78–81. doi: 10.1007/BF00650694
37.
Vázquez-GómezO, Gallegos-PérezAI, López-MartínezE, Criteria for the dilatometric analysis to determine the transformation kinetics during continuous heating. J Therm Anal Calorim. 2019;135(6):2985–2993. doi: 10.1007/s10973-018-7449-7
38.
DerczG, MatułaI, ZubkoM, Synthesis of porous Ti–50Ta alloy by powder metallurgy. Mater Charact. 2018;142:124–136. doi: 10.1016/j.matchar.2018.05.033
39.
ChávezJ, Jiménez AlemánO, Flores MartínezM, Characterization of Ti6Al4V–Ti6Al4V/30Ta bilayer components processed by powder metallurgy for biomedical applications. Met Mater Int. 2019: 1–16. DOI:10.1007/s12540-019-00326-y.
40.
KimHY, MiyazakiS.Martensitic transformation and superelastic properties of Ti-Nb Base alloys. Mater Trans. 2015;56:625–634. doi: 10.2320/matertrans.M2014454
41.
HöglundL, ÅgrenJ.Analysis of the Kirkendall effect, marker migration and pore formation. Acta Mater. 2001;49(8):1311–1317. doi: 10.1016/S1359-6454(01)00054-4
42.
HeYH, JiangY, XuNP, Fabrication of Ti–Al micro/nanometer-sized porous alloys through the Kirkendall effect. Adv Mater. 2007;19(16):2102–2106. doi: 10.1002/adma.200602398
43.
ZhouYL, NiinomiM.Ti–25ta alloy with the best mechanical compatibility in Ti–Ta alloys for biomedical applications. Mater Sci Eng C. 2009;29(3):1061–1065. doi: 10.1016/j.msec.2008.09.012
44.
XuS, LiuY, YangC, Compositionally gradient Ti-Ta metal-metal composite with ultra-high strength. Mater Sci Eng A. 2018;712:386–393. doi: 10.1016/j.msea.2017.11.089
45.
BuenconsejoPJS, KimHY, MiyazakiS.Novel β-TiTaAl alloys with excellent cold workability and a stable high-temperature shape memory effect. Scripta Mater. 2011;64(12):1114–1117. doi: 10.1016/j.scriptamat.2011.03.004
46.
GordinDM, DelvatE, ChelariuR, Characterization of Ti-Ta alloys Synthesized by cold Crucible Levitation melting. Adv Eng Mater. 2008;10(8):714–719. doi: 10.1002/adem.200800041
47.
FanZ.3 moduli of Ti-6Al-4V alloys. Scripta Metall Mater. 1993;29(11):1427–1432. doi: 10.1016/0956-716X(93)90331-L
48.
ZhouYL, NiinomiM.Microstructures and mechanical properties of Ti–50 mass% Ta alloy for biomedical applications. J Alloys Compd. 2008;466(1–2):535–542. doi: 10.1016/j.jallcom.2007.11.090
49.
HaoYL, YangR, NiinomiM, Young's modulus and mechanical properties of Ti-29Nb-13Ta-4.6 Zr in relation to α ″martensite. Metall Mater Trans A. 2002;33(10):3137–3144. doi: 10.1007/s11661-002-0299-7
50.
LongM, RackHJ.Titanium alloys in total joint replacement—a materials science perspective. Biomaterials. 1998;19(18):1621–1639. doi: 10.1016/S0142-9612(97)00146-4
51.
NiinomiM.Mechanical properties of biomedical titanium alloys. Mater Sci Eng A. 1998;243(1–2):231–236. doi: 10.1016/S0921-5093(97)00806-X
52.
ChávezJ, OlmosL, BouvardD.Synthesis and characterization of shape memory porous Ti6Al4V/Ta components for bone implant applications. Manuscript refereed by Prof Dr Efrain Carreño-Morelli. Proceedings of the Euro PM2019 – Materials for Biomedical Applications. 2019. p. 1–6.
